Volume 51
Main Index

Issue 01

Evaluation of a Ruthenium Oxyquinolate Architecture for Dye-Sensitized Solar Cells Helen C. Zhao, Joseph P. Harney, Yu-Ting Huang, Jun-Ho Yum, Md. K. Nazeeruddin, Michael Grätzel, Ming-Kang Tsai, and Jonathan Rochford pp 1–3 DOI: 10.1021/ic201375k

Direct Involvement of the Acetato Ligand in the Reductive Elimination Step of Rhodium-Catalyzed Methanol Carbonylation Nicolas Lassauque, Thomas Davin, Duc Hanh Nguyen, Romain J. Adcock, Yannick Coppel, Carole Le Berre, Philippe Serp, Laurent Maron, and Philippe Kalck pp 4–6 DOI: 10.1021/ic201574m

New Neptunium(V) Borates That Exhibit the Alexandrite Effect Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, and Thomas E. Albrecht-Schmitt pp 7–9 DOI: 10.1021/ic201682s

Cyclam Functionalization through Isocyanate Insertion in Zr–N Bonds Luis G. Alves and Ana M. Martins pp 10–12 DOI: 10.1021/ic201750y

Theoretical Examination of the Thermodynamic Factors in the Selective Extraction of Am3+ from Eu3+ by Dithiophosphinic Acids Jason M. Keith and Enrique R. Batista pp 13–15 DOI: 10.1021/ic202061b

A Homologous Series of Cobalt, Rhodium, and Iridium Metalloradicals Ayumi Takaoka and Jonas C. Peters pp 16–18 DOI: 10.1021/ic202079r

Hybrid Polyoxovanadates: Anion-Influenced Formation of Nanoscopic Cages and Supramolecular Assemblies of Asymmetric Clusters John M. Breen, Lei Zhang, Raphaèle Clement, and Wolfgang Schmitt pp 19–21 DOI: 10.1021/ic202104z

Four-Electron Oxygen Reduction by Brominated Cobalt Corrole Alex Schechter, Maria Stanevsky, Atif Mahammed, and Zeev Gross pp 22–24 DOI: 10.1021/ic202139f

Formation of the Imide [Ta(NMe2)3(μ-NSiMe3)]2 through an Unprecedented α-SiMe3 Abstraction by an Amide Ligand Bhavna Sharma, Shu-Jian Chen, Julia K. C. Abbott, Xue-Tai Chen, and Zi-Ling Xue pp 25–27 DOI: 10.1021/ic2021676

Variables That Influence Cellular Uptake and Cytotoxic/Cytoprotective Effects of Macrocyclic Iron Complexes Adi Haber, Michael Aviram, and Zeev Gross pp 28–30 DOI: 10.1021/ic202204u

Awakening of a Ferrous Complex’s Electronic Spin in an Aqueous Solution Induced by a Chemical Stimulus Fayçal Touti, Philippe Maurin, Laurence Canaple, Olivier Beuf, and Jens Hasserodt pp 31–33 DOI: 10.1021/ic202268e

Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity M. Angeles Alvarez, M. Esther García, Daniel García-Vivó, Alberto Ramos, Miguel A. Ruiz, and Jaime Suárez pp 34–36 DOI: 10.1021/ic2023456

Uranium Pyrrolylamine Complexes Featuring a Trigonal Binding Pocket and Interligand Noncovalent Interactions Andrew J. Lewis, Ursula J. Williams, James M. Kikkawa, Patrick J. Carroll, and Eric J. Schelter pp 37–39 DOI: 10.1021/ic202411f

Structure and Magnetism in Fe–Gd Based Dinuclear and Chain Systems. The Interplay of Weak Exchange Coupling and Zero Field Splitting Effects Marilena Ferbinteanu, Fanica Cimpoesu, Mihai A. Gîrţu, Cristian Enachescu, and Stefania Tanase pp 40–50 DOI: 10.1021/ic1023289

Enhanced Photocatalytic Activity of α-Methylstyrene Oligomerization through Effective Metal-to-Ligand Charge-Transfer Localization on the Bridging Ligand Hiroyuki Nitadori, Takeshi Takahashi, Akiko Inagaki, and Munetaka Akita pp 51–62 DOI: 10.1021/ic200291t

Hydroxylation Catalysis by Mononuclear and Dinuclear Iron Oxo Catalysts: a Methane Monooxygenase Model System versus the Fenton Reagent FeIVO(H2O)52+  G. Gopakumar, Paola Belanzoni, and Evert Jan Baerends pp 63–75 DOI: 10.1021/ic200754w

Role of NH3 in the Dehydrogenation of Calcium Amidoborane Ammoniate and Magnesium Amidoborane Ammoniate: A First-Principles Study Wen Li, Guotao Wu, Yongshen Chua, Yuan Ping Feng, and Ping Chen pp 76–87 DOI: 10.1021/ic200990m

Syntheses, Characterization, and Magnetic Studies of Copper(II) Complexes with the Ligand N,N,N′,N′-Tetrakis(2-pyridylmethyl)-1,3-benzenediamine (1,3-tpbd) and its Phenol Derivative 2,6-Bis[bis(2-pyridylmethyl)amino]-p-cresol] (2,6-Htpcd) Sabrina Turba, Simon P. Foxon, Alexander Beitat, Frank W. Heinemann, Konstantin Petukhov, Paul Müller, Olaf Walter, Francesc Lloret, Miguel Julve, and Siegfried Schindler pp 88–97 DOI: 10.1021/ic201051g

Self-Assembly of Silver(I) and Gold(I) N-Heterocyclic Carbene Complexes in Solid State, Mesophase, and Solution Tina H. T. Hsu, Jaishri J. Naidu, Bi-Jiuan Yang, Meng-Ying Jang, and Ivan J. B. Lin pp 98–108 DOI: 10.1021/ic2011343

Dual Luminescent Tetranuclear Organogold(I) Macrocycles of 5,5′-Diethynyl-2,2′-bipyridine and Their Efficient Sensitization of Yb(III) Luminescence Xiu-Ling Li, Ming Tan, Ke-Juan Zhang, Bo Yang, Jie Chen, and Yu-Bo Ai pp 109–118 DOI: 10.1021/ic201741h

Visible-Light Generation of the Naked 12-Electron Fragment C5H5Fe+: Alkyne-to-Vinylidene Isomerization and Synthesis of Polynuclear Iron Vinylidene and Alkynyl Complexes Including Hexairon Stars Yanlan Wang, Abdou K. Diallo, Cátia Ornelas, Jaime Ruiz, and Didier Astruc pp 119–127 DOI: 10.1021/ic201206e

Probing the Copper(II) Binding Features of Angiogenin. Similarities and Differences between a N-Terminus Peptide Fragment and the Recombinant Human Protein Diego La Mendola, Daniel Farkas, Francesco Bellia, Antonio Magrì, Alessio Travaglia, Örjan Hansson, and Enrico Rizzarelli pp 128–141 DOI: 10.1021/ic201300e

New Hybrid Layered Molybdates Based on 2/∞[MonO3n+1]2– Units (n = 7, 9) with Systematic Organic–Inorganic Interfaces Martine Bujoli-Doeuff, Rémi Dessapt, Philippe Deniard, and Stéphane Jobic pp 142–149 DOI: 10.1021/ic201298d

Unusual Nonoctahedral Geometry with Molybdenum Oxoimido Complexes Containing η2-Pyrazolate Ligands T. Arumuganathan, Manuel Volpe, Bastian Harum, Dietmar Wurm, Ferdinand Belaj, and Nadia C. Mösch-Zanetti pp 150–156 DOI: 10.1021/ic201308g

Synthesis, Reactivity Studies, Structural Aspects, and Solution Behavior of Half Sandwich Ruthenium(II) N,N′,N″-Triarylguanidinate Complexes Taruna Singh, Ram Kishan, Munirathinam Nethaji, and Natesan Thirupathi pp 157–169 DOI: 10.1021/ic201343w

17O NMR and Density Functional Theory Study of the Dynamics of the Carboxylate Groups in DOTA Complexes of Lanthanides in Aqueous Solution Florian Mayer, Carlos Platas-Iglesias, Lothar Helm, Joop A. Peters, and Kristina Djanashvili pp 170–178 DOI: 10.1021/ic201393n

Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3 (M = Fe2+, Cu2+) Complexes Fengjuan Cui, Shaoguang Li, Chuandong Jia, Jennifer S. Mathieson, Leroy Cronin, Xiao-Juan Yang, and Biao Wu pp 179–187 DOI: 10.1021/ic201417y

A Coordination Complex System for Generic, Ultrafast, and Sensitive Multimode Fluorescent Staining of Biomolecules Xingqiang Liu, Lingjuan Li, Jingjing Sun, Yishu Yan, Xin Shu, Baoqing Liu, Wei Sha, Hui Feng, Sha Sun, and Jin Zhu pp 188–192 DOI: 10.1021/ic201406b

Mercuric Ionic Liquids: [Cnmim][HgX3], Where n = 3, 4 and X = Cl, Br Bert Mallick, Andreas Metlen, Mark Nieuwenhuyzen, Robin D. Rogers, and Anja-Verena Mudring pp 193–200 DOI: 10.1021/ic201415d

Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer Karah E. Knope, Daniel T. de Lill, Clare E. Rowland, Paula M. Cantos, Ana de Bettencourt-Dias, and Christopher L. Cahill pp 201–206 DOI: 10.1021/ic201450e

New Ternary Germanides La4Mg5Ge6 and La4Mg7Ge6: Crystal Structure and Chemical Bonding Pavlo Solokha, Serena De Negri, Monika Skrobanska, Adriana Saccone, Volodymyr Pavlyuk, and Davide M. Proserpio pp 207–214 DOI: 10.1021/ic2014732

Acid-Induced Degradation of Phosphorescent Dopants for OLEDs and Its Application to the Synthesis of Tris-heteroleptic Iridium(III) Bis-cyclometalated Complexes Etienne Baranoff, Basile F. E. Curchod, Julien Frey, Rosario Scopelliti, Florian Kessler, Ivano Tavernelli, Ursula Rothlisberger, Michael Grätzel, and Md. Khaja Nazeeruddin pp 215–224 DOI: 10.1021/ic202162q

Divalent-Metal-Stabilized Aluminophosphates Exhibiting a New Zeolite Framework Topology Lang Shao, Yi Li, Jihong Yu, and Ruren Xu pp 225–229 DOI: 10.1021/ic201515z

Cu4I4 Clusters Supported by PN-type Ligands: New Structures with Tunable Emission Colors Zhiwei Liu, Peter I. Djurovich, Matthew T. Whited, and Mark E. Thompson pp 230–236 DOI: 10.1021/ic2015226

HSLS Transition in Iron(II) Two-Dimensional Coordination Networks Containing Tris(tetrazol-1-ylmethyl)methane As Triconnected Building Block Agata Białońska, Robert Bronisz, Mikołaj F. Rudolf, and Marek Weselski pp 237–245 DOI: 10.1021/ic201535x

Multinuclear Copper(I) Guanidinate Complexes Alexander M. Willcocks, Thomas P. Robinson, Christopher Roche, Thomas Pugh, Stephen P. Richards, Andrew J. Kingsley, John P. Lowe, and Andrew L. Johnson pp 246–257 DOI: 10.1021/ic201602m

Theoretical Elucidation of a Classic Reaction: Protonation of the Quadruple Bond of the Octachlorodimolybdate(II,II) [Mo2Cl8]4– Anion Emmanuel D. Simandiras, Metaxia Tsakiroglou, Nikolaos Psaroudakis, Dimitrios G. Liakos, and Konstantinos Mertis pp 258–266 DOI: 10.1021/ic2016325

Fluorescent Uranyl Ion Lidded Cucurbit[5]uril Capsule S. Kushwaha, Srinivas A. Rao, and Padmaja P. Sudhakar pp 267–273 DOI: 10.1021/ic201641g

Titanium Complexes Supported by an [OSSO]-Type Bis(phenolato) Ligand Based on a trans-Cyclooctanediyl Platform: Synthesis, Structures, and 1-Hexene Polymerization Norio Nakata, Tomoyuki Toda, Tsukasa Matsuo, and Akihiko Ishii pp 274–281 DOI: 10.1021/ic2016484

Structural Frustration and Occupational Disorder: The Rare Earth Metal Polysulfides Tb8S14.8, Dy8S14.9, Ho8S14.9, and Y8S14.8 Thomas Doert, Christian Graf, Inga G. Vasilyeva, and Walter Schnelle pp 282–289 DOI: 10.1021/ic201639f

Thermally Induced Defluorination during a mer to fac Transformation of a Blue-Green Phosphorescent Cyclometalated Iridium(III) Complex Yonghao Zheng, Andrei S. Batsanov, Robert M. Edkins, Andrew Beeby, and Martin R. Bryce pp 290–297 DOI: 10.1021/ic201655n

Synthesis and Characterization of Electroactive Ferrocene Derivatives: Ferrocenylimidazoquinazoline as a Multichannel Chemosensor Selectively for Hg2+ and Pb2+ Ions in an Aqueous Environment Rampal Pandey, Rakesh Kumar Gupta, Mohammad Shahid, Biswajit Maiti, Arvind Misra, and Daya Shankar Pandey pp 298–311 DOI: 10.1021/ic201663m

Improving the Performance of Pt(II) Complexes for Blue Light Emission by Enhancing the Molecular Rigidity Andreas F. Rausch, Lisa Murphy, J. A. Gareth Williams, and Hartmut Yersin pp 312–319 DOI: 10.1021/ic201664v

Synthesis, Structure, and Electronic Properties of RuN6 Dinuclear Ru-Hbpp Complexes Stephan Roeser, Mehmed Z. Ertem, Clyde Cady, Rainer Lomoth, Jordi Benet-Buchholz, Leif Hammarström, Biprajit Sarkar, Wolfgang Kaim, Christopher J. Cramer, and Antoni Llobet pp 320–327 DOI: 10.1021/ic201668r

Stereochemical Inversion of Phosphonothioate Methanolysis by La(III) and Zn(II): Mechanistic Implications for the Degradation of Organophosphate Neurotoxins Louis Y. Kuo and Sara K. Glazier pp 328–335 DOI: 10.1021/ic2016897

Recognition of Hg2+ and Cr3+ in Physiological Conditions by a Rhodamine Derivative and Its Application as a Reagent for Cell-Imaging Studies Sukdeb Saha, Prasenjit Mahato, Upendar Reddy G, E. Suresh, Arindam Chakrabarty, Mithu Baidya, Sudip K. Ghosh, and Amitava Das pp 336–345 DOI: 10.1021/ic2017243

Redox-Controlled Interconversion between Trigonal Prismatic and Octahedral Geometries in a Monodithiolene Tetracarbonyl Complex of Tungsten Yong Yan, Perumalreddy Chandrasekaran, Joel T. Mague, Serena DeBeer, Stephen Sproules, and James P. Donahue pp 346–361 DOI: 10.1021/ic201748v

Structural Stability of Quaternary ACuFeS2 (A = Li, K) Phases: A Computational Approach Sergio Conejeros, Pere Alemany, Miquel Llunell, Víctor Sánchez, Jaime Llanos, and Luis Padilla-Campos pp 362–369 DOI: 10.1021/ic201758j

Synthesis, Characterization, and Calculated Electronic Structure of the Crystalline Metal–Organic Polymers [Hg(SC6H4S)(en)]n and [Pb(SC6H4S)(dien)]n Dayna L. Turner, Kevin H. Stone, Peter W. Stephens, Aron Walsh, Mayank Pratap Singh, and Thomas P. Vaid pp 370–376 DOI: 10.1021/ic201779a

A Theoretical Study of Metal–Metal Cooperativity in the Homogeneous Water Gas Shift Reaction Nishamol Kuriakose, Shantanu Kadam, and Kumar Vanka pp 377–385 DOI: 10.1021/ic201788t

Novel Heterometallic Schiff Base Complexes Featuring Unusual Tetranuclear {CoIII2FeIII2(μ-O)6} and Octanuclear {CoIII4FeIII4(μ-O)14} Cores: Direct Synthesis, Crystal Structures, and Magnetic Properties Eduard N. Chygorin, Oksana V. Nesterova, Julia A. Rusanova, Vladimir N. Kokozay, Volodymyr V. Bon, Roman Boča, and Andrew Ozarowski pp 386–396 DOI: 10.1021/ic2017962

Using High Pressure to Prepare Polymorphs of the Ba2Co1–xZnxS3 (0 ≤ x ≤ 1.0) Compounds Francesco Mezzadri, Edmondo Gilioli, Gianluca Calestani, Andrea Migliori, Mark R. Harrison, David A. Headspith, and M. Grazia Francesconi pp 397–404 DOI: 10.1021/ic201773e

Polynuclear and Polymeric Gadolinium Acetate Derivatives with Large Magnetocaloric Effect Fu-Sheng Guo, Ji-Dong Leng, Jun-Liang Liu, Zhao-Sha Meng, and Ming-Liang Tong pp 405–413 DOI: 10.1021/ic2018314

In Situ X-ray Absorption Spectroscopy Study of Si1–xGexO2 Dissolution and Germanium Aqueous Speciation under Hydrothermal Conditions V. Ranieri, J. Haines, O. Cambon, C. Levelut, R. Le Parc, M. Cambon, and J.-L. Hazemann pp 414–419 DOI: 10.1021/ic201856p

BiSr3(YO)3(BO3)4: A New Gaudefroyite-Type Rare-Earth Borate with Moderate SHG Response Jianhua Gao and Shuai Li pp 420–424 DOI: 10.1021/ic201858x

A Study of the Hydration of the Alkali Metal Ions in Aqueous Solution Johan Mähler and Ingmar Persson pp 425–438 DOI: 10.1021/ic2018693

Coordination of a Complete Series of N2 Reduction Intermediates (N2H2, N2H4, and NH3) to an Iron Phosphine Scaffold Justin L. Crossland, Chantal G. Balesdent, and David R. Tyler pp 439–445 DOI: 10.1021/ic201873a

Luminescent Rhenium(I)-Dipyrrinato Complexes Tracey M. McLean, Janice L. Moody, Mark R. Waterland, and Shane G. Telfer pp 446–455 DOI: 10.1021/ic201877t

Crystal Structure, Spin Polarization, Solid-State Electrochemistry, and High n-Type Carrier Mobility of a Paramagnetic Semiconductor: Vanadyl Tetrakis(thiadiazole)porphyrazine Yasuhito Miyoshi, Kouji Takahashi, Takuya Fujimoto, Hirofumi Yoshikawa, Michio M. Matsushita, Yukio Ouchi, Mikael Kepenekian, Vincent Robert, Maria Pia Donzello, Claudio Ercolani, and Kunio Awaga pp 456–462 DOI: 10.1021/ic201880g

Synthesis, Characterization, and DNA Binding Properties of Ruthenium(II) Complexes Containing the Redox Active Ligand Benzo[i]dipyrido[3,2-a:2′,3′-c]phenazine-11,16-quinone Simon P. Foxon, Charlotte Green, Michael G. Walker, Ashley Wragg, Harry Adams, Julia A. Weinstein, Simon C. Parker, Anthony J. H. M. Meijer, and Jim A. Thomas pp 463–471 DOI: 10.1021/ic201914h

Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator Guang-Ning Liu, Guo-Cong Guo, Feng Chen, Shuai-Hua Wang, Jing Sun, and Jin-Shun Huang pp 472–482 DOI: 10.1021/ic201932z

Water-Free Neodymium 2,6-Naphthalenedicarboxylates Coordination Complexes and Their Application as Catalysts for Isoprene Polymerization Inês Rodrigues, Ionut Mihalcea, Christophe Volkringer, Thierry Loiseau, and Marc Visseaux pp 483–490 DOI: 10.1021/ic2019346

Detection of the Singlet and Triplet MM δδ* States in Quadruply Bonded Dimetal Tetracarboxylates (M = Mo, W) by Time-Resolved Infrared Spectroscopy Brian G. Alberding, Malcolm H. Chisholm, and Terry L. Gustafson pp 491–498 DOI: 10.1021/ic201957a

Interactions between Metal Ions and Carbohydrates. Spectroscopic Characterization and the Topology Coordination Behavior of Erythritol with Trivalent Lanthanide Ions Limin Yang, Xiaohui Hua, Junhui Xue, Qinghua Pan, Lei Yu, Weihong Li, Yizhuang Xu, Guozhong Zhao, Liming Liu, Kexin Liu, Jia’er Chen, and Jinguang Wu pp 499–510 DOI: 10.1021/ic2019605

Syntheses and Crystal Structures of the closo-Borate M[B8H9] (M = [PPh4]+ and [N(n-Bu4)]+) Florian Schlüter and Eduard Bernhardt pp 511–517 DOI: 10.1021/ic201973b

Synthesis of Hafnium Oxide-Gold Core–Shell Nanoparticles Naween Dahal and Viktor Chikan pp 518–522 DOI: 10.1021/ic201977d

Lanthanide-Thiophene-2,5-dicarboxylate Frameworks: Ionothermal Synthesis, Helical Structures, Photoluminescent Properties, and Single-Crystal-to-Single-Crystal Guest Exchange Cai-Hong Zhan, Fei Wang, Yao Kang, and Jian Zhang pp 523–530 DOI: 10.1021/ic201986m

Noninjection Facile Synthesis of Gram-Scale Highly Luminescent CdSe Multipod Nanocrystals Wenjin Zhang, Chan Jin, Yongji Yang, and Xinhua Zhong pp 531–535 DOI: 10.1021/ic201989w

Novel Air-Stable and Volatile Bis(pyridylalkenolato)palladium(II) and -platinum(II) Derivatives Lisa Brückmann, Wieland Tyrra, Stefan Stucky, and Sanjay Mathur pp 536–542 DOI: 10.1021/ic201996r

Molecular Structure and Vibrational Spectra of Mixed MDyX4 (M = Li, Na, K, Rb, Cs; X = F, Cl, Br, I) Vapor Complexes: A Computational and Matrix-Isolation Infrared Spectroscopic Study Cornelis Petrus Groen, Attila Kovács, Zoltán Varga, and Magdolna Hargittai pp 543–556 DOI: 10.1021/ic202009v

Spin 1/2 Delafossite Honeycomb Compound Cu5SbO6 E. Climent-Pascual, P. Norby, N.H. Andersen, P.W. Stephens, H.W. Zandbergen, J. Larsen, and R.J. Cava pp 557–565 DOI: 10.1021/ic202066n

From Solid State to Solution: Advancing Chemistry of Bi–Bi and Bi–Rh Paddlewheel Carboxylates Alexander S. Filatov, Margaret Napier, Volodimir D. Vreshch, Natalie J. Sumner, Evgeny V. Dikarev, and Marina A. Petrukhina pp 566–571 DOI: 10.1021/ic202089p

Selective CO2 Adsorption in a Robust and Water-Stable Porous Coordination Polymer with New Network Topology Sanjog S. Nagarkar, Abhijeet K. Chaudhari, and Sujit K. Ghosh pp 572–576 DOI: 10.1021/ic202102m

Complexation of Metal Ions with TRAP (1,4,7-Triazacyclononane Phosphinic Acid) Ligands and 1,4,7-Triazacyclononane-1,4,7-triacetic Acid: Phosphinate-Containing Ligands as Unique Chelators for Trivalent Gallium Jakub Šimeček, Martin Schulz, Johannes Notni, Jan Plutnar, Vojtěch Kubíček, Jana Havlíčková, and Petr Hermann pp 577–590 DOI: 10.1021/ic202103v

Complexation of Europium(III) by Bis(dialkyltriazinyl)bipyridines in 1-Octanol Michael Steppert, Ivana Císařová, Thomas Fanghänel, Andreas Geist, Patric Lindqvist-Reis, Petra Panak, Petr Štěpnička, Sascha Trumm, and Clemens Walther pp 591–600 DOI: 10.1021/ic202119x

Manganese Carbonyls Bearing Tripodal Polypyridine Ligands as Photoactive Carbon Monoxide-Releasing Molecules Margarita A. Gonzalez, Melanie A. Yim, Stephanie Cheng, Amie Moyes, Adrian J. Hobbs, and Pradip K. Mascharak pp 601–608 DOI: 10.1021/ic2021287

New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+) Jeongho Yeon, Sang-Hwan Kim, Sau Doan Nguyen, Hana Lee, and P. Shiv Halasyamani pp 609–619 DOI: 10.1021/ic2021403

Synthesis, Structure, Chemical Bonding, and Magnetism of the Series RELiGe2 (RE = La–Nd, Sm, Eu) Svilen Bobev, Tae-Soo You, and Nian-Tzu Suen , Shanta Saha, Richard Greene, and Johnpierre Paglione pp 620–628 DOI: 10.1021/ic2021484

Synthesis, Biological Evaluation, and Radioiodination of Halogenated closo-Carboranylthymidine Analogues Rohit Tiwari, Antonio Toppino, Hitesh K. Agarwal, Tianyao Huo, Youngjoo Byun, Judith Gallucci, Sherifa Hasabelnaby, Ahmed Khalil, Ayman Goudah, Robert A. Baiocchi, Michael V. Darby, Rolf F. Barth, and Werner Tjarks pp 629–639 DOI: 10.1021/ic202150b

Design of Neutral Lewis Superacids of Group 13 Elements Leonie Anna Mück, Alexey Y. Timoshkin, and Gernot Frenking pp 640–646 DOI: 10.1021/ic202152h

Structural and Photophysical Properties of Visible- and Near-IR-Emitting Tris Lanthanide(III) Complexes Formed with the Enantiomers of N,N′-Bis(1-phenylethyl)-2,6-pyridinedicarboxamide KimNgan T. Hua, Jide Xu, Eliseo E. Quiroz, Sabrina Lopez, Andrew J. Ingram, Victoria Anne Johnson, Angela R. Tisch, Ana de Bettencourt-Dias, Daniel A. Straus, and Gilles Muller pp 647–660 DOI: 10.1021/ic202094p

Ba8Hg3U3S18: A Complex Uranium(+4)/Uranium(+5) Sulfide Daniel E. Bugaris and James A. Ibers pp 661–666 DOI: 10.1021/ic202161y

Matrix Infrared Spectroscopic and Theoretical of the Difluoroamino Metal Fluoride Molecules: F2NMF (M = Cu, Ag, Au) Yu Gong and Lester Andrews pp 667–673 DOI: 10.1021/ic2021758

Mn(II)-Based Porous Metal–Organic Framework Showing Metamagnetic Properties and High Hydrogen Adsorption at Low Pressure Zheng-Bo Han, Rui-Yun Lu, Yan-Fang Liang, Yan-Ling Zhou, Qing Chen, and Ming-Hua Zeng pp 674–679 DOI: 10.1021/ic2021929

Manganese K-Edge X-Ray Absorption Spectroscopy as a Probe of the Metal–Ligand Interactions in Coordination Compounds Michael Roemelt, Martha A. Beckwith, Carole Duboc, Marie-Noëlle Collomb, Frank Neese, and Serena DeBeer pp 680–687 DOI: 10.1021/ic202229b

Reactivity of Cr(III) μ-Oxo Compounds: Catalyst Regeneration and Atom Transfer Processes K. Cory MacLeod, Brian O. Patrick, and Kevin M. Smith pp 688–700 DOI: 10.1021/ic202233f

Dynamics of ZnII Binding as a Key Feature in the Formation of Amyloid Fibrils by Aβ11-28 Bruno Alies, Pier-Lorenzo Solari, Christelle Hureau, and Peter Faller pp 701–708 DOI: 10.1021/ic202247m

Self-Decelerating Relaxation of the Light-Induced Spin States in Molecular Magnets Cu(hfac)2LR Studied by Electron Paramagnetic Resonance Matvey V. Fedin, Ksenia Yu. Maryunina, Renad Z. Sagdeev, Victor I. Ovcharenko, and Elena G. Bagryanskaya pp 709–717 DOI: 10.1021/ic202248v

Electrical Conductivity and Luminescence in Coordination Polymers Based on Copper(I)-Halides and Sulfur-Pyrimidine Ligands Almudena Gallego, Oscar Castillo, Carlos J. Gómez-García, Félix Zamora, and Salome Delgado pp 718–727 DOI: 10.1021/ic202255w

A Combined Spectroscopic and Computational Study of a High-Spin S = 7/2 Diiron Complex with a Short Iron–Iron Bond Christopher M. Zall, Danylo Zherebetskyy, Allison L. Dzubak, Eckhard Bill, Laura Gagliardi, and Connie C. Lu pp 728–736 DOI: 10.1021/ic202384b

Investigations on the Interaction of Dichloroaluminum Carboxylates with Lewis Bases and Water: an Efficient Road toward Oxo- and Hydroxoaluminum Carboxylate Complexes Wojciech Bury, Elżbieta Chwojnowska, Iwona Justyniak, Janusz Lewiński, Aneta Affek, Ewa Zygadło-Monikowska, Joanna Bąk, and Zbigniew Florjańczyk pp 737–745 DOI: 10.1021/ic2023924

X-ray Structures of Sc2C2@C2n (n = 40–42): In-Depth Understanding of the Core–Shell Interplay in Carbide Cluster Metallofullerenes Hiroki Kurihara, Xing Lu, Yuko Iiduka, Hidefumi Nikawa, Makoto Hachiya, Naomi Mizorogi, Zdenek Slanina, Takahiro Tsuchiya, Shigeru Nagase, and Takeshi Akasaka pp 746–750 DOI: 10.1021/ic202438u

Issue 02

Bismuth Pyrostannate, Bi2Sn2O7, from the First Structurally Characterized Heterobimetallic Bi:Sn Alkoxides Philip C. Andrews, Peter C. Junk, Iryna Nuzhnaya, and Dominique T. Thielemann pp 751–753 DOI: 10.1021/ic202707p

An Unexpected Mechanism of Hydrosilylation by a Silyl Hydride Complex of Molybdenum Andrey Y. Khalimon, Stanislav K. Ignatov, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A. K. Howard, and Georgii I Nikonov pp 754–756 DOI: 10.1021/ic201550a

Spin-Canting Magnetization in an Unusual Co4 Cluster-Based Layer Compound from a 2,3-Dihydroxyquinoxaline Ligand Chen-I Yang, Po-Hsiang Chuang, Gene-Hsiang Lee, Shie-Ming Peng, and Kuang-Lieh Lu pp 757–759 DOI: 10.1021/ic201636g

Molecular Thioamide ↔ Iminothiolate Switches for Sulfur Mustards Qi-Qiang Wang, Rowshan Ara Begum, Victor W. Day, and Kristin Bowman-James pp 760–762 DOI: 10.1021/ic202087u

Complexes of Ge(IV)- and Sn(IV)-Fluorides with Cyclic and Acyclic Carbenes: Bis(dialkylamino)-difluoromethylenes as Carbene Sources Tobias Böttcher, Bassem S. Bassil, and Gerd-Volker Röschenthaler pp 763–765 DOI: 10.1021/ic202008m

Anion-Controlled Assembly of Four Manganese Ions: Structural, Magnetic, and Electrochemical Properties of Tetramanganese Complexes Stabilized by Xanthene-Bridged Schiff Base Ligands Masakazu Hirotsu, Yuu Shimizu, Naoto Kuwamura, Rika Tanaka, Isamu Kinoshita, Ryoichi Takada, Yoshio Teki, and Hideki Hashimoto pp 766–768 DOI: 10.1021/ic202287k

Switching from Bonding to Nonbonding: Temperature-Dependent Metal Coordination in a Zinc(II) Sulfadiazine Complex Fangfang Pan, Ruimin Wang, and Ulli Englert pp 769–771 DOI: 10.1021/ic202303c

An Organoselenium-Based Highly Sensitive and Selective Fluorescent “Turn-On” Probe for the Hg2+ Ion Abhishek Kumar and Jai Deo Singh pp 772–774 DOI: 10.1021/ic2023902

Ionic Crystals [M3O(OOCC6H5)6(H2O)3]4[α-SiW12O40] (M = Cr, Fe) as Heterogeneous Catalysts for Pinacol Rearrangement Sayaka Uchida, Aldes Lesbani, Yoshiyuki Ogasawara, and Noritaka Mizuno pp 775–777 DOI: 10.1021/ic2025186

Triarylboron-Functionalized Cu(II) Carboxylate Paddlewheel Complexes Barry A. Blight, Alexander F. Stewart, Nan Wang, Jia-sheng Lu, and Suning Wang pp 778–780 DOI: 10.1021/ic202521z

Formation of a Uranium Trithiocarbonate Complex via the Nucleophilic Addition of a Sulfide-Bridged Uranium Complex to CS2 Oanh P. Lam, Ludovic Castro, Boris Kosog, Frank W. Heinemann, Laurent Maron, and Karsten Meyer pp 781–783 DOI: 10.1021/ic202535e

Lanthanide Complexes of Macrocyclic Polyoxovanadates by VO4 Units: Synthesis, Characterization, and Structure Elucidation by X-ray Crystallography and EXAFS Spectroscopy Masaki Nishio, Shinnosuke Inami, Misaki Katayama, Kazuhiko Ozutsumi, and Yoshihito Hayashi pp 784–793 DOI: 10.1021/ic200638f

Siloxanol-Functionalized Copper Iodide Cluster as a Thermochromic Luminescent Building Block Sandrine Perruchas, Nicolas Desboeufs, Sébastien Maron, Xavier F. Le Goff, Alexandre Fargues, Alain Garcia, Thierry Gacoin, and Jean-Pierre Boilot pp 794–798 DOI: 10.1021/ic200672r

Influence of Halogen Atoms on a Homologous Series of Bis-Cyclometalated Iridium(III) Complexes Etienne Baranoff, Basile F. E. Curchod, Filippo Monti, Frédéric Steimer, Gianluca Accorsi, Ivano Tavernelli, Ursula Rothlisberger, Rosario Scopelliti, Michael Grätzel, and Md. Khaja Nazeeruddin pp 799–811 DOI: 10.1021/ic2011474

Highly Selective Mitochondria-Targeting Amphiphilic Silicon(IV) Phthalocyanines with Axially Ligated Rhodamine B for Photodynamic Therapy Zhixin Zhao, Pui-Shan Chan, Hongguang Li, Ka-Leung Wong, Ricky Ngok Shun Wong, Nai-Ki Mak, Jie Zhang, Hoi-Lam Tam, Wai-Yeung Wong, Daniel W. J. Kwong, and Wai-Kwok Wong pp 812–821 DOI: 10.1021/ic201178e

Bis-Cyclometalated Iridium(III) Complexes Bearing Ancillary Guanidinate Ligands. Synthesis, Structure, and Highly Efficient Electroluminescence Virendra Kumar Rai, Masayoshi Nishiura, Masanori Takimoto, Shanshan Zhao, Yu Liu, and Zhaomin Hou pp 822–835 DOI: 10.1021/ic201217a

Intramolecular Interactions in Crystals of Tris(2,6-diisopropylphenoxy)silanethiol and Its Sodium Salts Anna Dołęga, Wojciech Marynowski, Katarzyna Baranowska, Maciej Śmiechowski, and Janusz Stangret pp 836–843 DOI: 10.1021/ic2013073

Sonochemical Synthesis and Properties of Nanoparticles of FeSbO4 Pratanu Nag, Suparna Banerjee, Yongmoon Lee, Ali Bumajdad, Yongjae Lee, and P. Sujatha Devi pp 844–850 DOI: 10.1021/ic201353u

Stannylenes: Structures, Electron Affinities, Ionization Energies, and Singlet–Triplet Gaps of SnX2/SnXY and XSnR/SnR2/RSnR′ Species (X; Y = H, F, Cl, Br, I, and R; R′ = CH3, SiH3, GeH3, SnH3) Ashwini Bundhun, Ponnadurai Ramasami, Peter P. Gaspar, and Henry F. Schaefer, III pp 851–863 DOI: 10.1021/ic201389y

Crystal Structure, Fluorescence, and Nanostructuration Studies of the First ZnII Anthracene-Based Curcuminoid Núria Aliaga-Alcalde, Laura Rodrı́guez, Marilena Ferbinteanu, Petra Höfer, and Thomas Weyhermüller pp 864–873 DOI: 10.1021/ic201420d

The Intramolecular Rearrangement of Phosphinohydrazides [R′2P–NR–NR–M] → [RN═PR′2–NR–M]: General Rules and Exceptions. Transformations of Bulky Phosphinohydrazines (R–NH–N(PPh2)2, R = tBu, Ph2P) Alexander N. Kornev, Vyacheslav V. Sushev, Yulia S. Panova, Natalia V. Belina, Olga V. Lukoyanova, Georgy K. Fukin, Sergey Y. Ketkov, Gleb A. Abakumov, Peter Lönnecke, and Evamarie Hey-Hawkins pp 874–881 DOI: 10.1021/ic201617p

Neutral Acyclic Anion Receptor with Thiadiazole Spacer: Halide Binding Study and Halide-Directed Self-Assembly in the Solid State Arghya Basu and Gopal Das pp 882–889 DOI: 10.1021/ic201656y

Tuning of Redox Potentials by Introducing a Cyclometalated Bond to Bis-tridentate Ruthenium(II) Complexes Bearing Bis(N-methylbenzimidazolyl)benzene or -pyridine Ligands Wen-Wen Yang, Yu-Wu Zhong, Shinpei Yoshikawa, Jiang-Yang Shao, Shigeyuki Masaoka, Ken Sakai, Jiannian Yao, and Masa-aki Haga pp 890–899 DOI: 10.1021/ic2016885

Ligand Exchange and Spin State Equilibria of FeII(N4Py) and Related Complexes in Aqueous Media Apparao Draksharapu, Qian Li, Hella Logtenberg, Tieme A. van den Berg, Auke Meetsma, J. Scott Killeen, Ben L. Feringa, Ronald Hage, Gerard Roelfes, and Wesley R. Browne pp 900–913 DOI: 10.1021/ic201879b

A Novel PbS Hierarchical Superstructure Guided by the Balance between Thermodynamic and Kinetic Control via a Single-Source Precursor Route Xiaochuan Duan, Jianmin Ma, Yan Shen, and Wenjun Zheng pp 914–919 DOI: 10.1021/ic201889n

Crystal Growth, Structure, and Physical Properties of LnCu2(Al,Si)5 (Ln = La and Ce) W. Adam Phelan, Michael J. Kangas, Brenton L. Drake, Liang L. Zhao, Jiakui K. Wang, J. F. DiTusa, Emilia Morosan, and Julia Y. Chan pp 920–927 DOI: 10.1021/ic2019378

Labile Zinc-Assisted Biological Phosphate Chemosensing and Related Molecular Logic Gating Interpretations Kibong Kim, Yonghwang Ha, Léo Kaufman, and David G. Churchill pp 928–938 DOI: 10.1021/ic201948c

Phosphodiester Cleavage Properties of Copper(II) Complexes of 1,4,7-Triazacyclononane Ligands Bearing Single Alkyl Guanidine Pendants Linda Tjioe, Tanmaya Joshi, Craig M. Forsyth, Boujemaa Moubaraki, Keith S. Murray, Joël Brugger, Bim Graham, and Leone Spiccia pp 939–953 DOI: 10.1021/ic2019814

Pyridine Analogues of the Antimetastatic Ru(III) Complex NAMI-A Targeting Non-Covalent Interactions with Albumin Michael I. Webb, Ryan A. Chard, Yaser M. Al-Jobory, Michael R. Jones, Edwin W. Y. Wong, and Charles J. Walsby pp 954–966 DOI: 10.1021/ic202029e

Quantification of the Trans Influence in Hypervalent Iodine Complexes P. K. Sajith and Cherumuttathu H. Suresh pp 967–977 DOI: 10.1021/ic202047g

In Solution Sensitization of Er(III) Luminescence by the 4-Tetrathiafulvalene-2,6-pyridinedicarboxylic Acid Dimethyl Antenna Ligand Fabrice Pointillart, Adrien Bourdolle, Thomas Cauchy, Olivier Maury, Yann Le Gal, Stéphane Golhen, Olivier Cador, and Lahcène Ouahab pp 978–984 DOI: 10.1021/ic202045a

Antisymmetric Exchange in Triangular Tricopper(II) Complexes: Correlation among Structural, Magnetic, and Electron Paramagnetic Resonance Parameters Sacramento Ferrer, Francesc Lloret, Emilio Pardo, Juan Modesto Clemente-Juan, Malva Liu-González, and Santiago García-Granda pp 985–1001 DOI: 10.1021/ic2020034

Reactivity of Digermylenes toward Potassium Graphite: Synthesis and Characterization of Germylidenide Anions Siew-Peng Chia, Hui-Xian Yeong, and Cheuk-Wai So pp 1002–1010 DOI: 10.1021/ic202138t

Experimental Evidence and DFT Studies of Next-Nearest-Neighbor Magnetic Interactions through Diamagnetic 3d and 4d Ions Jean-Pierre Costes, Carine Duhayon, Laure Vendier, Enrique Colacio, Antonio J. Mota Ávila, and Jose Suarez Varela pp 1011–1019 DOI: 10.1021/ic202157q

Effects of the Alkali-Metal Cation Size on Molecular and Extended Structures: Formation of Coordination Polymers and Hybrid Materials in the Homologous Series [(4-Et-C6H4OM)·(diox)n], M = Li, Na, K, Rb, Cs Jeffrey A. Bertke, Allen G. Oliver, and Kenneth W. Henderson pp 1020–1027 DOI: 10.1021/ic202158m

Lanthanide Complexes of Tritopic Bis(hydrazone) Ligands: Single-Molecule Magnet Behavior in a Linear DyIII3 Complex Muhammad U. Anwar, Santokh S. Tandon, Louise N. Dawe, Fatemah Habib, Muralee Murugesu, and Laurence K. Thompson pp 1028–1034 DOI: 10.1021/ic2022006

LiGaGe2Se6: A New IR Nonlinear Optical Material with Low Melting Point Dajiang Mei, Wenlong Yin, Kai Feng, Zheshuai Lin, Lei Bai, Jiyong Yao, and Yicheng Wu pp 1035–1040 DOI: 10.1021/ic202202j

Novel Stannatranes of the Type N(CH2CMe2O)3SnX (X = OR, SR, OC(O)R, SP(S)Ph2, Halogen). Synthesis, Molecular Structures, and Electrochemical Properties Thomas Zöller, Christina Dietz, Ljuba Iovkova-Berends, Olga Karsten, Gerrit Bradtmöller, Ann-Kristin Wiegand, Yu Wang, Viatcheslav Jouikov, and Klaus Jurkschat pp 1041–1056 DOI: 10.1021/ic202179e

Investigation of the Reactivity between a Ruthenium Hexacationic Prism and Biological Ligands Lydia E. H. Paul, Bruno Therrien, and Julien Furrer pp 1057–1067 DOI: 10.1021/ic2021935

Copper(II) Carboxylate Dimers Prepared from Ligands Designed to Form a Robust π···π Stacking Synthon: Supramolecular Structures and Molecular Properties Daniel L. Reger, Agota Debreczeni, and Mark D. Smith , Julia Jezierska , Andrew Ozarowski pp 1068–1083 DOI: 10.1021/ic202198k

Tris(5-methylpyrazolyl)methane: Synthesis and Properties of Its Iron(II) Complex Margaret A. Goodman, Alexander Y. Nazarenko, Barbara J. Casavant, Zhanjie Li, William W. Brennessel, Michael J. DeMarco, Gen Long, and M. Scott Goodman pp 1084–1093 DOI: 10.1021/ic2022038

Sr2GaScO5, Sr10Ga6Sc4O25, and SrGa0.75Sc0.25O2.5: a Play in the Octahedra to Tetrahedra Ratio in Oxygen-Deficient Perovskites Sergey V. Chernov, Yuri A. Dobrovolsky, Sergey Ya. Istomin, Evgeny V. Antipov, Jekabs Grins, Gunnar Svensson, Nadezhda V. Tarakina, Artem M. Abakumov, Gustaaf Van Tendeloo, Sten G. Eriksson, and Seikh M. H. Rahman pp 1094–1103 DOI: 10.1021/ic202236h

Time-Dependent Control of Hole-Opening Degree of Porous ZnO Hollow Microspheres Nirmalya Tripathy, Rafiq Ahmad, Han-Sol Jeong, and Yoon-Bong Hahn pp 1104–1110 DOI: 10.1021/ic2022598

The Series of Molecular Conductors and Superconductors ET4[AFe(C2O4)3]·PhX (ET = bis(ethylenedithio)tetrathiafulvalene; (C2O4)2– = oxalate; A+ = H3O+, K+; X = F, Cl, Br, and I): Influence of the Halobenzene Guest Molecules on the Crystal Structure and Superconducting Properties Eugenio Coronado, Simona Curreli, Carlos Giménez-Saiz, and Carlos J. Gómez-García pp 1111–1126 DOI: 10.1021/ic202269x

Binary Group 15 Polyazides. Structural Characterization of [Bi(N3)4]−, [Bi(N3)5]2–, [bipy·Bi(N3)5]2–, [Bi(N3)6]3–, bipy·As(N3)3, bipy·Sb(N3)3, and [(bipy)2·Bi(N3)3]2 and on the Lone Pair Activation of Valence Electrons Ralf Haiges, Martin Rahm, David A. Dixon, Edward B. Garner, III, and Karl O. Christe pp 1127–1141 DOI: 10.1021/ic202307a

Sensitization of Lanthanoid Luminescence by Organic and Inorganic Ligands in Lanthanoid-Organic-Polyoxometalates Chris Ritchie, Valérie Baslon, Evan G. Moore, Christian Reber, and Colette Boskovic pp 1142–1151 DOI: 10.1021/ic202349u

Synthesis and Crystal Structure of an Oxovanadium(IV) Complex with a Pyrazolone Ligand and Its Use as a Heterogeneous Catalyst for the Oxidation of Styrene under Mild Conditions Sanjay Parihar, Soyeb Pathan, R. N. Jadeja, Anjali Patel, and Vivek K. Gupta pp 1152–1161 DOI: 10.1021/ic202396q

Formation of Phosphino-Substituted Isocyanate by Reaction of CO2 with Group 2 Complexes Based on the (Me3Si)(i-Pr2P)NH Ligand Diane A. Dickie, Kevin B. Gislason, and Richard A. Kemp pp 1162–1169 DOI: 10.1021/ic202399z

2-Aminoisobutyric Acid in Co(II) and Co(II)/Ln(III) Chemistry: Homometallic and Heterometallic Clusters George J. Sopasis, Maria Orfanoudaki, Pavlos Zarmpas, Aggelos Philippidis, Milosz Siczek, Tadeusz Lis, James R. O’Brien, and Constantinos J. Milios pp 1170–1179 DOI: 10.1021/ic2024007

Role of the Sintering Temperature and Doping Level in the Structural and Spectral Properties of Eu-Doped Nanocrystalline YVO4 R. J. Wiglusz, A. Bednarkiewicz, and W. Strek pp 1180–1186 DOI: 10.1021/ic202444s

Evaluation of Donor and Steric Properties of Anionic Ligands on High Valent Transition Metals Stephen A. DiFranco, Nicholas A. Maciulis, Richard J. Staples, Rami J. Batrice, and Aaron L. Odom pp 1187–1200 DOI: 10.1021/ic202524r

Issue 03

In Situ Formed White-Light-Emitting Lanthanide–Zinc–Organic Frameworks Shu-Mu Li, Xiang-Jun Zheng, Da-Qiang Yuan, Ayjamal Ablet, and Lin-Pei Jin pp 1201–1203 DOI: 10.1021/ic201425v

Ru–OSO Coordination Photogenerated at 100 K in Tetraammineaqua(sulfur dioxide)ruthenium(II) (±)-Camphorsulfonate Anthony E. Phillips, Jacqueline M. Cole, Thierry d’Almeida, and Kian Sing Low pp 1204–1206 DOI: 10.1021/ic2021808

Modulation of Luminescence by Subtle Anion–Cation and Anion−π Interactions in a Trigonal AuI···CuI Complex Kelly Chen, Christoph E. Strasser, Jennifer C. Schmitt, Jason Shearer, and Vincent J. Catalano pp 1207–1209 DOI: 10.1021/ic2023192

Post-Protein-Binding Reactivity and Modifications of the fac-[Re(CO)3]+ Core Fabio Zobi and Bernhard Spingler pp 1210–1212 DOI: 10.1021/ic2023314

A Sensitive and Selective Fluorescence Sensor for the Detection of Arsenic(III) in Organic Media Vivian C. Ezeh and Todd C. Harrop pp 1213–1215 DOI: 10.1021/ic2023715

Slow Relaxation of the Magnetization in a 4,2-Wavelike FeIII2CoII Heterobimetallic Chain Luminita Marilena Toma, Catalina Ruiz-Pérez, Francesc Lloret, and Miguel Julve pp 1216–1218 DOI: 10.1021/ic202410t

A Wheel-Shaped Indium–Telluride Nanocluster [In18Te30(dach)6]6–: Its Formation and Structure Yu-Hong Wang, Wen Luo, Jian-Bing Jiang, Guo-Qing Bian, Qin-Yu Zhu, and Jie Dai pp 1219–1221 DOI: 10.1021/ic202490q

First Total H+/Li+ Ion Exchange in Garnet-Type Li5La3Nb2O12 Using Organic Acids and Studies on the Effect of Li Stuffing Lina Truong and Venkataraman Thangadurai pp 1222–1224 DOI: 10.1021/ic202491m

Synthesis and Structure of Distanna and Tristanna Ansa Half-Sandwich Complexes of Ruthenium and Nickel Holger Braunschweig, Rainer Dörfler, Kai Hammond, Thomas Kramer, Jan Mies, Krzysztof Radacki, and Marius Schäfer pp 1225–1227 DOI: 10.1021/ic202512y

Ir3Co6 and Co3Fe3 Dithiolene Cluster Complexes: Multiple Metal–Metal Bond Formation and Correlation between Structure and Internuclear Electronic Communication Satoru Tsukada, Yusuke Shibata, Ryota Sakamoto, Tetsuya Kambe, Tomoji Ozeki, and Hiroshi Nishihara pp 1228–1230 DOI: 10.1021/ic202548g

Counterion Influence on the Vibrational Wavenumbers in Ternary and Quaternary Metal Hydride Salts, A2MH6 (A = Alkali Metal, Alkaline Earth, and Lanthanides; M = Ir, Fe, Ru, Os, Pt, Mn) Denis F. R. Gilson and Ralph O. Moyer, Jr. pp 1231–1232 DOI: 10.1021/ic202534p

The First {Dy4} Single-Molecule Magnet with a Toroidal Magnetic Moment in the Ground State Peng-Hu Guo, Jun-Liang Liu, Ze-Min Zhang, Liviu Ungur, Liviu F. Chibotaru, Ji-Dong Leng, Fu-Sheng Guo, and Ming-Liang Tong pp 1233–1235 DOI: 10.1021/ic202650f

Synthesis, Characterization, and Reactivity of a Novel μ-η2:η2-Diselenidodicopper(II) Complex Jun Matsumoto, Yuji Kajita, and Hideki Masuda pp 1236–1238 DOI: 10.1021/ic202690e

Molybdenum(VI) Complexes of a 2,2′-Biphenyl-bridged Bis(amidophenoxide): Competition between Metal–Ligand and Metal–Amidophenoxide π Bonding Jason A. Kopec, Sukesh Shekar, and Seth N. Brown pp 1239–1250 DOI: 10.1021/ic201736h

Metrical Oxidation States of 2-Amidophenoxide and Catecholate Ligands: Structural Signatures of Metal–Ligand π Bonding in Potentially Noninnocent Ligands Seth N. Brown pp 1251–1260 DOI: 10.1021/ic202764j

Role of Ruthenium Oxidation States in Ligand-to-Ligand Charge Transfer Processes Cristina L. Ramírez, César N. Pegoraro, Oscar Filevich, Andrea Bruttomeso, Roberto Etchenique, and Alejandro R. Parise pp 1261–1268 DOI: 10.1021/ic200966f

Topotactic Oxidation Pathway of ScTiO3 and High-Temperature Structure Evolution of ScTiO3.5 and Sc4Ti3O12-Type Phases Shahid P. Shafi, Bradley C. Hernden, Lachlan M. D. Cranswick, Thomas C. Hansen, and Mario Bieringer pp 1269–1277 DOI: 10.1021/ic201034x

Metal-Assisted Ring-Closing/Opening Process of a Chiral Tetrahydroquinazoline Ana M. García-Deibe, Jesús Sanmartín-Matalobos, Concepción González-Bello, Emilio Lence, Cristina Portela-García, Luis Martínez-Rodríguez, and Matilde Fondo pp 1278–1293 DOI: 10.1021/ic2017038

Photophysical Properties of {[Au(CN)2]−}2 Dimers Trapped in a Supramolecular Electron-Acceptor Organic Framework Ahmed S. Abouelwafa, Christopher E. Anson, Andreas Hauser, Howard H. Patterson, François Baril-Robert, Xiaobo Li, and Annie K. Powell pp 1294–1301 DOI: 10.1021/ic201109u

Understanding the “Tailoring Synthesis” of CdS Nanorods by O2 Guoxin Zhang, Peilei He, Xiuju Ma, Yun Kuang, Junfeng Liu, and Xiaoming Sun pp 1302–1308 DOI: 10.1021/ic201119c

Tuning of the Emission Efficiency and HOMO–LUMO Band Gap for Ester-Functionalized {Al(salophen)(H2O)2}+ Blue Luminophors Virginie Béreau, Carine Duhayon, Alix Sournia-Saquet, and Jean-Pascal Sutter pp 1309–1318 DOI: 10.1021/ic201208c

Ligand-Bridged Dinuclear Cyclometalated IrIII Complexes: From Metallamacrocycles to Discrete Dimers Vadapalli Chandrasekhar, Tanima Hajra, Jitendra K. Bera, S.M. Wahidur Rahaman, Nisa Satumtira, Oussama Elbjeirami, and Mohammad A. Omary pp 1319–1329 DOI: 10.1021/ic2012952

Ionic Crystals of {[Ni(phen)3]2Ge4S10}·xSol, Showing Solid-State Solvatochromism and Rapid Solvent-Induced Recrystallization Wen-Qin Mu, Qin-Yu Zhu, Li-Sheng You, Xu Zhang, Wen Luo, Guo-Qing Bian, and Jie Dai pp 1330–1335 DOI: 10.1021/ic2014682

Formation of Soluble Hexanuclear Neptunium(IV) Nanoclusters in Aqueous Solution: Growth Termination of Actinide(IV) Hydrous Oxides by Carboxylates Koichiro Takao, Shinobu Takao, Andreas C. Scheinost, Gert Bernhard, and Christoph Hennig pp 1336–1344 DOI: 10.1021/ic201482n

Electronic Structure of the Water Oxidation Catalyst cis,cis-[(bpy)2(H2O)RuIIIORuIII(OH2)(bpy)2]4+, The Blue Dimer Jonah W. Jurss, Javier J. Concepcion, Jennifer M. Butler, Kristin M. Omberg, Luis M. Baraldo, Darla Graff Thompson, Estelle L. Lebeau, Brooks Hornstein, Jon R. Schoonover, Hershel Jude, Joe D. Thompson, Dana M. Dattelbaum, Reginaldo C. Rocha, Joseph L. Templeton, and Thomas J. Meyer pp 1345–1358 DOI: 10.1021/ic201521w

Nuclear Resonance Vibrational Spectra of Five-Coordinate Imidazole-Ligated Iron(II) Porphyrinates Chuanjiang Hu, Alexander Barabanschikov, Mary K. Ellison, Jiyong Zhao, E. Ercan Alp, Wolfgang Sturhahn, Marek Z. Zgierski, J. Timothy Sage, and W. Robert Scheidt pp 1359–1370 DOI: 10.1021/ic201580v

Platinum-Modified Adenines: Unprecedented Protonation Behavior Revealed by NMR Spectroscopy and Relativistic Density-Functional Theory Calculations Jan Vícha, Gabriel Demo, and Radek Marek pp 1371–1379 DOI: 10.1021/ic201595e

K2MIII2(MVIO4)(PO4)2 (MIII = Fe, Sc; MVI = Mo, W), Novel Members of the Lagbeinite-Related Family: Synthesis, Structure, and Magnetic Properties Nikolay S. Slobodyanik, Kateryna V. Terebilenko, Ivan V. Ogorodnyk, Igor V. Zatovsky, Maksym Seredyuk, Vyacheslav N. Baumer, and Philipp Gütlich pp 1380–1385 DOI: 10.1021/ic201575v

Copper(II)-Binding Ability of Stereoisomeric cis- and trans-2-Aminocyclohexanecarboxylic Acid–l-Phenylalanine Dipeptides. A Combined CW/Pulsed EPR and DFT Study Nóra V. Nagy, Sabine Van Doorslaer, Terézia Szabó-Plánka, Senne Van Rompaey, Andrea Hamza, Ferenc Fülöp, Gábor K. Tóth, and Antal Rockenbauer pp 1386–1399 DOI: 10.1021/ic2016116

1H NMR, Electron Paramagnetic Resonance, and Density Functional Theory Study of Dinuclear Pentaammineruthenium Dicyanamidobenzene Complexes Mark L. Naklicki, Serge I. Gorelsky, Wolfgang Kaim, Biprajit Sarkar, and Robert J. Crutchley pp 1400–1407 DOI: 10.1021/ic2016403

Identity of the Exchangeable Sulfur-Containing Ligand at the Mo(V) Center of R160Q Human Sulfite Oxidase Eric L. Klein, Arnold M. Raitsimring, Andrei V. Astashkin, Asha Rajapakshe, Kayunta Johnson-Winters, Anna R. Arnold, Alexey Potapov, Daniella Goldfarb, and John H. Enemark pp 1408–1418 DOI: 10.1021/ic201643t

Biologically Compatible, Phosphorescent Dimetallic Rhenium Complexes Linked through Functionalized Alkyl Chains: Syntheses, Spectroscopic Properties, and Applications in Imaging Microscopy Rebeca G. Balasingham, Flora L. Thorp-Greenwood, Catrin F. Williams, Michael P. Coogan, and Simon J. A. Pope pp 1419–1426 DOI: 10.1021/ic201654d

Lanthanide Paramagnetic Probes for NMR Spectroscopic Studies of Fast Molecular Conformational Dynamics and Temperature Control. Effective Six-Site Proton Exchange in 18-Crown-6 by Exchange Spectroscopy Sergey P. Babailov pp 1427–1433 DOI: 10.1021/ic201662q

“yl”-Oxygen Exchange in Uranyl(VI) Ion: A Mechanism Involving (UO2)2(μ-OH)22+ via U–Oyl–U Bridge Formation Satoru Tsushima pp 1434–1439 DOI: 10.1021/ic201679e

Molybdenum(VI) Dioxo and Oxo-Imido Complexes of Fluorinated β-Ketiminato Ligands and Their Use in OAT Reactions Manuel Volpe and Nadia C. Mösch-Zanetti pp 1440–1449 DOI: 10.1021/ic201681u

Redox Non-innocence of Thioether Crowns: Elucidation of the Electronic Structure of the Mononuclear Pd(III) Complexes [Pd([9]aneS3)2]3+ and [Pd([18]aneS6)]3+ Emma Stephen, Alexander J. Blake, Emma Carter, David Collison, E. Stephen Davies, Ruth Edge, William Lewis, Damien M. Murphy, Claire Wilson, Robert O. Gould, Alan J. Holder, Jonathan McMaster, and Martin Schröder pp 1450–1461 DOI: 10.1021/ic2017006

Synthesis and Structural Investigation of a Unique Columnar Phase in the Bi2O3–TeO2–V2O5 System Vaishali Thakral, Neha Bhardwaj, and S. Uma pp 1462–1470 DOI: 10.1021/ic2017159

Distinct Photophysics of the Isomers of B18H22 Explained Michael G. S. Londesborough, Drahomír Hnyk, Jonathan Bould, Luis Serrano-Andrés, Vicenta Sauri, Josep M. Oliva, Pavel Kubát, Tomáš Polívka, and Kamil Lang pp 1471–1479 DOI: 10.1021/ic201726k

A Sterically Demanding Iminopyridine Ligand Affords Redox-Active Complexes of Aluminum(III) and Gallium(III) Thomas W. Myers and Louise A. Berben pp 1480–1488 DOI: 10.1021/ic201729b

3-D Germanate Constructed with Ge7 Cluster Layers and Nickel–Ethanolamine Linkage Wen Luo, Wen-Qin Mu, Xu Zhang, Xiang Zhang, Ya-Yang Pu, Qin-Yu Zhu, and Jie Dai pp 1489–1494 DOI: 10.1021/ic201754z

Solvothermal Synthesis of NiCo Alloy Icosahedral Nanocrystals Mingzhu Cheng, Ming Wen, Shiqing Zhou, Qingsheng Wu, and Baolei Sun pp 1495–1500 DOI: 10.1021/ic201763j

Derivatization of Bichromic Cyclometalated Ru(II) Complexes with Hydrophobic Substituents Kiyoshi C. D. Robson, Bryan D. Koivisto, and Curtis P. Berlinguette pp 1501–1507 DOI: 10.1021/ic201768e

Heterodinuclear Metal Arrangement in a Flat Macrocycle with Two Chemically- Equivalent Metal Chelating Sites Masumi Kuritani, Shohei Tashiro, and Mitsuhiko Shionoya pp 1508–1515 DOI: 10.1021/ic201803c

Role of π-Acceptor Effects in Controlling the Lability of Novel Monofunctional Pt(II) and Pd(II) Complexes: Crystal Structure of [Pt(tripyridinedimethane)Cl]Cl Biljana Petrović, Živadin D. Bugarčić, Anne Dees, Ivana Ivanović-Burmazović, Frank W. Heinemann, Ralph Puchta, Stephan N. Steinmann, Clemence Corminboeuf, and Rudi van Eldik pp 1516–1529 DOI: 10.1021/ic201807a

Substituent Effects on Core Structures and Heterogeneous Catalytic Activities of MnIII(μ-O)2MnIV Dimers with 2,2′:6′,2″-Terpyridine Derivative Ligands for Water Oxidation Hirosato Yamazaki, Satoshi Igarashi, Toshi Nagata, and Masayuki Yagi pp 1530–1539 DOI: 10.1021/ic201797h

Photochromogenic Nanosheet Crystallites of Tungstate with a 2D Bronze Structure Katsutoshi Fukuda, Kosho Akatsuka, Yasuo Ebina, Minoru Osada, Wataru Sugimoto, Mutsumi Kimura, and Takayoshi Sasaki pp 1540–1543 DOI: 10.1021/ic201834y

Reactivity of Divalent Germanium Alkoxide Complexes Is in Sharp Contrast to the Heavier Tin and Lead Analogues Lorenzo Ferro, Peter B. Hitchcock, Martyn P. Coles, and J. Robin Fulton pp 1544–1551 DOI: 10.1021/ic201841m

Electrochemical Illumination of Intramolecular Communication in Ferrocene-Containing tris-β-Diketonato Aluminum(III) Complexes; Cytotoxicity of Al(FcCOCHCOCF3)3 Henno J. Gericke, Alfred J. Muller, and Jannie C. Swarts pp 1552–1561 DOI: 10.1021/ic201849u

Heptabismuthate [Bi7I24]3–: A Main Group Element Anderson-Type Structure and Its Relationships with the Polyoxometalates Kirill Yu. Monakhov, Christophe Gourlaouen, Roberto Pattacini, and Pierre Braunstein pp 1562–1568 DOI: 10.1021/ic201859c

Synthesis, Magnetostructural Correlation, and Catalytic Promiscuity of Unsymmetric Dinuclear Copper(II) Complexes: Models for Catechol Oxidases and Hydrolases Renata E. H. M. B. Osório, Rosely A. Peralta, Adailton J. Bortoluzzi, Vicente R. de Almeida, Bruno Szpoganicz, Franciele L. Fischer, Hernán Terenzi, Antonio S. Mangrich, Karen Mary Mantovani, Dalva E. C. Ferreira, Willian R. Rocha, Wolfgang Haase, Zbigniew Tomkowicz, Ademir dos Anjos, and Ademir Neves pp 1569–1589 DOI: 10.1021/ic201876k

Charge Delocalization of 1,4-Benzenedicyclometalated Ruthenium: A Comparison between Tris-bidentate and Bis-tridentate Complexes Long-Zhen Sui, Wen-Wen Yang, Chang-Jiang Yao, Hai-Yan Xie, and Yu-Wu Zhong pp 1590–1598 DOI: 10.1021/ic202295b

Monoammoniate of Calcium Amidoborane: Synthesis, Structure, and Hydrogen-Storage Properties Yong Shen Chua, Hui Wu, Wei Zhou, Terrence J. Udovic, Guotao Wu, Zhitao Xiong, Ming Wah Wong, and Ping Chen pp 1599–1603 DOI: 10.1021/ic201898v

Neutral Gold Complexes with Tridentate SNS Thiosemicarbazide Ligands Pedro I. da S. Maia, Hung Huy Nguyen, Daniela Ponader, Adelheid Hagenbach, Silke Bergemann, Ronald Gust, Victor M. Deflon, and Ulrich Abram pp 1604–1613 DOI: 10.1021/ic201905t

Synthesis of Panchromatic Ru(II) Thienyl-Dipyrrin Complexes and Evaluation of Their Light-Harvesting Capacity Guocan Li, Lipika Ray, Elliot N. Glass, Kirill Kovnir, Andrey Khoroshutin, Serge I. Gorelsky, and Michael Shatruk pp 1614–1624 DOI: 10.1021/ic2019204

Synthesis, Molecular and Electronic Structure of UV(O)[N(SiMe3)2]3 Skye Fortier, Jessie L. Brown, Nikolas Kaltsoyannis, Guang Wu, and Trevor W. Hayton pp 1625–1633 DOI: 10.1021/ic201936j

Fluorescence Signaling of Zr4+ by Hydrogen Peroxide Assisted Selective Desulfurization of Thioamide Jiyoung Hwang, Myung Gil Choi, Suyoung Eor, and Suk-Kyu Chang pp 1634–1639 DOI: 10.1021/ic2019428

Syntheses, Structures, and Antimicrobial Activities of Remarkably Light-Stable and Water-Soluble Silver Complexes with Amino Acid Derivatives, Silver(I) N-Acetylmethioninates Noriko Chikaraishi Kasuga, Rie Yoshikawa, Yoshitaka Sakai, and Kenji Nomiya pp 1640–1647 DOI: 10.1021/ic201950p

Highly Efficient Near-Infrared-Emitting Lanthanide(III) Complexes Formed by Heterogeneous Self-Assembly of AgI, LnIII, and Thiacalix[4]arene-p-tetrasulfonate in Aqueous Solution (LnIII = NdIII, YbIII) Nobuhiko Iki, Shouichi Hiro-oka, Teppei Tanaka, Chizuko Kabuto, and Hitoshi Hoshino pp 1648–1656 DOI: 10.1021/ic2019583

Enhanced Catalytic Activity of Zeolite Encapsulated Fe(III)-Schiff-Base Complexes for Oxidative Coupling of 2-Napthol Kusum K. Bania, Dipsikha Bharali, B. Viswanathan, and Ramesh C. Deka pp 1657–1674 DOI: 10.1021/ic201959g

Asymmetrical Diruthenium Complex Bridged by a Redox-Active Ligand Amit Das, Thomas Michael Scherer, Abhishek Dutta Chowdhury, Shaikh M. Mobin, Wolfgang Kaim, and Goutam Kumar Lahiri pp 1675–1684 DOI: 10.1021/ic201975h

Decaborane Thiols as Building Blocks for Self-Assembled Monolayers on Metal Surfaces Jonathan Bould, Jan Macháček, Michael G. S. Londesborough, Ramón Macías, John D. Kennedy, Zdeněk Bastl, Patrick Rupper, and Tomáš Baše pp 1685–1694 DOI: 10.1021/ic202000b

Four Polyanionic Compounds in the K–Au–Ga System: A Case Study in Exploratory Synthesis and of the Art of Structural Analysis Volodymyr Smetana, John D. Corbett, and Gordon J. Miller pp 1695–1702 DOI: 10.1021/ic201999u

Series of Metal Organic Frameworks Assembled from Ln(III), Na(I), and Chiral Flexible-Achiral Rigid Dicarboxylates Exhibiting Tunable UV–vis–IR Light Emission Zakariae Amghouz, Santiago García-Granda, and José R. García , Rute A. S. Ferreira, Luís Mafra, Luis D. Carlos, and João Rocha pp 1703–1716 DOI: 10.1021/ic202020z

Reactivity and Biological Properties of a Series of Cytotoxic PtI2(amine)2 Complexes, Either cis or trans Configured Luigi Messori, Leticia Cubo, Chiara Gabbiani, Amparo Álvarez-Valdés, Elena Michelucci, Giuseppe Pieraccini, Carla Ríos-Luci, Leticia G. León, José M. Padrón, Carmen Navarro-Ranninger, Angela Casini, and Adoración G. Quiroga pp 1717–1726 DOI: 10.1021/ic202036c

Oxyanion-Encapsulated Caged Supramolecular Frameworks of a Tris(urea) Receptor: Evidence of Hydroxide- and Fluoride-Ion-Induced Fixation of Atmospheric CO2 as a Trapped CO32– Anion Sandeep Kumar Dey, Romen Chutia, and Gopal Das pp 1727–1738 DOI: 10.1021/ic2020379

Turning on Red and Near-Infrared Phosphorescence in Octahedral Complexes with Metalated Quinones Aurélie Damas, Barbara Ventura, Jamal Moussa, Alessandra Degli Esposti, Lise-Marie Chamoreau, Andrea Barbieri, and Hani Amouri pp 1739–1750 DOI: 10.1021/ic202021w

CaSO4 and Its Pressure-Induced Phase Transitions. A Density Functional Theory Study Lourdes Gracia, Armando Beltrán, Daniel Errandonea, and Juan Andrés pp 1751–1759 DOI: 10.1021/ic202056b

Reactions of Hydridoirida-β-diketones with Amines or with 2-Aminopyridines: Formation of Hydridoirida-β-ketoimines, PCN Terdentate Ligands, and Acyl Decarbonylation Roberto Ciganda, María A. Garralda, Lourdes Ibarlucea, Claudio Mendicute-Fierro, M. Carmen Torralba, and M. Rosario Torres pp 1760–1768 DOI: 10.1021/ic202065d

Ratiometric Detection of Cr3+ and Hg2+ by a Naphthalimide-Rhodamine Based Fluorescent Probe Prasenjit Mahato, Sukdeb Saha, E. Suresh, Rosa Di Liddo, Pier Paolo Parnigotto, Maria Teresa Conconi, Manoj K. Kesharwani, Bishwajit Ganguly, and Amitava Das pp 1769–1777 DOI: 10.1021/ic202073q

Blue-Emitting Dinuclear N-heterocyclic Dicarbene Gold(I) Complex Featuring a Nearly Unit Quantum Yield Marco Baron, Cristina Tubaro, Andrea Biffis, Marino Basato, Claudia Graiff, Albert Poater, Luigi Cavallo, Nicola Armaroli, and Gianluca Accorsi pp 1778–1784 DOI: 10.1021/ic2020786

Stepwise Formation of Iridium(III) Complexes with Monocyclometalating and Dicyclometalating Phosphorus Chelates Cheng-Huei Lin, Chih-Yuan Lin, Jui-Yi Hung, Yao-Yuan Chang, Yun Chi, Min-Wen Chung, Yuh-Chia Chang, Chun Liu, Hsiao-An Pan, Gene-Hsiang Lee, and Pi-Tai Chou pp 1785–1795 DOI: 10.1021/ic202090j

Cytotoxicity and Hydrolysis of trans-Ti(IV) Complexes of Salen Ligands: Structure–Activity Relationship Studies Avia Tzubery and Edit Y. Tshuva pp 1796–1804 DOI: 10.1021/ic202092u

Neutron Diffraction Study of the Type I Clathrate Ba8AlxSi46–x: Site Occupancies, Cage Volumes, and the Interaction between the Guest and the Host Framework John H. Roudebush, Clarina de la Cruz, Bryan C. Chakoumakos, and Susan M. Kauzlarich pp 1805–1812 DOI: 10.1021/ic202095e

Microwave-Assisted Synthesis of a Series of Lanthanide Metal–Organic Frameworks and Gas Sorption Properties Zu-Jin Lin, Zhen Yang, Tian-Fu Liu, Yuan-Biao Huang, and Rong Cao pp 1813–1820 DOI: 10.1021/ic202082w

Reduction of Terphenyl Co(II) Halide Derivatives in the Presence of Arenes: Insertion of Co(I) into a C–F Bond Hao Lei, James C. Fettinger, and Philip P. Power pp 1821–1826 DOI: 10.1021/ic202116s

27Al and 29Si Solid-State NMR Characterization of Calcium-Aluminosilicate-Hydrate Xiaolin Pardal, Francine Brunet, Thibault Charpentier, Isabelle Pochard, and André Nonat pp 1827–1836 DOI: 10.1021/ic202124x

Host–Guest Supramolecular Interactions in the Coordination Compounds of 4,4′-Azobis(pyridine) with MnX2 (X = NCS–, NCNCN–, and PF6–): Structural Analyses and Theoretical Study Paramita Kar, Rituparna Biswas, Michael G. B. Drew, Antonio Frontera, and Ashutosh Ghosh pp 1837–1851 DOI: 10.1021/ic202129a

UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units Li Wang, Shilie Pan, Lixian Chang, Jianyang Hu, and Hongwei Yu pp 1852–1858 DOI: 10.1021/ic2021337

Zinc-Specific Fluorescent Response of Tris(isoquinolylmethyl)amines (isoTQAs) Yuji Mikata, Keiko Kawata, Satoshi Iwatsuki, and Hideo Konno pp 1859–1865 DOI: 10.1021/ic202159v

Synthesis and Structural Characterization of High Spin M/Cu (M = Mn, Fe) Heterobimetallic and Fe/Cu2 Trimetallic Phosphinoamides Subramaniam Kuppuswamy, Benjamin G. Cooper, Mark W. Bezpalko, Bruce M. Foxman, Tamara M. Powers, and Christine M. Thomas pp 1866–1873 DOI: 10.1021/ic202165z

Variations of Structures and Gas Sorption Properties of Three Coordination Polymers Induced by Fluorine Atom Positions in Azamacrocyclic Ligands Long Jiang, Xian-Rui Meng, Hua Xiang, Ping Ju, Di-Chang Zhong, and Tong-Bu Lu pp 1874–1880 DOI: 10.1021/ic202168r

Cu(I)/O2 Chemistry Using a β-Diketiminate Supporting Ligand Derived from N,N-Dimethylhydrazine: A [Cu3O2]3+ Complex with Novel Reactivity Aalo K. Gupta and William B. Tolman pp 1881–1888 DOI: 10.1021/ic202214c

Substitution Reactions in Dinuclear Ru-Hbpp Complexes: an Evaluation of Through-Space Interactions Nora Planas, Gemma Christian, Stephan Roeser, Elena Mas-Marzá, Mohan-Rao Kollipara, Jordi Benet-Buchholz, Feliu Maseras, and Antoni Llobet pp 1889–1901 DOI: 10.1021/ic202225g

Fully Delocalized (Ethynyl)(vinyl)phenylene Bridged Triruthenium Complexes in up to Five Different Oxidation States Evelyn Wuttke, Florian Pevny, Yves-Marie Hervault, Lucie Norel, Malte Drescher, Rainer F. Winter, and Stéphane Rigaut pp 1902–1915 DOI: 10.1021/ic2022177

Application of Atomic Hirshfeld Surface Analysis to Intermetallic Systems: Is Mn in Cubic CeMnNi4 a Thermoelectric Rattler atom? Mads R. V. Jørgensen, Iben Skovsen, Henrik F. Clausen, Jian-Li Mi, Mogens Christensen, Eiji Nishibori, Mark A. Spackman, and Bo B. Iversen pp 1916–1924 DOI: 10.1021/ic202231k

Polymorphs and Aurophilic Interactions in Colorless Crystals of Au2(μ-1,2 bis-(diphenylarsino)ethane)X2, (X = Cl, Br, I) Sang Ho Lim, Marilyn M. Olmstead, James C. Fettinger, and Alan L. Balch pp 1925–1932 DOI: 10.1021/ic2022165

Gold(I)-Coordination Triggered Multistep and Multiple Photochromic Reactions in Multi-Dithienylethene (DTE) Systems Bin Li, Yu-Hui Wu, Hui-Min Wen, Lin-Xi Shi, and Zhong-Ning Chen pp 1933–1942 DOI: 10.1021/ic202265u

Water versus Acetonitrile Coordination to Uranyl. Effect of Chloride Ligands Michael Bühl, Nicolas Sieffert, Alain Chaumont, and Georges Wipff pp 1943–1952 DOI: 10.1021/ic202270u

Crystal and Magnetic Structures and Magnetic Properties of Selenate Containing Natrochalcite, AIMII2(H3O2)(SeO4)2 Where A = Na or K and M = Mn, Co, or Ni Wassim Maalej, Serge Vilminot, Gilles André, Zakaria Elaoud, Tahar Mhiri, and Mohamedally Kurmoo pp 1953–1962 DOI: 10.1021/ic202273e

1,1-Diamino-2,2-dintroethene (FOX-7) in Copper and Nickel Diamine Complexes and Copper FOX-7 Thao T. Vo, Damon A. Parrish, and Jean’ne M. Shreeve pp 1963–1968 DOI: 10.1021/ic202288t

|(C4NH12)4|[M4Al12P16O64] (M = Co, Zn): New Heteroatom-Containing Aluminophosphate Molecular Sieves with Two Intersecting 8-Ring Channels Zhuo Liu, Xiaowei Song, Jiyang Li, Yi Li, Jihong Yu, and Ruren Xu pp 1969–1974 DOI: 10.1021/ic2022903

Correction to Blue-Light Emission of Cu(I) Complexes and Singlet Harvesting Rafał Czerwieniec, Jiangbo Yu, and Hartmut Yersin pp 1975–1975 DOI: 10.1021/ic202653h

Issue 04

Effect of Water during the Quantitation of Formate in Photocatalytic Studies on CO2 Reduction in Dimethylformamide Avishek Paul, Damian Connolly, Martin Schulz, Mary T. Pryce, and Johannes G. Vos pp 1977–1979 DOI: 10.1021/ic202121s

Fe4 Cluster and a Buckled Macrocycle Complex from the Reduction of [(dmgBF2)2Fe(L)2] (L = MeCN, tBuiNC) Michael J. Rose, Jay R. Winkler, and Harry B. Gray pp 1980–1982 DOI: 10.1021/ic202253v

5d Early-Transition-Metal Corroles: a Trioxo-Bridged Binuclear Tungsten(VI) Derivative Izana Nigel-Etinger, Israel Goldberg, and Zeev Gross pp 1983–1985 DOI: 10.1021/ic202325h

Intrinsic Optical Properties and Divergent Doping Effects of Manganese(II) on Luminescence for Tin(II) Phosphite Grown from a Deep-Eutectic Solvent Hui-Lin Huang, Yei-Chen Lai, Yun-Wei Chiang, and Sue-Lein Wang pp 1986–1988 DOI: 10.1021/ic202419q

Ag(nic)2 (nic = Nicotinate): A Spin-Canted Quasi-2D Antiferromagnet Composed of Square-Planar S = 1/2 AgII Ions Jamie L. Manson, Toby J. Woods, Saul H. Lapidus, Peter W. Stephens, Heather I. Southerland, Vivien S. Zapf, John Singleton, Paul A. Goddard, Tom Lancaster, Andrew J. Steele, and Stephen J. Blundell pp 1989–1991 DOI: 10.1021/ic202600n

Application of 204mPb Perturbed Angular Correlation of γ-rays Spectroscopy in Coordination Chemistry Johan Vibenholt, Magnus Schau-Magnussen, Monika Stachura, Morten J. Bjerrum, Peter W. Thulstrup, Vaida Arcisauskaite, and Lars Hemmingsen pp 1992–1994 DOI: 10.1021/ic202614j

Microporous Zinc Tris[(4-carboxyl)phenylduryl]amine Framework with an Unusual Topological Net for Gas Storage and Separation Yan-Ping He, Yan-Xi Tan, Fei Wang, and Jian Zhang pp 1995–1997 DOI: 10.1021/ic202713e

TCM Active Ingredient Oxoglaucine Metal Complexes: Crystal Structure, Cytotoxicity, and Interaction with DNA Zhen-Feng Chen, Yan-Fang Shi, Yan-Cheng Liu, Xue Hong, Bo Geng, Yan Peng, and Hong Liang pp 1998–2009 DOI: 10.1021/ic200443p

Fine-Tuning the Luminescence and HOMO–LUMO Energy Levels in Tetranuclear Gold(I) Fluorinated Amidinate Complexes Hanan E. Abdou, Ahmed A. Mohamed, José M. López-de-Luzuriaga, Miguel Monge, and John P. Fackler, Jr. pp 2010–2015 DOI: 10.1021/ic2010634

Syntheses, X-ray Crystal Structures, and Optical, Fluorescence, and Nonlinear Optical Characterizations of Diphenylphosphino-Substituted Bithiophenes Qun Zhao, Jason L. Freeman, Jianwei Wang, Yuanli Zhang, Tracy P. Hamilton, Christopher M. Lawson, and Gary M. Gray pp 2016–2030 DOI: 10.1021/ic201309k

Cyclo- and Carbophosphazene-Supported Ligands for the Assembly of Heterometallic (Cu2+/Ca2+, Cu2+/Dy3+, Cu2+/Tb3+) Complexes: Synthesis, Structure, and Magnetism Vadapalli Chandrasekhar, Tapas Senapati, Atanu Dey, Sourav Das, Marguerite Kalisz, and Rodolphe Clérac pp 2031–2038 DOI: 10.1021/ic201463g

Violating the Isolated Pentagon Rule (IPR): Endohedral Non-IPR C98 Cages of Gd2@C98 Xiang Zhao, Wei-Yin Gao, Tao Yang, Jia-Jia Zheng, Le-Sheng Li, Ling He, Rui-Jun Cao, and Shigeru Nagase pp 2039–2045 DOI: 10.1021/ic201585j

Detecting DNA Mismatches with Metallo-Insertors: A Molecular Simulation Study Attilio V. Vargiu and Alessandra Magistrato pp 2046–2057 DOI: 10.1021/ic201659v

Computational Insights into Uranium Complexes Supported by Redox-Active α-Diimine Ligands Giovanni Li Manni, Justin R. Walensky, Steven J. Kraft, William P. Forrest, Lisa M. Pérez, Michael B. Hall, Laura Gagliardi, and Suzanne C. Bart pp 2058–2064 DOI: 10.1021/ic202522w

Spectroscopic and Catalytic Characterization of a Functional FeIIIFeII Biomimetic for the Active Site of Uteroferrin and Protein Cleavage Sarah J. Smith, Rosely A. Peralta, Rafael Jovito, Adolfo Horn, Jr., Adailton J. Bortoluzzi, Christopher J. Noble, Graeme R. Hanson, Robert Stranger, Vidura Jayaratne, Germán Cavigliasso, Lawrence R. Gahan, Gerhard Schenk, Otaciro R. Nascimento, Angélica Cavalett, Tiago Bortolotto, Guilherme Razzera, Hernán Terenzi, Ademir Neves, and Mark J. Riley pp 2065–2078 DOI: 10.1021/ic201711p

Synthesis and Reactivity of an Isolable Cobalt(I) Complex Containing a β-Diketiminate-Based Acyclic Tetradentate Ligand Elodie E. Marlier, Bridget A. Ulrich, and Kristopher McNeill pp 2079–2085 DOI: 10.1021/ic201780c

The X-ray Absorption Spectroscopic Model of the Copper(II) Imidazole Complex Ion in Liquid Aqueous Solution: A Strongly Solvated Square Pyramid Patrick Frank, Maurizio Benfatto, Britt Hedman, and Keith O. Hodgson pp 2086–2096 DOI: 10.1021/ic2017819

Solar Cell Sensitizer Models [Ru(bpy-R)2(NCS)2] Probed by Spectroelectrochemistry Sara Kämper, Alexa Paretzki, Jan Fiedler, Stanislav Záliš, and Wolfgang Kaim pp 2097–2104 DOI: 10.1021/ic201825h

Phosphorescence Imaging of Living Cells with Amino Acid-Functionalized Tris(2-phenylpyridine)iridium(III) Complexes Peter Steunenberg, Albert Ruggi, Nynke S. van den Berg, Tessa Buckle, Joeri Kuil, Fijs W.B. van Leeuwen, and Aldrik H. Velders pp 2105–2114 DOI: 10.1021/ic201860s

Phosphine Coordination to a Cobalt Diimine–Dioxime Catalyst Increases Stability during Light-Driven H2 Production Pan Zhang, Pierre-André Jacques, Murielle Chavarot-Kerlidou, Mei Wang, Licheng Sun, Marc Fontecave, and Vincent Artero pp 2115–2120 DOI: 10.1021/ic2019132

Importance of Halogen···Halogen Contacts for the Structural and Magnetic Properties of CuX2(pyrazine-N,N′-dioxide)(H2O)2 (X = Cl and Br) John A. Schlueter, Hyunsoo Park, Gregory J. Halder, William R. Armand, Cortney Dunmars, Karena W. Chapman, Jamie L. Manson, John Singleton, Ross McDonald, Alex Plonczak, Jinhee Kang, Chaghoon Lee, Myung-Hwan Whangbo, Tom Lancaster, Andrew J. Steele, Isabel Franke, Jack D. Wright, Stephen J. Blundell, Francis L. Pratt, Joseph deGeorge, Mark M. Turnbull, and Christopher P. Landee pp 2121–2129 DOI: 10.1021/ic201924q

Flexible and Dynamic Thermal Behavior of Self-Catenated [{Ni3(H2O)3(Bpa)4}(V6O18)]·8H2O Constructed from 10-c Heterometallic Inorganic–Organic Clusters Roberto Fernández de Luis, José L. Mesa, M. Karmele Urtiaga, Edurne S. Larrea, Teófilo Rojo, and María I. Arriortua pp 2130–2139 DOI: 10.1021/ic201951e

Chiral Cyanide-Bridged CrIII–MnIII Heterobimetallic Chains Based on [(Tp)Cr(CN)3]−: Synthesis, Structures, and Magnetic Properties Min-Xia Yao, Qi Zheng, Xu-Min Cai, Yi-Zhi Li, You Song, and Jing-Lin Zuo pp 2140–2149 DOI: 10.1021/ic201982d

New Fluorogenic Sensors for Hg2+ Ions: Through-Bond Energy Transfer from Pentaquinone to Rhodamine Vandana Bhalla, Roopa, Manoj Kumar, Parduman Raj Sharma, and Tandeep Kaur pp 2150–2156 DOI: 10.1021/ic201990q

Phosphasalen Yttrium Complexes: Highly Active and Stereoselective Initiators for Lactide Polymerization Thi-Phuong-Anh Cao, Antoine Buchard, Xavier F. Le Goff, Audrey Auffrant, and Charlotte K. Williams pp 2157–2169 DOI: 10.1021/ic202015z

Syntheses, Structures, Luminescence, and Magnetic Properties of One-dimensional Lanthanide Coordination Polymers with a Rigid 2,2′-Bipyridine-3,3′,6,6′-tetracarboxylic Acid Ligand Baoming Ji, Dongsheng Deng, Xiao He, Bin Liu, Shaobin Miao, Ning Ma, Weizhou Wang, Liguo Ji, Peng Liu, and Xianfei Li pp 2170–2177 DOI: 10.1021/ic202063h

Accurate Rate Constants for Decomposition of Aqueous Nitrous Acid Mark S. Rayson, John C. Mackie, Eric M. Kennedy, and Bogdan Z. Dlugogorski pp 2178–2185 DOI: 10.1021/ic202081z

Trigonal Bipyramidal Dy5 Cluster Exhibiting Slow Magnetic Relaxation Jun-Bo Peng, Xiang-Jian Kong, Yan-Ping Ren, La-Sheng Long, Rong-Bin Huang, and Lan-Sun Zheng pp 2186–2190 DOI: 10.1021/ic202147h

Rhodium Complexes of a Chelating Ligand with Imidazol-2-ylidene and Pyridin-2-ylidene Donors: The Effect of C-Metalation of Nicotinamide Groups on Uptake of Hydride Ion Alex McSkimming, Graham E. Ball, Mohan M. Bhadbhade, and Stephen B. Colbran pp 2191–2203 DOI: 10.1021/ic202164v

Studies of the Ligand Effect on the Synthesis of Dialuminoxanes by Various β-Diketiminato Ligands Ying Yang, Haipu Li, Chen Wang, and Herbert W. Roesky pp 2204–2211 DOI: 10.1021/ic2021879

Abnormally Long-Range Diamagnetic Anisotropy Induced by Cyclic dδ–pπ π Conjugation within a Six-Membered Dimolybdenum/Chalcogen Ring Zhong Fei Tan, Chun Y. Liu, Ziyun Li, Miao Meng, and Ng Seik Weng pp 2212–2221 DOI: 10.1021/ic2021947

Photocatalyzed Sulfide Oxygenation with Water as the Unique Oxygen Atom Source Pascal Guillo, Olivier Hamelin, Pinar Batat, Gediminas Jonusauskas, Nathan D. McClenaghan, and Stéphane Ménage pp 2222–2230 DOI: 10.1021/ic2022159

Unexpected Reactivity and Coordination in Gallium(III) and Indium(III) Chloride Complexes With Geometrically Constrained Thio- and Selenoether Ligands Kathryn George, Marek Jura, William Levason, Mark E. Light, Luke P. Ollivere, and Gillian Reid pp 2231–2240 DOI: 10.1021/ic202670v

Formation of Crystalline Na2V6O16·3H2O Ribbons into Belts and Rings P. Chithaiah, G. T. Chandrappa, and J. Livage pp 2241–2246 DOI: 10.1021/ic202260w

BaAuxZn13–x: Electron-Poor Cubic NaZn13-Type Intermetallic and Its Ordered Tetragonal Variant Shalabh Gupta and John D. Corbett pp 2247–2253 DOI: 10.1021/ic2022787

Bis(allyl)gallium Cation, Tris(allyl)gallium, and Tetrakis(allyl)gallate: Synthesis, Characterization, and Reactivity Crispin Lichtenberg, Thomas P. Spaniol, and Jun Okuda pp 2254–2262 DOI: 10.1021/ic202293t

Bright Blue Phosphorescence from Cationic Bis-Cyclometalated Iridium(III) Isocyanide Complexes Nail M. Shavaleev, Filippo Monti, Rubén D. Costa, Rosario Scopelliti, Henk J. Bolink, Enrique Ortí, Gianluca Accorsi, Nicola Armaroli, Etienne Baranoff, Michael Grätzel, and Mohammad K. Nazeeruddin pp 2263–2271 DOI: 10.1021/ic202297h

Synthesis and Structure Resolution of RbLaF4 Anne-Laure Rollet, Mathieu Allix, Emmanuel Veron, Michael Deschamps, Valérie Montouillout, Matthew R. Suchomel, Emmanuelle Suard, Maud Barre, Manuel Ocaña, Aymeric Sadoc, Florent Boucher, Catherine Bessada, Dominique Massiot, and Franck Fayon pp 2272–2282 DOI: 10.1021/ic202301e

Solvothermal Synthesis and Characterization of a Series of Lanthanide Thiostannates(IV): The First Examples of Inorganic–Organic Hybrid Cationic Lanthanide Thiostannates(IV) Jian Zhou, Xing Liu, Litao An, Feilong Hu, Wenbin Yan, and Yunyan Zhang pp 2283–2290 DOI: 10.1021/ic2023083

Tuning the Photochromic Properties of Molybdenum Bisphosphonate Polyoxometalates Hani El Moll, Anne Dolbecq, Israël Martyr Mbomekalle, Jérôme Marrot, Philippe Deniard, Rémi Dessapt, and Pierre Mialane pp 2291–2302 DOI: 10.1021/ic202299d

Temperature-Controlled Chiral and Achiral Copper Tetrazolate Metal–Organic Frameworks: Syntheses, Structures, and I2 Adsorption Ping Cui, Lijun Ren, Zhi Chen, Huancheng Hu, Bin Zhao, Wei Shi, and Peng Cheng pp 2303–2310 DOI: 10.1021/ic2023105

Expansion of Antimonato Polyoxovanadates with Transition Metal Complexes: (Co(N3C5H15)2)2[{Co(N3C5H15)2}V15Sb6O42(H2O)]·5H2O and (Ni(N3C5H15)2)2[{Ni(N3C5H15)2}V15Sb6O42(H2O)]·8H2O Elena Antonova, Christian Näther, Paul Kögerler, and Wolfgang Bensch pp 2311–2317 DOI: 10.1021/ic2023117

Double Sandwich Polyoxometalate and Its Fe(III) Substituted Derivative, [As2Fe5Mo21O82]17– and [As2Fe6Mo20O80(H2O)2]16– Xiangqian Dong, Yanping Zhang, Bin Liu, Yanzhong Zhen, Huaiming Hu, and Ganglin Xue pp 2318–2324 DOI: 10.1021/ic202314g

Dual-Functional Gadolinium-Based Copper(II) Probe for Selective Magnetic Resonance Imaging and Fluorescence Sensing Xiaolin Zhang, Xu Jing, Tao Liu, Gang Han, Huaqiang Li, and Chunying Duan pp 2325–2331 DOI: 10.1021/ic202322f

FTIR Study of Manganese Dimers with Carboxylate Donors As Model Complexes for the Water Oxidation Complex in Photosystem II Gustav Berggren, Magnus F. Anderlund, Stenbjörn Styring, and Anders Thapper pp 2332–2337 DOI: 10.1021/ic202323b

Mixed-Valence Nickel–Iron Dithiolate Models of the [NiFe]-Hydrogenase Active Site David Schilter, Mark J. Nilges, Mrinmoy Chakrabarti, Paul A. Lindahl, Thomas B. Rauchfuss, and Matthias Stein pp 2338–2348 DOI: 10.1021/ic202329y

Oxothiomolybdenum Derivatives of the Superlacunary Crown Heteropolyanion {P8W48}: Structure of [K4{Mo4O4S4(H2O)3(OH)2}2(WO2)(P8W48O184)]30– and Studies in Solution Vladimir S. Korenev, Sébastien Floquet, Jérôme Marrot, Mohamed Haouas, Israël-Martyr Mbomekallé, Francis Taulelle, Maxim N. Sokolov, Vladimir P. Fedin, and Emmanuel Cadot pp 2349–2358 DOI: 10.1021/ic202346r

Linkage Isomerism in Coordination Polymers Samia Benmansour, Fatima Setifi, Smail Triki, and Carlos J. Gómez-García pp 2359–2365 DOI: 10.1021/ic202361p

Synthesis of Alkaline Earth Diazenides MAEN2 (MAE = Ca, Sr, Ba) by Controlled Thermal Decomposition of Azides under High Pressure Sebastian B. Schneider, Rainer Frankovsky, and Wolfgang Schnick pp 2366–2373 DOI: 10.1021/ic2023677

Unusual Cationic Tris(Dimethylsulfide)-Substituted closo-Boranes: Preparation and Characterization of [1,7,9-(Me2S)3-B12H9] BF4 and [1,2,10-(Me2S)3-B10H7] BF4 Ewan J. M. Hamilton, Hoitung T. Leung, Roman G. Kultyshev, Xuenian Chen, Edward A. Meyers, and Sheldon G. Shore pp 2374–2380 DOI: 10.1021/ic2023709

Diversity of Lanthanide(III)–Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties Qing-Yan Liu, Wu-Fang Wang, Yu-Ling Wang, Zeng-Mei Shan, Ming-Sheng Wang, and Jinkui Tang pp 2381–2392 DOI: 10.1021/ic2023727

Evaluating the Identity and Diiron Core Transformations of a (μ-Oxo)diiron(III) Complex Supported by Electron-Rich Tris(pyridyl-2-methyl)amine Ligands Loi H. Do, Genqiang Xue, Lawrence Que, Jr., and Stephen J. Lippard pp 2393–2402 DOI: 10.1021/ic202379b

Uranyl Peroxide Oxalate Cage and Core–Shell Clusters Containing 50 and 120 Uranyl Ions Jie Ling, Jie Qiu, and Peter C. Burns pp 2403–2408 DOI: 10.1021/ic202380g

Role of Bond Strength on the Lattice Thermal Expansion and Oxide Ion Conductivity in Quaternary Pyrochlore Solid Solutions A. N. Radhakrishnan, P. Prabhakar Rao, S. K. Mahesh, D. S. Vaisakhan Thampi, and Peter Koshy pp 2409–2419 DOI: 10.1021/ic202383f

Solid-State Energetics and Electrostatics: Madelung Constants and Madelung Energies Leslie Glasser pp 2420–2424 DOI: 10.1021/ic2023852

Synthesis and Characterization of β-Diketiminate Germanium(II) Compounds Ying Yang, Na Zhao, Yile Wu, Hongping Zhu, and Herbert W. Roesky pp 2425–2431 DOI: 10.1021/ic202388d

Metal Site-Mediated, Thermally Induced Structural Changes in Cr6+-Silicalite-2 (MEL) Molecular Sieves Yuchuan Tao, Adrian Lita, Lambertus J. van de Burgt, Haidong Zhou, and A. E. Stiegman pp 2432–2437 DOI: 10.1021/ic202401a

A 3D Polar Nanotubular Coordination Polymer with Dynamic Structural Transformation and Ferroelectric and Nonlinear-Optical Properties Lina Li, Jingxin Ma, Cheng Song, Tianliang Chen, Zhihua Sun, Shuyun Wang, Junhua Luo, and Maochun Hong pp 2438–2442 DOI: 10.1021/ic202406f

Self-Assembly of [M8L4] and [M4L2] Fluorescent Metallomacrocycles with Carbazole-Based Dipyrazole Ligands Lin Qin, Liao-Yuan Yao, and Shu-Yan Yu pp 2443–2453 DOI: 10.1021/ic202407b

A Retrievable and Highly Selective Fluorescent Probe for Monitoring Sulfide and Imaging in Living Cells Fengping Hou, Liang Huang, Pinxian Xi, Ju Cheng, Xuefei Zhao, Guoqiang Xie, Yanjun Shi, Fengjuan Cheng, Xiaojun Yao, Decheng Bai, and Zhengzhi Zeng pp 2454–2460 DOI: 10.1021/ic2024082

Syntheses and Structures of Sc2Nb4–xSn5, YNb6Sn6, and ErNb6Sn5: Exploratory Studies in Ternary Rare-Earth Niobium Stannides Cheng-Yang Yue and Xiao-Wu Lei pp 2461–2471 DOI: 10.1021/ic202414h

Thermochemical Properties of Selenium Fluorides, Oxides, and Oxofluorides Virgil E. Jackson and David A. Dixon , Karl O. Christe pp 2472–2485 DOI: 10.1021/ic202417n

Binding of β-Lactam Antibiotics to a Bioinspired Dizinc Complex Reminiscent of the Active Site of Metallo-β-lactamases Simone Wöckel, Joanna Galezowska, Sebastian Dechert, and Franc Meyer pp 2486–2493 DOI: 10.1021/ic202425m

Synthesis and Calorimetric, Spectroscopic, and Structural Characterization of Isocyanide Complexes of Trialkylaluminum and Tri-tert-butylgallium Nicholas B. Kingsley, Kristin Kirschbaum, Joseph A. Teprovich, Jr., Robert A. Flowers, II, and Mark R. Mason pp 2494–2502 DOI: 10.1021/ic202427z

Highly Porous 4,8-Connected Metal–Organic Frameworks: Synthesis, Characterization, and Hydrogen Uptake David J. Mihalcik, Teng Zhang, Liqing Ma, and Wenbin Lin pp 2503–2508 DOI: 10.1021/ic2024296

Lanthanide(III) Complexes with Ligands Derived from a Cyclen Framework Containing Pyridinecarboxylate Pendants. The Effect of Steric Hindrance on the Hydration Number Aurora Rodríguez-Rodríguez, David Esteban-Gómez, Andrés de Blas, Teresa Rodríguez-Blas, Marianna Fekete, Mauro Botta, Raphaël Tripier, and Carlos Platas-Iglesias pp 2509–2521 DOI: 10.1021/ic202436j

Isoquinoline-Based Lanthanide Complexes: Bright NIR Optical Probes and Efficient MRI Agents Fabien Caillé, Célia S. Bonnet, Frédéric Buron, Sandrine Villette, Lothar Helm, Stéphane Petoud, Franck Suzenet, and Éva Tóth pp 2522–2532 DOI: 10.1021/ic202446e

Palladacycle-Catalyzed Asymmetric Hydrophosphination of Enones for Synthesis of C*- and P*-Chiral Tertiary Phosphines Yinhua Huang, Sumod A. Pullarkat, Yongxin Li, and Pak-Hing Leung pp 2533–2540 DOI: 10.1021/ic202472f

Molecular and Electronic Structure, Magnetotropicity and Absorption Spectra of Benzene–Trinuclear Copper(I) and Silver(I) Trihalide Columnar Binary Stacks A. C. Tsipis and A. V. Stalikas pp 2541–2559 DOI: 10.1021/ic202497j

On the Intercalation of the Iodine–Iodide Couple on Layered Double Hydroxides with Different Particle Sizes Maria Bastianini, Daniele Costenaro, Chiara Bisio, Leonardo Marchese, Umberto Costantino, Riccardo Vivani, and Morena Nocchetti pp 2560–2568 DOI: 10.1021/ic202520v

Synthesis of Mixed Tin–Ruthenium and Tin–Germanium–Ruthenium Carbonyl Clusters from [Ru3(CO)12] and Diaminometalenes (M = Sn, Ge) Javier A. Cabeza, Pablo García-Álvarez, and Diego Polo pp 2569–2576 DOI: 10.1021/ic202532u

Pyrazolium- and 1,2-Cyclopentadiene-Based Ligands as σ-Donors: a Theoretical Study of Electronic Structure and Bonding Anssi Peuronen, Mikko M. Hänninen, and Heikki M. Tuononen pp 2577–2587 DOI: 10.1021/ic202546a

Versatile Chemical Transformations of Benzoxazole Based Ligands on Complexation with 3d-Metal Ions Olga Iasco, Ghenadie Novitchi, Erwann Jeanneau, Jean Bernard Tommasino, Nans Roques, and Dominique Luneau pp 2588–2596 DOI: 10.1021/ic202493z

Equilibrium and NMR Relaxometric Studies on the s-Triazine-Based Heptadentate Ligand PTDITA Showing High Selectivity for Gd3+ Ions Zsolt Baranyai, Lorenzo Tei, Giovanni B. Giovenzana, Ferenc K. Kálmán, and Mauro Botta pp 2597–2607 DOI: 10.1021/ic202559h

Preparation and Properties of Two Novel Selenoacetic Acids: HCF2C(O)SeH and ClCF2C(O)SeH Jovanny A. Gómez Castaño, Rosana M. Romano, Helmut Beckers, Helge Willner, and Carlos O. Della Védova pp 2608–2615 DOI: 10.1021/ic202572n

Reaction of Organylxenonium(II) Salts, [RXe][Y], with Organyl Iodides, R′I, in Anhydrous HF: Scope and Limitation of a New Synthetic Approach to Iodonium Salts, [RR′I][Y] Hermann-Josef Frohn and Vadim V. Bardin pp 2616–2620 DOI: 10.1021/ic202576v

Ternary Arsenides A2Zn2As3 (A = Sr, Eu) and Their Stuffed Derivatives A2Ag2ZnAs3 Stanislav S. Stoyko, Mansura Khatun, and Arthur Mar pp 2621–2628 DOI: 10.1021/ic202580m

Unfairly Forgotten Member of the Iodocarborane Family: Synthesis and Structural Characterization of 8-Iodo-1,2-dicarba-closo-dodecaborane, Its Precursors, and Derivatives. Alexander V. Safronov, Yulia V. Sevryugina, Satish S. Jalisatgi, Robert D. Kennedy, Charles L. Barnes, and M. Frederick Hawthorne pp 2629–2637 DOI: 10.1021/ic2025846

A Vacancy-Disordered, Oxygen-Deficient Perovskite with Long-Range Magnetic Ordering: Local and Average Structures and Magnetic Properties of Sr2Fe1.5Cr0.5O5 Farshid Ramezanipour, John E. Greedan, Joan Siewenie, Ronald L. Donaberger, Stuart Turner, and Gianluigi A. Botton pp 2638–2644 DOI: 10.1021/ic202590r

Oxido-Bridged Di-, Tri-, and Tetra-Nuclear Iron Complexes Bearing Bis(trimethylsilyl)amide and Thiolate Ligands Shun Ohta, Saori Yokozawa, Yasuhiro Ohki, and Kazuyuki Tatsumi pp 2645–2651 DOI: 10.1021/ic2025928

Triple-Stranded Helicates of Zinc(II) and Cadmium(II) Involving a New Redox-Active Multiring Nitrogenous Heterocyclic Ligand: Synthesis, Structure, and Electrochemical and Photophysical Properties Nabanita Kundu, Sk Md Towsif Abtab, Sanchita Kundu, Akira Endo, Simon J. Teat, and Muktimoy Chaudhury pp 2652–2661 DOI: 10.1021/ic202595p

Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+) Jeongho Yeon, Sang-Hwan Kim, Sau Doan Nguyen, Hana Lee, and P. Shiv Halasyamani pp 2662–2668 DOI: 10.1021/ic202602q

Structure–Property Studies Toward the Stimuli-Responsive Behavior of Benzyl–Phospholium Acenes Yi Ren and Thomas Baumgartner pp 2669–2678 DOI: 10.1021/ic2026335

Microwave-Assisted Kumada-Type Cross-Coupling Reactions of Iodinated Carba-closo-dodecaborate Anions Alexander Himmelspach, Guido J. Reiss, and Maik Finze pp 2679–2688 DOI: 10.1021/ic202638k

Synthesis, Characterization, and Glutathionylation of Cobalamin Model Complexes [Co(N4PyCO2Me)Cl]Cl2 and [Co(Bn-CDPy3)Cl]Cl2 Jai Prakash and Jeremy J. Kodanko pp 2689–2698 DOI: 10.1021/ic2026736

Syntheses, Structures, and Magnetic Analyses of a Family of Heterometallic Hexanuclear [Ni4M2] (M = Gd, Dy, Y) Compounds: Observation of Slow Magnetic Relaxation in the DyIII Derivative Hongshan Ke, Lang Zhao, Yang Guo, and Jinkui Tang pp 2699–2705 DOI: 10.1021/ic202699k

Rational Synthesis of [Ge9{Si(SiMe3)3}3]− from Its Parent Zintl Ion Ge94– Feng Li and Slavi C. Sevov pp 2706–2708 DOI: 10.1021/ic202744d

Axial Functionalization of Sterically Hindered Titanium Phthalocyanines Elisabeth Seikel, Benjamin Oelkers, and Jörg Sundermeyer pp 2709–2717 DOI: 10.1021/ic202749v

Correction to Syntheses and Structures of Cationic and Neutral, Homo- and Heteroleptic tert-Butoxides of the Group 4 Metals Edmond Y. Njua, Alexander Steiner, and Lothar Stahl pp 2718–2718 DOI: 10.1021/ic300043m

Issue 05

Capturing C84 Isomers as Chlorides and Pentafluoroethyl Derivatives: C84Cl22 and C84(C2F5)12 Maria A. Lanskikh, Nadezhda B. Tamm, Lev N. Sidorov, and Sergey I. Troyanov pp 2719–2721 DOI: 10.1021/ic202210s

Polyoxometalate-Supported 3d–4f Heterometallic Single-Molecule Magnets Xiaojia Feng, Wenzhe Zhou, Yangguang Li, Hongshan Ke, Jinkui Tang, Rodolphe Clérac, Yonghui Wang, Zhongmin Su, and Enbo Wang pp 2722–2724 DOI: 10.1021/ic202418y

A Homogeneous Gallium(III) Compound Selectively Catalyzes the Epoxidation of Alkenes Wenchan Jiang, John D. Gorden, and Christian R. Goldsmith pp 2725–2727 DOI: 10.1021/ic300159a

Improved Hydrogen Release from Ammonia–Borane with ZIF-8 Rui-Qin Zhong, Ru-Qiang Zou, Tessui Nakagawa, Michael Janicke, Troy A. Semelsberger, Anthony K. Burrell, and Rico E. Del Sesto pp 2728–2730 DOI: 10.1021/ic202562b

Charge Ordering and Carrier Generation by Air Oxidation of a Nickel Complex with Selenium-Containing Extended-Tetrathiafulvalenedithiolate Ligands Hiroyuki Yajima, Biao Zhou, Emiko Fujiwara, Akiko Kobayashi, and Hayao Kobayashi pp 2731–2733 DOI: 10.1021/ic2026768

Chiral Hexanuclear Ferric Wheels John Fielden, Manfred Speldrich, Claire Besson, and Paul Kögerler pp 2734–2736 DOI: 10.1021/ic300042q

Ethylene Sensing by Silver(I) Salt-Impregnated Luminescent Films Michael Santiago Cintrón, Omar Green, and Judith N. Burstyn pp 2737–2746 DOI: 10.1021/ic102590f

Zinc Chalcogenolate Complexes as Precursors to ZnE and Mn/ZnE (E = S, Se) Clusters Chhatra B. Khadka, Andreas Eichhöfer, Florian Weigend, and John F. Corrigan pp 2747–2756 DOI: 10.1021/ic200307g

Switching Off Electron Transfer Reactions in Confined Media: Reduction of [Co(dipic)2]− and [Co(edta)]− by Hexacyanoferrate(II) Michael D. Johnson, Bret B. Lorenz, Patricia C. Wilkins, Brant G. Lemons, Bharat Baruah, Nathan Lamborn, Michelle Stahla, Pabitra B. Chatterjee, David T. Richens, and Debbie C. Crans pp 2757–2765 DOI: 10.1021/ic201247v

Syntheses, X-ray Structural Characterizations, and Thermal Stabilities of Two Nonclassical Trinuclear Vanadium(IV) Complexes, (V3(μ3-O)O2)(μ2-O2P(CH2C6H5)2)6(H2O) and (V3(μ3-O)O2)(μ2-O2P(CH2C6H5)2)6(py), and Polymeric Complexes of Stoichiometry (VO(O2PR2)2)∞, R2 = Ph2 and o-(CH2)2(C6H4) John S. Maass, Zhichao Chen, Matthias Zeller, Floriana Tuna, Richard E. P. Winpenny, and Rudy L. Luck pp 2766–2776 DOI: 10.1021/ic201259u

Luminescence Rigidochromism and Redox Chemistry of Pyrazolate-Bridged Binuclear Platinum(II) Diimine Complex Intercalated into Zirconium Phosphate Layers Eladio J. Rivera, Cindy Barbosa, Rafael Torres, Harry Rivera, Estevao R. Fachini, Tyler W. Green, William B. Connick, and Jorge L. Colón pp 2777–2784 DOI: 10.1021/ic201423q

Oscillator Strength of Symmetry-Forbidden d-d Absorption of Octahedral Transition Metal Complex: Theoretical Evaluation Ken Saito, Yoshinori Eishiro, Yoshihide Nakao, Hirofumi Sato, and Shigeyoshi Sakaki pp 2785–2792 DOI: 10.1021/ic2017402

Electronic Structure of Nickel(II) and Zinc(II) Borohydrides from Spectroscopic Measurements and Computational Modeling Patrick J. Desrochers, Christopher A. Sutton, Micah L. Abrams, Shengfa Ye, Frank Neese, Joshua Telser, Andrew Ozarowski, and J. Krzystek pp 2793–2805 DOI: 10.1021/ic201775c

Structural and Spectroscopic Properties of the Peroxodiferric Intermediate of Ricinus communis Soluble Δ9 Desaturase Martin Srnec, Tibor András Rokob, Jennifer K. Schwartz, Yeonju Kwak, Lubomír Rulíšek, and Edward I. Solomon pp 2806–2820 DOI: 10.1021/ic2018067

Effects of Fluorination on Iridium(III) Complex Phosphorescence: Magnetic Circular Dichroism and Relativistic Time-Dependent Density Functional Theory A. R. G. Smith, M. J. Riley, P. L. Burn, I. R. Gentle, S.-C. Lo, and B. J. Powell pp 2821–2831 DOI: 10.1021/ic201899z

Spirobifluorene Bridged Ir(III) and Os(II) Polypyridyl Arrays: Synthesis, Photophysical Characterization, and Energy Transfer Dynamics Barbara Ventura, Andrea Barbieri, Alessandra Degli Esposti, Julie Batcha Seneclauze, and Raymond Ziessel pp 2832–2840 DOI: 10.1021/ic201903g

Dioxygen Reactivity of New Bispidine-Copper Complexes Peter Comba, Christina Haaf, Stefan Helmle, Kenneth D. Karlin, Shanthi Pandian, and Arkadius Waleska pp 2841–2851 DOI: 10.1021/ic2019296

Spectroscopic and Magnetic Properties of the Metastable States in the Coordination Network [{Co(prm)2}2{Co(H2O)2}{W(CN)8}2]·4H2O (prm = pyrimidine) Rémy Le Bris, Yoshihide Tsunobuchi, Corine Mathonière, Hiroko Tokoro, Shin-ichi Ohkoshi, Nawel Ould-Moussa, Gabor Molnar, Azzedine Bousseksou, and Jean-François Létard. pp 2852–2859 DOI: 10.1021/ic2019692

Crystal Structure and a Giant Magnetoresistance Effect in the New Zintl Compound Eu3Ga2P4 Naohito Tsujii, Catherine A. Uvarov, Peter Klavins, Tanghong Yi, and Susan M. Kauzlarich pp 2860–2866 DOI: 10.1021/ic202018r

Combined Spectroscopic/Computational Studies of Vitamin B12 Precursors: Geometric and Electronic Structures of Cobinamides Amanda J. Reig, Karen S. Conrad, and Thomas C. Brunold pp 2867–2879 DOI: 10.1021/ic202052g

Colorimetric and Fluorescent Signaling of Au3+ by Desulfurization of Thiocoumarin Ji Eun Park, Myung Gil Choi, and Suk-Kyu Chang pp 2880–2884 DOI: 10.1021/ic202080v

Co4(OH)2(C10H16O4)3 Metal–Organic Framework: Slow Magnetic Relaxation in the Ordered Phase of Magnetic Chains Romain Sibille, Thomas Mazet, Bernard Malaman, Thomas Gaudisson, and Michel François pp 2885–2892 DOI: 10.1021/ic2020995

Highly Fluorinated Aryl-Substituted Tris(indazolyl)borate Thallium Complexes: Diverse Regiochemistry at the B–N Bond Wilfried-Solo Ojo, Kane Jacob, Emmanuelle Despagnet-Ayoub, Bianca K. Muñoz, Sergio Gonell, Laure Vendier, Viet-Hoang Nguyen, and Michel Etienne pp 2893–2901 DOI: 10.1021/ic202125c

μ-η6,η6-Arene-Bridged Diuranium Hexakisketimide Complexes Isolable in Two States of Charge Paula L. Diaconescu and Christopher C. Cummins pp 2902–2916 DOI: 10.1021/ic202163m

Structural, EPR, and Mössbauer Characterization of (μ-Alkoxo)(μ-Carboxylato)Diiron(II,III) Model Complexes for the Active Sites of Mixed-Valent Diiron Enzymes Feifei Li, Mrinmoy Chakrabarti, Yanhong Dong, Karl Kauffmann, Emile L. Bominaar, Eckard Münck, and Lawrence Que, Jr. pp 2917–2929 DOI: 10.1021/ic2021726

Further Observations on Water Oxidation Catalyzed by Mononuclear Ru(II) Complexes Nattawut Kaveevivitchai, Ruifa Zong, Huan-Wei Tseng, Raghu Chitta, and Randolph P. Thummel pp 2930–2939 DOI: 10.1021/ic202174j

A Ratiometric Luminescence Probe for Highly Reactive Oxygen Species Based on Lanthanide Complexes Yunna Xiao, Zhiqiang Ye, Guilan Wang, and Jingli Yuan pp 2940–2946 DOI: 10.1021/ic202195a

Reactions of Diiminopyridine Ligands with Chalcogen Halides Caleb D. Martin and Paul J. Ragogna pp 2947–2953 DOI: 10.1021/ic202213x

Synthesis of Adenine-Modified Reduced Graphene Oxide Nanosheets Huaqiang Cao, Xiaoming Wu, Gui Yin, and Jamie H. Warner pp 2954–2960 DOI: 10.1021/ic2022402

Host Sensitization of Tb3+ Ions in Tribarium Lanthanide Borates Ba3Ln (BO3)3 (Ln = Lu and Gd) De-Yin Wang, Teng-Ming Chen, and Bing-Ming Cheng pp 2961–2965 DOI: 10.1021/ic202241h

Electrochemical, Computational, and Photophysical Characterization of New Luminescent Dirhenium–Pyridazine Complexes Containing Bridging OR or SR Anions Alessio Raimondi, Monica Panigati, Daniela Maggioni, Laura D’Alfonso, Pierluigi Mercandelli, Patrizia Mussini, and Giuseppe D’Alfonso pp 2966–2975 DOI: 10.1021/ic202284a

(Nd1.5Mg0.5)Ni7-Based Compounds: Structural and Hydrogen Storage Properties Qingan Zhang, Bin Zhao, Miaohui Fang, Chaoren Liu, Qingmiao Hu, Fang Fang, Dalin Sun, Liuzhang Ouyang, and Min Zhu pp 2976–2983 DOI: 10.1021/ic2022962

Iminopyridine Complexes of Manganese, Rhenium, and Molybdenum Derived from Amino Ester Methylserine and Peptides Gly-Gly, Gly-Val, and Gly-Gly-Gly: Self-Assembly of the Peptide Chains Celedonio M. Álvarez, Raúl García-Rodríguez, and Daniel Miguel pp 2984–2996 DOI: 10.1021/ic2022984

Electronic Spectra and Crystal-Field Analysis of Europium in Hexanitritolanthanate Systems Peter A. Tanner, Wenyu Li, and Lixin Ning pp 2997–3006 DOI: 10.1021/ic202330h

Metal-Ion-Complexing Properties of 2-(Pyrid-2′-yl)-1,10-phenanthroline, a More Preorganized Analogue of Terpyridyl. A Crystallographic, Fluorescence, and Thermodynamic Study Ashley N. Carolan, Amy E. Mroz, Maya El Ojaimi, Donald G. VanDerveer, Randolph P. Thummel, and Robert D. Hancock pp 3007–3015 DOI: 10.1021/ic202337v

Structure and Hydrolysis of the U(IV), U(V), and U(VI) Aqua Ions from Ab Initio Molecular Simulations Raymond Atta-Fynn, Donald F. Johnson, Eric J. Bylaska, Eugene S. Ilton, Gregory K. Schenter, and Wibe A. de Jong pp 3016–3024 DOI: 10.1021/ic202338z

Reactivity of a Cytostatic Active N,N-Donor-Containing Dinuclear Pt(II) Complex with Biological Relevant Nucleophiles Stephanie Hochreuther and Rudi van Eldik pp 3025–3038 DOI: 10.1021/ic202351r

Titanium/Yttrium Mixed Metal Nitride Clusterfullerene TiY2N@C80: Synthesis, Isolation, and Effect of the Group-III Metal Chuanbao Chen, Fupin Liu, Shujuan Li, Nan Wang, Alexey A. Popov, Mingzhi Jiao, Tao Wei, Qunxiang Li, Lothar Dunsch, and Shangfeng Yang pp 3039–3045 DOI: 10.1021/ic202354u

Interpenetrating Three-Dimensional Diamondoid Lattices and Antiferromagnetic Ordering (Tc = 73 K) of MnII(CN)2 Christopher M. Kareis, Saul H. Lapidus, Peter W. Stephens, and Joel S. Miller pp 3046–3050 DOI: 10.1021/ic202393d

One-Pot Synthesis of Mo0 Dinitrogen Complexes Possessing Monodentate and Multidentate Phosphine Ligands Yalan Ning, Amy A. Sarjeant, Charlotte L. Stern, Thomas H. Peterson, and SonBinh T. Nguyen pp 3051–3058 DOI: 10.1021/ic202430m

Synthesis and Characterization of Ru(II)–DMSO–Cl–Chalcone Complexes: DNA Binding, Nuclease, and Topoisomerase II Inhibitory Activity Ruchi Gaur and Lallan Mishra pp 3059–3070 DOI: 10.1021/ic202440r

Comparison of the Site Occupancies Determined by Combined Rietveld Refinement and Density Functional Theory Calculations: Example of the Ternary Mo–Ni–Re σ Phase Khurram Yaqoob, Jean-Claude Crivello, and Jean-Marc Joubert pp 3071–3078 DOI: 10.1021/ic202479y

Series of Lanthanide Organometallic Single-Ion Magnets Shang-Da Jiang, Shan-Shan Liu, Li-Nan Zhou, Bing-Wu Wang, Zhe-Ming Wang, and Song Gao pp 3079–3087 DOI: 10.1021/ic202511n

Crystallization of New Samarium Polyborates Zheng Ying Wu, Paula Brandao, and Zhi Lin pp 3088–3093 DOI: 10.1021/ic202516z

Cis–Trans Isomeric and Polymorphic Effects on the Magnetic Properties of Water-Bridged Copper Coordination Chains Bojan Kozlevčar, Nives Kitanovski, Zvonko Jagličić, Nuno A. G. Bandeira, Vincent Robert, Boris Le Guennic, and Patrick Gamez pp 3094–3102 DOI: 10.1021/ic202568y

3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials Hong-Yue Wu, Run-Xue Wang, Weiting Yang, Jinlei Chen, Zhong-Ming Sun, Jun Li, and Hongjie Zhang pp 3103–3107 DOI: 10.1021/ic202577z

Systematic Investigation of Zinc Aminoalkylphosphonates: Influence of the Alkyl Chain Lengths on the Structure Formation Corinna Schmidt and Norbert Stock pp 3108–3118 DOI: 10.1021/ic202589s

Closely Related Rare-Earth Metal Germanides RE2Li2Ge3 and RE3Li4Ge4 (RE = La–Nd, Sm): Synthesis, Crystal Chemistry, and Magnetic Properties Sheng-Ping Guo, Tae-Soo You, and Svilen Bobev pp 3119–3129 DOI: 10.1021/ic202591j

Rhenium(V) and Technetium(V) Nitrido Complexes with Mixed Tridentate π-Donor and Monodentate π-Acceptor Ligands Alessandra Boschi, Emiliano Cazzola, Licia Uccelli, Micol Pasquali, Valeria Ferretti, Valerio Bertolasi, and Adriano Duatti pp 3130–3137 DOI: 10.1021/ic202605z

Magnetic Mn and Co Complexes with a Large Polycyclic Aromatic Substituted Nitronylnitroxide Maria G. F. Vaz, Rafael A. Allão, Handan Akpinar, John A. Schlueter, Sauli Santos, Jr., Paul M. Lahti, and Miguel A. Novak pp 3138–3145 DOI: 10.1021/ic202623p

Iron(III) Phosphates Obtained by Thermal Treatment of the Tavorite-Type FePO4·H2O Material: Structures and Electrochemical Properties in Lithium Batteries Nicolas Marx, Lydie Bourgeois, Dany Carlier, Alain Wattiaux, Emmanuelle Suard, Frédéric Le Cras, and Laurence Croguennec pp 3146–3155 DOI: 10.1021/ic2026279

Blue-Colored, Linear Rigid-Axle [2]Pseudorotaxanes: Metal-Binding Properties, Crystal Structures, and Blue/Red Dichroism Isurika R. Fernando and Gellert Mezei pp 3156–3160 DOI: 10.1021/ic2026329

Synthesis, Structural Characterization, Solution Behavior, and in Vitro Antiproliferative Properties of a Series of Gold Complexes with 2-(2′-Pyridyl)benzimidazole as Ligand: Comparisons of Gold(III) versus Gold(I) and Mononuclear versus Binuclear Derivatives Maria Serratrice, Maria A. Cinellu, Laura Maiore, Maria Pilo, Antonio Zucca, Chiara Gabbiani, Annalisa Guerri, Ida Landini, Stefania Nobili, Enrico Mini, and Luigi Messori pp 3161–3171 DOI: 10.1021/ic202639t

Electron-Deficient Eu6.5Gd0.5Ge6 Intermetallic: A Layered Intergrowth Phase of the Gd5Si4- and FeB-Type Structures Jinlei Yao, Peng Wang, and Yurij Mozharivskyj pp 3172–3178 DOI: 10.1021/ic2026413

trans-[RuII(dpp)Cl2]: A Convenient Reagent for the Preparation of Heteroleptic Ru(dpp) Complexes, Where dpp Is 2,9-Di(pyrid-2′-yl)-1,10-phenanthroline Ruifa Zong, Bin Wang, and Randolph P. Thummel pp 3179–3185 DOI: 10.1021/ic202648h

Synthesis and Characterization of [Ir(1,5-Cyclooctadiene)(μ-H)]4: A Tetrametallic Ir4H4-Core, Coordinatively Unsaturated Cluster Kuang-Hway Yih, Isil K. Hamdemir, Joseph E. Mondloch, Ercan Bayram, Saim Özkar, Relja Vasić, Anatoly I. Frenkel, Oren P. Anderson, and Richard G. Finke pp 3186–3193 DOI: 10.1021/ic2026494

Lattice Dynamics of β-V2O5: Raman Spectroscopic Insight into the Atomistic Structure of a High-Pressure Vanadium Pentoxide Polymorph R. Baddour-Hadjean, M. B. Smirnov, K. S. Smirnov, V. Yu Kazimirov, J. M. Gallardo-Amores, U. Amador, M. E. Arroyo-de Dompablo, and J. P. Pereira-Ramos pp 3194–3201 DOI: 10.1021/ic202651b

Reactivity Studies of Oxo–Mo(IV) Complexes Containing Potential Hydrogen-Bond Acceptor/Donor Phenolate Ligands Victor Wee Lin Ng, Michelle K. Taylor, and Charles G. Young pp 3202–3211 DOI: 10.1021/ic2026686

Two-Coordinate, Quasi-Two-Coordinate, and Distorted Three Coordinate, T-Shaped Chromium(II) Amido Complexes: Unusual Effects of Coordination Geometry on the Lowering of Ground State Magnetic Moments Jessica N. Boynton, W. Alexander Merrill, William M. Reiff, James C. Fettinger, and Philip P. Power pp 3212–3219 DOI: 10.1021/ic202661n

Three New Sodium Neptunyl(V) Selenate Hydrates: Structures, Raman Spectroscopy, and Magnetism Geng Bang Jin, S. Skanthakumar, and L. Soderholm pp 3220–3230 DOI: 10.1021/ic202703j

Electronic Spectra and Excited States of Neptunyl and Its [NpO2Cl4]2– Complex Jing Su, W. H. E. Schwarz, and Jun Li pp 3231–3238 DOI: 10.1021/ic202712p

New Superhindered Polydentate Polyphosphine Ligands P(CH2CH2PtBu2)3, PhP(CH2CH2PtBu2)2, P(CH2CH2CH2PtBu2)3, and their Ruthenium(II) Chloride Complexes Ryan Gilbert-Wilson, Leslie D. Field, and Mohan M. Bhadbhade pp 3239–3246 DOI: 10.1021/ic2027169

Nickel(II) and Palladium(II) Thiaethyneporphyrins. Intramolecular Metal(II)−η2-CC Interaction inside a Porphyrinoid Frame Elżbieta Nojman, Anna Berlicka, Ludmiła Szterenberg, and Lechosław Latos-Grażyński pp 3247–3260 DOI: 10.1021/ic2027175

Diruthenium(III,III) Bis(alkynyl) Compounds with Donor/Acceptor-Substituted geminal-Diethynylethene Ligands William P. Forrest, Zhi Cao, Kerry M. Hassell, Boone M. Prentice, Phillip E. Fanwick, and Tong Ren pp 3261–3269 DOI: 10.1021/ic202720c

Structures and Magnetic Properties of an Antiferromagnetically Coupled Polymeric Copper(II) Complex and Ferromagnetically Coupled Hexanuclear Nickel(II) Clusters Santokh S. Tandon, Scott D. Bunge, Joaquin Sanchiz, and Laurence K. Thompson pp 3270–3282 DOI: 10.1021/ic202732k

A Series of Octanuclear-Nickel(II) Complexes Supported by Thiacalix[4]arenes Kecai Xiong, Feilong Jiang, Yanli Gai, Youfu Zhou, Daqiang Yuan, Kongzhao Su, Xinyi Wang, and Maochun Hong pp 3283–3288 DOI: 10.1021/ic202737h

Theoretical Insights into the Ferromagnetic Coupling in Oxalato-Bridged Chromium(III)-Cobalt(II) and Chromium(III)-Manganese(II) Dinuclear Complexes with Aromatic Diimine Ligands Julia Vallejo, Isabel Castro, Mariadel Déniz, Catalina Ruiz-Pérez, Francesc Lloret, Miguel Julve, Rafael Ruiz-García, and Joan Cano pp 3289–3301 DOI: 10.1021/ic202755z

Electrochemiluminescent Monomers for Solid Support Syntheses of Ru(II)-PNA Bioconjugates: Multimodal Biosensing Tools with Enhanced Duplex Stability Tanmaya Joshi, Gregory J. Barbante, Paul S. Francis, Conor F. Hogan, Alan M. Bond, Gilles Gasser, and Leone Spiccia pp 3302–3315 DOI: 10.1021/ic202761w

Two Isotypic Transition Metal Germanophosphates MII4(H2O)4[Ge(OH)2(HPO4)2(PO4)2] (MII = Fe, Co): Synthesis, Structure, Mössbauer Spectroscopy, and Magnetic Properties Ya-Xi Huang, Xin Zhang, Xuan Huang, Walter Schnelle, Jun Lin, Jin-Xiao Mi, Mei-Bo Tang, and Jing-Tai Zhao pp 3316–3323 DOI: 10.1021/ic202773p

Dimethylalkoxygallanes: Monomeric versus Dimeric Gas-Phase Structures Caroline E. Knapp, Derek A. Wann, Andrzej Bil, Julien T. Schirlin, Heather E. Robertson, Paul F. McMillan, David W. H. Rankin, and Claire J. Carmalt pp 3324–3331 DOI: 10.1021/ic202775x

Synthesis and Characterization of Th2N2(NH) Isomorphous to Th2N3 G. W. Chinthaka Silva, Charles B. Yeamans, Philppe F. Weck, John D. Hunn, Gary S. Cerefice, Alfred P. Sattelberger, and Ken R. Czerwinski pp 3332–3340 DOI: 10.1021/ic300025b

Correction to Thermodynamic and Kinetic Studies on Novel Dinuclear Platinum(II) Complexes Containing Bidentate N,N-donor ligands Stephanie Hochreuther, Ralph Puchta, and Rudi van Eldik pp 3341–3341 DOI: 10.1021/ic300283v

Issue 06

Nuclease Activity via Self-Activation and Anticancer Activity of a Mononuclear Copper(II) Complex: Novel Role of the Tertiary Butyl Group in the Ligand Frame Kaushik Ghosh, Pramod Kumar, Varun Mohan, Udai P. Singh, Sahba Kasiri, and Subhrangsu S. Mandal pp 3343–3345 DOI: 10.1021/ic2016676

Structure Flexibility of the Cu2ZnSnS4 Absorber in Low-Cost Photovoltaic Cells: From the Stoichiometric to the Copper-Poor Compounds L. Choubrac, A. Lafond, C. Guillot-Deudon, Y. Moëlo, and S. Jobic pp 3346–3348 DOI: 10.1021/ic202569q

Heterobimetallic Chalcogenidometallate Strands: Synthesis, Structure, Magnetism, and Conductivity Günther Thiele, Sabrina Peter, Martin Schwarzer, Eugen Ruzin, Rodolphe Clérac, Halgard Staesche, Carola Rößer, Bernhard Roling, and Stefanie Dehnen pp 3349–3351 DOI: 10.1021/ic300075a

Reduction of Carbon Monoxide by [(TMTAA)Rh]2 To Form a Dimetal Ketone Complex Gregory H. Imler, Salome Bhagan, Virginia L. Coffin, and Bradford B. Wayland pp 3352–3354 DOI: 10.1021/ic3001224

Environmental Sensitivity of Ru(II) Complexes: The Role of the Accessory Ligands Eileen N. Dixon, Michael Z. Snow, Jennifer L. Bon, Alison M. Whitehurst, Benjamin A. DeGraff, Carl Trindle, and James N. Demas pp 3355–3365 DOI: 10.1021/ic201114u

Synthesis, Structural, and Magnetic Characterization of Linear and Bent Geometry Cobalt(II) and Nickel(II) Amido Complexes: Evidence of Very Large Spin–Orbit Coupling Effects in Rigorously Linear Coordinated Co2+ Aimee M. Bryan, W. Alexander Merrill, William M. Reiff, James C. Fettinger, and Philip P. Power pp 3366–3373 DOI: 10.1021/ic2012414

Formation of Cationic [RP5Cl]+-Cages via Insertion of [RPCl]+-Cations into a P–P Bond of the P4 Tetrahedron Michael H. Holthausen, Kai-Oliver Feldmann, Stephen Schulz, Alexander Hepp, and Jan J. Weigand pp 3374–3387 DOI: 10.1021/ic2013304

Water Oxidation Catalysis: Influence of Anionic Ligands upon the Redox Properties and Catalytic Performance of Mononuclear Ruthenium Complexes Lianpeng Tong, Ying Wang, Lele Duan, Yunhua Xu, Xiao Cheng, Andreas Fischer, Mårten S. G. Ahlquist, and Licheng Sun pp 3388–3398 DOI: 10.1021/ic201348u

Synthesis, Structural, and Photoluminescence Studies of Gd(terpy)(H2O)(NO3)2M(CN)2 (M = Au, Ag) Complexes: Multiple Emissions from Intra- and Intermolecular Excimers and Exciplexes Rylee B. Thomas, Philip A. Smith, Ayesha Jaleel, Paul Vogel, Carlos Crawford, Zerihun Assefa, and Richard E. Sykora pp 3399–3408 DOI: 10.1021/ic2014495

DFT Investigation of the Molybdenum Cofactor in Periplasmic Nitrate Reductases: Structure of the Mo(V) EPR-Active Species Frédéric Biaso, Bénédicte Burlat, and Bruno Guigliarelli pp 3409–3419 DOI: 10.1021/ic201533p

Effect of the Cooling Rate on Dimerization of C60•– in Fullerene Salt (DMI+)2·(C60•–)·{Cd(Et2NCS2)2I–} Dmitri V. Konarev, Salavat S. Khasanov, Akihiro Otsuka, Hideki Yamochi, Gunzi Saito, and Rimma N. Lyubovskaya pp 3420–3426 DOI: 10.1021/ic201732t

Highly Luminescent Half-Lantern Cyclometalated Platinum(II) Complex: Synthesis, Structure, Luminescence Studies, and Reactivity. Violeta Sicilia, Juan Forniés, José Ma Casas, Antonio Martín, José A. López, Carmen Larraz, Pilar Borja, Carmen Ovejero, Daniel Tordera, and Henk Bolink pp 3427–3435 DOI: 10.1021/ic201910t

Substrate and Metal Control of Barrier Heights for Oxo Transfer to Mo and W Bis-dithiolene Sites Adam L. Tenderholt, Keith O. Hodgson, Britt Hedman, Richard H. Holm, and Edward I. Solomon pp 3436–3442 DOI: 10.1021/ic2020397

Role of Entropy and Autosolvation in Dimerization and Complexation of C60 by Zn7 Metallocavitands Peter D. Frischmann, S. Hessam M. Mehr, Brian O. Patrick, Francesco Lelj, and Mark J. MacLachlan pp 3443–3453 DOI: 10.1021/ic202049t

Affinity of Two Novel Five-Coordinated Anticancer Pt(II) Complexes to Human and Bovine Serum Albumins: A Spectroscopic Approach Fayezeh Samari, Bahram Hemmateenejad, Mojtaba Shamsipur, Mehdi Rashidi, and Hamidreza Samouei pp 3454–3464 DOI: 10.1021/ic202141g

Structurally Diverse Copper(II) Complexes of Polyaza Ligands Containing 1,2,3-Triazoles: Site Selectivity and Magnetic Properties Pampa M. Guha, Hoa Phan, Jared S. Kinyon, Wendy S. Brotherton, Kesavapillai Sreenath, J. Tyler Simmons, Zhenxing Wang, Ronald J. Clark, Naresh S. Dalal, Michael Shatruk, and Lei Zhu pp 3465–3477 DOI: 10.1021/ic2021319

Mechanism of RuO2 Crystallization in Borosilicate Glass: An Original in Situ ESEM Approach Hassiba Boucetta, Renaud Podor, Lorenzo Stievano, Johann Ravaux, Xavier Carrier, Sandra Casale, Stéphane Gossé, Amélie Monteiro, and Sophie Schuller pp 3478–3489 DOI: 10.1021/ic202156y

Cisplatin-Tethered Gold Nanoparticles That Exhibit Enhanced Reproducibility, Drug Loading, and Stability: a Step Closer to Pharmaceutical Approval? Gemma E. Craig, Sarah D. Brown, Dimitrios A. Lamprou, Duncan Graham, and Nial J. Wheate pp 3490–3497 DOI: 10.1021/ic202197g

Cobalt-Centered Ten-Vertex Germanium Clusters: The Pentagonal Prism as an Alternative to Polyhedra Predicted by the Wade–Mingos Rules M. M. Uţă, D. Cioloboc, and R. B. King pp 3498–3504 DOI: 10.1021/ic202226k

Microwave-Solvothermal Synthesis of Various Polymorphs of Nanostructured TiO2 in Different Alcohol Media and Their Lithium Ion Storage Properties Sukeun Yoon, Eun-Sung Lee, and Arumugam Manthiram pp 3505–3512 DOI: 10.1021/ic202239n

Role of the Tyr-Cys Cross-link to the Active Site Properties of Galactose Oxidase Dalia Rokhsana, Alta E. Howells, David M. Dooley, and Robert K. Szilagyi pp 3513–3524 DOI: 10.1021/ic2022769

Copper Ion Mediated Selective Cleavage of C–S Bond in Ferrocenylthiosemicarbazone Forming Mixed Geometrical [(PPh3)Cu(μ-S)2Cu(PPh3)2] Having Cu2S2 Core: Toward a New Avenue in Copper–Sulfur Chemistry Rathinasabapathi Prabhakaran, Palaniappan Kalaivani, Somanur V. Renukadevi, Rui Huang, Kittusamy Senthilkumar, Ramasamy Karvembu, and Karuppannan Natarajan pp 3525–3532 DOI: 10.1021/ic2022616

[M(rac-N-benzyl Asp)(H2O)] (M = Co, Ni): Noncentrosymmetric Coordination Polymeric Chains with Racemic Chiral Ligands Junghwan Do, Yumi Lee, Jaeun Kang, Yong Sun Park, Bernd Lorenz, and Allan J. Jacobson pp 3533–3539 DOI: 10.1021/ic202302x

Promising Oxonitridosilicate Phosphor Host Sr3Si2O4N2: Synthesis, Structure, and Luminescence Properties Activated by Eu2+ and Ce3+/Li+ for pc-LEDs Xiao-Ming Wang, Chun-Hai Wang, Xiao-Jun Kuang, Ru-Qiang Zou, Ying-Xia Wang, and Xi-Ping Jing pp 3540–3547 DOI: 10.1021/ic202340q

Gold Derivatives of Eight Rare-Earth-Metal-Rich Tellurides: Monoclinic R7Au2Te2 and Orthorhombic R6AuTe2 Types Ping Chai and John D. Corbett pp 3548–3556 DOI: 10.1021/ic202342v

Anion Induced Formation of Supramolecular Associations Involving Lone pair−π and Anion−π Interactions in Co(II) Malonate Complexes: Experimental Observations, Hirshfeld Surface Analyses and DFT Studies Prankrishna Manna, Saikat Kumar Seth, Amrita Das, Joanna Hemming, Richard Prendergast, Madeleine Helliwell, Somnath Ray Choudhury, Antonio Frontera, and Subrata Mukhopadhyay pp 3557–3571 DOI: 10.1021/ic202317f

Magnetic and Neutron Diffraction Study on Melilite-Type Oxides Sr2MGe2O7 (M = Mn, Co) Takashi Endo, Yoshihiro Doi, Yukio Hinatsu, and Kenji Ohoyama pp 3572–3578 DOI: 10.1021/ic202386h

One-Pot Noninjection Synthesis of Cu-Doped ZnxCd1-xS Nanocrystals with Emission Color Tunable over Entire Visible Spectrum Wenjin Zhang, Xinggui Zhou, and Xinhua Zhong pp 3579–3587 DOI: 10.1021/ic2024023

Hydrothermal Synthesis and Comparative Coordination Chemistry of New Rare-Earth V4+ Compounds Martin M. Kimani, Colin D. McMillen, and Joseph W. Kolis pp 3588–3596 DOI: 10.1021/ic2024132

Salicylimine-Based Fluorescent Chemosensor for Aluminum Ions and Application to Bioimaging Soojin Kim, Jin Young Noh, Ka Young Kim, Jin Hoon Kim, Hee Kyung Kang, Seong-Won Nam, So Hyun Kim, Sungsu Park, Cheal Kim, and Jinheung Kim pp 3597–3602 DOI: 10.1021/ic2024583

Hydroxide Ion versus Chloride and Methoxide as an Exogenous Ligand Reveals the Influence of Hydrogen Bonding with Second-Sphere Coordination Water Molecules in the Electron Transfer Kinetics of Mn Complexes Sanae El Ghachtouli, Régis Guillot, Ally Aukauloo, Pierre Dorlet, Elodie Anxolabéhère-Mallart, and Cyrille Costentin pp 3603–3612 DOI: 10.1021/ic202480h

Uranium and Thorium Hydride Complexes as Multielectron Reductants: A Combined Neutron Diffraction and Quantum Chemical Study Daniel J. Grant, Timothy J. Stewart, Robert Bau, Kevin A. Miller, Sax A. Mason, Matthias Gutmann, Garry J. McIntyre, Laura Gagliardi, and William J. Evans pp 3613–3624 DOI: 10.1021/ic202503h

Reaction of Metal-Binding Ligands with the Zinc Proteome: Zinc Sensors and N,N,N′,N′-Tetrakis(2-pyridylmethyl)ethylenediamine Jeffrey W. Meeusen, Andrew Nowakowski, and David H. Petering pp 3625–3632 DOI: 10.1021/ic2025236

Anthracene-Tethered Ruthenium(II) Arene Complexes as Tools To Visualize the Cellular Localization of Putative Organometallic Anticancer Compounds Alexey A. Nazarov, Julie Risse, Wee Han Ang, Frederic Schmitt, Olivier Zava, Albert Ruggi, Michael Groessl, Rosario Scopelitti, Lucienne Juillerat-Jeanneret, Christian G. Hartinger, and Paul J. Dyson pp 3633–3639 DOI: 10.1021/ic202530j

Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes Containing an Imidodiphosphinate Ligand Guo-Cang Wang, Herman H. Y. Sung, Ian D. Williams, and Wa-Hung Leung pp 3640–3647 DOI: 10.1021/ic202564h

Photomagnetic K0.25Ni1–xCox[Fe(CN)6]·nH2O and K0.25Co[Fe(CN)6]0.75y[Cr(CN)6]0.75(1–y)·nH2O Prussian Blue Analogue Solid Solutions Daniel M. Pajerowski, Takashi Yamamoto, and Yasuaki Einaga pp 3648–3655 DOI: 10.1021/ic202571d

Syntheses and Excitation Transfer Studies of Near-Orthogonal Free-Base Porphyrin–Ruthenium Phthalocyanine Dyads and Pentad Rachel Jacobs, Kati Stranius, Eranda Maligaspe, Helge Lemmetyinen, Nikolai V. Tkachenko, Melvin E. Zandler, and Francis D’Souza pp 3656–3665 DOI: 10.1021/ic202574q

An Octanuclear Molybdenum(VI) Complex Containing Coordinatively Bound 4,4′-di-tert-Butyl-2,2′-Bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins Tatiana R. Amarante, Patrícia Neves, Cátia Tomé, Marta Abrantes, Anabela A. Valente, Filipe A. Almeida Paz, Martyn Pillinger, and Isabel S. Gonçalves pp 3666–3676 DOI: 10.1021/ic202640a

Insertion and Substitution Chemistry at the Boron Fourth Position in Charge-Neutral Zwitterionic Tripodal Tris(methimazolyl)borate Ligands Philip J. Bailey, Nicola L. Bell, Gary S. Nichol, Simon Parsons, and Fraser White. pp 3677–3689 DOI: 10.1021/ic202618p

Coordination of Methyl Coenzyme M and Coenzyme M at Divalent and Trivalent Nickel Cyclams: Model Studies of Methyl Coenzyme M Reductase Active Site Jun-ichi Nishigaki, Tsuyoshi Matsumoto, and Kazuyuki Tatsumi pp 3690–3697 DOI: 10.1021/ic202686x

Activation of H–H and H–O Bonds at Phosphorus with Diiron Complexes Bearing Pyramidal Phosphinidene Ligands M. Angeles Alvarez, M. Esther García, Daniel García-Vivó, Alberto Ramos, and Miguel A. Ruiz pp 3698–3706 DOI: 10.1021/ic2026945

Electronic Structures of the [V(tbpy)3]z (z = 3+, 2+, 0, 1−) Electron Transfer Series Amanda C. Bowman, Stephen Sproules, and Karl Wieghardt pp 3707–3717 DOI: 10.1021/ic202711s

Experimental Fingerprints for Redox-Active Terpyridine in [Cr(tpy)2](PF6)n (n = 3–0), and the Remarkable Electronic Structure of [Cr(tpy)2]1– Christopher C. Scarborough, Kyle M. Lancaster, Serena DeBeer, Thomas Weyhermüller, Stephen Sproules, and Karl Wieghardt pp 3718–3732 DOI: 10.1021/ic2027219

Side-on Bound Complexes of Phenyl- and Methyl-diazene Leslie D. Field, Hsiu L. Li, Scott J. Dalgarno, and Ruaraidh D. McIntosh pp 3733–3742 DOI: 10.1021/ic2027225

Spectroscopic and Theoretical Studies of Ga(III)protoporphyrin-IX and Its Reactions with Myoglobin Tyler B. J. Pinter, Erin L. Dodd, D. Scott Bohle, and Martin J. Stillman pp 3743–3753 DOI: 10.1021/ic202731g

Can a Formally Zwitterionic Rhodium(I) Complex Emulate the Charge Density of a Cationic Rhodium(I) Complex? A Combined Synchrotron X-ray and Theoretical Charge-Density Study El-Eulmi Bendeif, Chérif F. Matta, Mark Stradiotto, Pierre Fertey, and Claude Lecomte pp 3754–3769 DOI: 10.1021/ic2026347

Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives. S. Chantal E. Stieber, Carsten Milsmann, Jordan M. Hoyt, Zoë R. Turner, Kenneth D. Finkelstein, Karl Wieghardt, Serena DeBeer, and Paul J. Chirik pp 3770–3785 DOI: 10.1021/ic202750n

Intramolecular Aminoalkene Hydroamination Mediated by a Tethered Bis(ureate)zirconium Complex: Computational Perusal of Various Pathways for Aminoalkene Activation Sven Tobisch pp 3786–3795 DOI: 10.1021/ic202753m

Cyanido-Bridged Fe(III)–Mn(III) Heterobimetallic Materials Built From Mn(III) Schiff Base Complexes and Di- or Tri-Cyanido Fe(III) Precursors Tapas Senapati, Céline Pichon, Rodica Ababei, Corine Mathonière, and Rodolphe Clérac pp 3796–3812 DOI: 10.1021/ic2027708

Luminescent Iridium(III) Complexes with NCN-Coordinated Terdentate Ligands: Dual Tuning of the Emission Energy and Application to Organic Light-Emitting Devices Pierpaolo Brulatti, Richard J. Gildea, Judith A. K. Howard, Valeria Fattori, Massimo Cocchi, and J. A. Gareth Williams pp 3813–3826 DOI: 10.1021/ic202756w

Metal Complexes of Bridging Neutral Radical Ligands: pymDTDA and pymDSDA Jian Wu, Daniel J. MacDonald, Rodolphe Clérac, Ie-Rang Jeon, Michael Jennings, Alan J. Lough, James Britten, Craig Robertson, Paul A. Dube, and Kathryn E. Preuss pp 3827–3839 DOI: 10.1021/ic3000284

Uranyl-Peroxide Nanocapsules: Electronic Structure and Cation Complexation in [(UO2)20(μ-O2)30]20– Pere Miro and Carles Bo pp 3840–3845 DOI: 10.1021/ic300029d

Comparison of Cu(II)-Promoted Leaving Group Stabilization of the Cleavage of a Homologous Set of Phosphate Mono-, Di-, and Triesters in Water, Methanol, and Ethanol Mark A. R. Raycroft, C. Tony Liu, and R. Stan Brown pp 3846–3854 DOI: 10.1021/ic300059e

How Amidoximate Binds the Uranyl Cation Sinisa Vukovic, Lori A. Watson, Sung Ok Kang, Radu Custelcean, and Benjamin P. Hay pp 3855–3859 DOI: 10.1021/ic300062s

Structural Diversity in Coordination Self-Assembled Networks of a Multimodal Ligand Azacalix[4]pyrazine Jin-Cheng Wu, Liang Zhao, De-Xian Wang, and Mei-Xiang Wang pp 3860–3867 DOI: 10.1021/ic3000679

Dissolution of Cerium(IV)–Lanthanide(III) Oxides: Comparative Effect of Chemical Composition, Temperature, and Acidity D. Horlait, N. Clavier, S. Szenknect, N. Dacheux, and V. Dubois pp 3868–3878 DOI: 10.1021/ic300071c

Cs3UGe7O18: A Pentavalent Uranium Germanate Containing Four- and Six-Coordinate Germanium Quang Bac Nguyen, Chun-Liang Chen, Yun-Wei Chiang, and Kwang-Hwa Lii pp 3879–3882 DOI: 10.1021/ic3000872

Investigation of in Situ Oxalate Formation from 2,3-Pyrazinedicarboxylate under Hydrothermal Conditions Using Nuclear Magnetic Resonance Spectroscopy Karah E. Knope, Hiroshi Kimura, Yoshiro Yasaka, Masaru Nakahara, Michael B. Andrews, and Christopher L. Cahill pp 3883–3890 DOI: 10.1021/ic3000944

Synthesis, Structure, and Aromaticity of the Nickel(II) Complex of Pyricorrole, a Molecular Hybrid of Porphyrin and Corrole Saburo Neya, Masaaki Suzuki, Takashi Matsugae, and Tyuji Hoshino pp 3891–3895 DOI: 10.1021/ic3001043

Diaminogermylene and Diaminostannylene Derivatives of Gold(I): Novel AuM and AuM2 (M = Ge, Sn) Complexes Javier A. Cabeza, José M. Fernández-Colinas, Pablo García-Álvarez, and Diego Polo pp 3896–3903 DOI: 10.1021/ic3001575

Symmetrical P4 Cleavage at Cobalt: Characterization of Intermediates on the Way from P4 to Coordinated P2 Units Simon Dürr, Daniel Ertler, and Udo Radius pp 3904–3909 DOI: 10.1021/ic300219w

β-Nitro Derivatives of Iron Corrolates Sara Nardis, Manuela Stefanelli, Pruthviraj Mohite, Giuseppe Pomarico, Luca Tortora, Machima Manowong, Ping Chen, Karl M. Kadish, Frank R. Fronczek, Gregory T. McCandless, Kevin M. Smith, and Roberto Paolesse pp 3910–3920 DOI: 10.1021/ic3002459

Correction to Characterization of Low Energy Charge Transfer Transitions in (terpyridine)(bipyridine)Ruthenium(II) Complexes and their Cyanide-Bridged Bi- and Tri-Metallic Analogues Chia-Nung Tsai, Marco M. Allard, Richard L. Lord, Dao-Wen Luo, Yuan-Jang Chen, H. Bernhard Schlegel, and John F. Endicott pp 3921–3921 DOI: 10.1021/ic300452n

Issue 07

Independent 1D Nanosized Metal–Organic Tube: Anion Exchange, Separation, and Anion-Responsive Luminescence Chao Fang, Qi-Kui Liu, Jian-Ping Ma, and Yu-Bin Dong pp 3923–3925 DOI: 10.1021/ic201765u

[Ni(phen)3]2Sb18S29: A Novel Three-Dimensional Framework Thioantimonate(III) Templated by [Ni(phen)3] Complexes Ke-Zhao Du, Mei-Ling Feng, Long-Hua Li, Bing Hu, Zu-Ju Ma, Peng Wang, Jian-Rong Li, Yu-Long Wang, Guo-Dong Zou, and Xiao-Ying Huang pp 3926–3928 DOI: 10.1021/ic202246q

Structure and Properties of New Mixed-Valent [MnIII2MnIV3LnIII5O5] Complexes (LnIII = TmIII, LuIII, and YbIII) Kirstin Hallier, Małgorzata Hołyńska, Mathieu Rouzières, Rodolphe Clérac, and Stefanie Dehnen pp 3929–3931 DOI: 10.1021/ic202443u

Homogeneous CO2 Reduction by Ni(cyclam) at a Glassy Carbon Electrode Jesse D. Froehlich and Clifford P. Kubiak pp 3932–3934 DOI: 10.1021/ic3001619

Dodecanuclear [CuII6GdIII6] Nanoclusters as Magnetic Refrigerants Alina S. Dinca, Alberto Ghirri, Augustin M. Madalan, Marco Affronte, and Marius Andruh pp 3935–3937 DOI: 10.1021/ic3001762

Macrocycle Formation by Proton-Template-Induced Dimerization of Complexes with (Alkoxoimino)pyridine Celedonio M. Álvarez, Raúl García-Rodríguez, Jose M. Martín-Alvarez, Daniel Miguel, and José A. Turiel pp 3938–3940 DOI: 10.1021/ic300196w

Rich Coordination of Nd3+ in Mg2Nd13(BO3)8(SiO4)4(OH)3, Derived from High-Pressure/High-Temperature Conditions Shijun Wu, Philip Kegler, Shuao Wang, Astrid Holzheid, Wulf Depmeier, Thomas Malcherek, Evgeny V. Alekseev, and Thomas E. Albrecht-Schmitt pp 3941–3943 DOI: 10.1021/ic3002493

A Two-Step Valence Tautomeric Transition in a Dinuclear Cobalt Complex Kerwyn G. Alley, Giordano Poneti, Jade B. Aitken, Rosalie K. Hocking, Boujemaa Moubaraki, Keith S. Murray, Brendan F. Abrahams, Hugh H. Harris, Lorenzo Sorace, and Colette Boskovic pp 3944–3946 DOI: 10.1021/ic3002527

Magnetic Properties of Hexanuclear Lanthanide(III) Clusters Incorporating a Central μ6-Carbonate Ligand Derived from Atmospheric CO2 Fixation Stuart K. Langley, Boujemaa Moubaraki, and Keith S. Murray pp 3947–3949 DOI: 10.1021/ic3002724

Synthesis of a High-Valent, Four-Coordinate Manganese Cubane Cluster with a Pendant Mn Atom: Photosystem II-Inspired Manganese–Nitrogen Clusters Shivaiah Vaddypally, Sandeep K. Kondaveeti, and Michael J. Zdilla pp 3950–3952 DOI: 10.1021/ic300502s

Two Novel Acentric Borate Fluorides: M3B6O11F2 (M = Sr, Ba) Colin D. McMillen, Jared T. Stritzinger, and Joseph W. Kolis pp 3953–3955 DOI: 10.1021/ic202318b

Hydrothermal Synthesis and Crystal Structure of Two New Hydrated Alkaline Earth Metal Borates Sr3B6O11(OH)2 and Ba3B6O11(OH)2 Carla Heyward, Colin McMillen, and Joseph Kolis pp 3956–3962 DOI: 10.1021/ic202316t

Monodisperse Lanthanide Fluoride Nanocrystals: Synthesis and Luminescent Properties Xingbo Li, Shili Gai, Chunxia Li, Dong Wang, Na Niu, Fei He, and Piaoping Yang pp 3963–3971 DOI: 10.1021/ic200925v

Carbonyl Amine/Schiff Base Ligands in Manganese Complexes: Theoretical Study on the Mechanism, Capability of NO Release Weili Zheng, Shuixing Wu, Shanshan Zhao, Yun Geng, Junling Jin, Zhongmin Su, and Qiang Fu pp 3972–3980 DOI: 10.1021/ic2011953

New Dicarboxylic Acid Bipyridine Ligand for Ruthenium Polypyridyl Sensitization of TiO2 William B. Heuer, Hai-Long Xia, William Ward, Zhen Zhou, Wayne H. Pearson, Maxime A. Siegler, Amy A. Narducci Sarjeant, Maria Abrahamsson, and Gerald J. Meyer pp 3981–3988 DOI: 10.1021/ic201395q

{Sn9[Si(SiMe3)3]3}− and {Sn8Si[Si(SiMe3)3]3}−: Variations of the E9 Cage of Metalloid Group 14 Clusters Claudio Schrenk, Marco Neumaier, and Andreas Schnepf pp 3989–3995 DOI: 10.1021/ic201730g

Reactivity of a Tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide Complex Toward Sulfur: Synthesis and 119Sn Mössbauer Spectroscopic Studies of [{(μ-S)SnC(PPh2═NSiMe3)(PPh2═S)}3Sn(μ3-S)] Jia-Yi Guo, Hong-Wei Xi, Israel Nowik, Rolfe H. Herber, Yongxin Li, Kok Hwa Lim, and Cheuk-Wai So pp 3996–4001 DOI: 10.1021/ic2019633

Low-Energy States of Manganese–Oxo Corrole and Corrolazine: Multiconfiguration Reference ab Initio Calculations Hailiang Zhao, Kristine Pierloot, Ernie H. G. Langner, Jannie C. Swarts, Jeanet Conradie, and Abhik Ghosh pp 4002–4006 DOI: 10.1021/ic201972f

The Incommensurately Modulated Structures of the Perovskites NaCeMnWO6 and NaPrMnWO6 Susana García-Martín, Graham King, Gwilherm Nénert, C. Ritter, and Patrick M. Woodward pp 4007–4014 DOI: 10.1021/ic202071n

Photochromic Metal Complexes of N-Methyl-4,4′-Bipyridinium: Mechanism and Influence of Halogen Atoms Xiang-Ying Lv, Ming-Sheng Wang, Chen Yang, Guan-E Wang, Shuai-Hua Wang, Rong-Guang Lin, and Guo-Cong Guo pp 4015–4019 DOI: 10.1021/ic2020868

Germyl- and Germylene-Bridged Complexes of Rh/Ir and Subsequent Chemistry of a Bridging Germylene Group Md Hosnay Mobarok, Robert McDonald, Michael J. Ferguson, and Martin Cowie pp 4020–4034 DOI: 10.1021/ic2021269

Molecular Assembly and Magnetic Dynamics of Two Novel Dy6 and Dy8 Aggregates Yun-Nan Guo, Xiao-Hua Chen, Shufang Xue, and Jinkui Tang pp 4035–4042 DOI: 10.1021/ic202170z

Water Oxidation Catalyzed by the Tetranuclear Mn Complex [MnIV4O5(terpy)4(H2O)2](ClO4)6 Yunlong Gao, Robert H. Crabtree, and Gary W. Brudvig pp 4043–4050 DOI: 10.1021/ic2021897

Combining Bifunctional Chelator with (3 + 2)-Cycloaddition Approaches: Synthesis of Dual-Function Technetium Complexes Henrik Braband, Sebastian Imstepf, Michael Benz, Bernhard Spingler, and Roger Alberto pp 4051–4057 DOI: 10.1021/ic202212e

Extreme Differences in Oxidation States: Synthesis and Structural Analysis of the Germanide Oxometallates A10[Ge9]2[WO4] As Well As A10+x[Ge9]2[W1–xNbxO4] with A = K and Rb Containing [Ge9]4– Polyanions Viktor Hlukhyy, Thomas F. Fässler, Siméon Ponou, Sven Lidin, Natalia P. Ivleva, and Reinhard Niessner pp 4058–4065 DOI: 10.1021/ic202234b

Spin Delocalization Over Type Zero Copper Alexey Potapov, Kyle M. Lancaster, John H. Richards, Harry B. Gray, and Daniella Goldfarb pp 4066–4075 DOI: 10.1021/ic202336m

Insight into the Dinuclear {Fe(NO)2}10{Fe(NO)2}10 and Mononuclear {Fe(NO)2}10 Dinitrosyliron Complexes Shih-Wey Yeh, Chih-Wei Lin, Ya-Wen Li, I-Jui Hsu, Chien-Hong Chen, Ling-Yun Jang, Jyh-Fu Lee, and Wen-Feng Liaw pp 4076–4087 DOI: 10.1021/ic202332d

Periodic Trends in Hexanuclear Actinide Clusters Juan Diwu, Shuao Wang, and Thomas E. Albrecht-Schmitt pp 4088–4093 DOI: 10.1021/ic2023242

Chiral Sensing Using an Achiral Europium(III) Complex by Induced Circularly Polarized Luminescence Munetaka Iwamura, Yoshihiro Kimura, Risa Miyamoto, and Koichi Nozaki pp 4094–4098 DOI: 10.1021/ic202355s

Low-Melting Salts Based on a Glycolated Cobalt Bis(dicarbollide) Anion Jakub Rak, Milan Jakubek, Robert Kaplánek, and Vladimír Král pp 4099–4107 DOI: 10.1021/ic2023665

Solid-State NMR Study of Li-Assisted Dehydrogenation of Ammonia Borane Takeshi Kobayashi, Ihor Z. Hlova, Niraj K. Singh, Vitalij. K. Pecharsky, and Marek Pruski pp 4108–4115 DOI: 10.1021/ic202368a

Self-Assembly of Discrete M6L8 Coordination Cages Based on a Conformationally Flexible Tripodal Phosphoric Triamide Ligand Xing-Jun Li, Fei-Long Jiang, Ming-Yan Wu, Shu-Quan Zhang, You-Fu Zhou, and Mao-Chun Hong pp 4116–4122 DOI: 10.1021/ic202373a

Impact of Ligand Modification on Hydrogen Photogeneration and Light-Harvesting Applications Using Cyclometalated Iridium Complexes Yong-Jun Yuan, Ji-Yuan Zhang, Zhen-Tao Yu, Jian-Yong Feng, Wen-Jun Luo, Jin-Hua Ye, and Zhi-Gang Zou pp 4123–4133 DOI: 10.1021/ic202423y

Planar-Chiral Metal Complexes Comprised of Square-Planar Metal and Achiral Tetradentate Ligands: Design, Optical Resolution, and Thermodynamics Hidetoshi Goto, Teppei Hayakawa, Kanako Furutachi, Hiroshi Sugimoto, and Shohei Inoue pp 4134–4142 DOI: 10.1021/ic2024742

Synthesis, Crystal Structures, and Hydrogen-Storage Properties of Eu(AlH4)2 and Sr(AlH4)2 and of Their Decomposition Intermediates, EuAlH5 and SrAlH5 André Pommerin, Aron Wosylus, Michael Felderhoff, Ferdi Schüth, and Claudia Weidenthaler pp 4143–4150 DOI: 10.1021/ic202492v

Divalent Lanthanide Complexes Supported by the Bridged Bis(amidinates) L [L = Me3SiN(Ph)CN(CH2)3NC(Ph)NSiMe3]: Synthesis, Molecular Structures and One-Electron-Transfer Reactions Lijuan Yan, Haidong Liu, Junfeng Wang, Yong Zhang, and Qi Shen pp 4151–4160 DOI: 10.1021/ic202505d

Phase Range of the Type-I Clathrate Sr8AlxSi46–x and Crystal Structure of Sr8Al10Si36 John H. Roudebush, Naohito Tsujii, Antonio Hurtando, Håkon Hope, Yuri Grin, and Susan M. Kauzlarich pp 4161–4169 DOI: 10.1021/ic2024814

N-Heterocyclic Phosphenium Ligands as Sterically and Electronically-Tunable Isolobal Analogues of Nitrosyls Baofei Pan, Zhequan Xu, Mark W. Bezpalko, Bruce M. Foxman, and Christine M. Thomas pp 4170–4179 DOI: 10.1021/ic202581v

Stereochemical Consequences of Oxygen Atom Transfer and Electron Transfer in Imido/Oxido Molybdenum(IV, V, VI) Complexes with Two Unsymmetric Bidentate Ligands Kristina Hüttinger, Christoph Förster, Timo Bund, Dariush Hinderberger, and Katja Heinze pp 4180–4192 DOI: 10.1021/ic202588u

Electron vs Energy Transfer in Arrays Featuring Two Bodipy Chromophores Axially Bound to a Sn(IV) Porphyrin via a Phenolate or Benzoate Bridge Theodore Lazarides, Susanne Kuhri, Georgios Charalambidis, Manas K. Panda, Dirk M. Guldi, and Athanassios G. Coutsolelos pp 4193–4204 DOI: 10.1021/ic2026472

Redox Energetics of Hypercloso Boron Hydrides BnHn (n = 6–13) and B12X12 (X = F, Cl, OH, and CH3) Tae Bum Lee and Michael L. McKee pp 4205–4214 DOI: 10.1021/ic202660d

Magnesium Azaphthalocyanines: An Emerging Family of Excellent Red-Emitting Fluorophores Petr Zimcik, Veronika Novakova, Kamil Kopecky, Miroslav Miletin, Rabia Zeynep Uslu Kobak, Eva Svandrlikova, Lenka Váchová, and Kamil Lang pp 4215–4223 DOI: 10.1021/ic2027016

Syntheses and Characterization of Nine Quaternary Uranium Chalcogenides Among the Compounds A2M3UQ6 (A = K, Rb, Cs; M = Pd, Pt; Q = S, Se) George N. Oh, Eun Sang Choi, and James A. Ibers pp 4224–4230 DOI: 10.1021/ic2027048

Hydrogen in La2MgNi9D13: The Role of Magnesium Roman V. Denys, Volodymyr A. Yartys, and Colin J. Webb pp 4231–4238 DOI: 10.1021/ic202705u

Thorium(IV)–Selenate Clusters Containing an Octanuclear Th(IV) Hydroxide/Oxide Core Karah E. Knope, Monica Vasiliu, David A. Dixon, and L. Soderholm pp 4239–4249 DOI: 10.1021/ic202706s

The μ3 Model of Acids and Bases: Extending the Lewis Theory to Intermetallics Timothy E. Stacey and Daniel C. Fredrickson pp 4250–4264 DOI: 10.1021/ic202727k

Antiferromagnetic Porous Metal–Organic Framework Containing Mixed-Valence [MnII4MnIII2(μ4-O)2]10+ Units with Catecholase Activity and Selective Gas Adsorption Paramita Kar, Ritesh Haldar, Carlos J. Gómez-García, and Ashutosh Ghosh pp 4265–4273 DOI: 10.1021/ic2027362

Spectroscopic, Structural, and Theoretical Studies of Halide Complexes with a Urea-Based Tripodal Receptor Avijit Pramanik, Douglas R. Powell, Bryan M. Wong, and Md. Alamgir Hossain pp 4274–4284 DOI: 10.1021/ic202747q

Synthesis, Spectral, Electrochemical, and Anion Binding Properties of 3,5-Bis(Dipyrromethanyl) Boron-Dipyrromethenes Sheri Madhu and Mangalampalli Ravikanth pp 4285–4292 DOI: 10.1021/ic202758r

Na2EuAs2S5, NaEuAsS4, and Na4Eu(AsS4)2: Controlling the Valency of Arsenic in Polysulfide Fluxes Tarun K. Bera and Mercouri G. Kanatzidis pp 4293–4299 DOI: 10.1021/ic202781c

Mechanistic Aspects of Hydrosilylation Catalyzed by (ArN=)Mo(H)(Cl)(PMe3)3 Andrey Y. Khalimon, Oleg G. Shirobokov, Erik Peterson, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A.K. Howard, and Georgii I. Nikonov pp 4300–4313 DOI: 10.1021/ic300010c

Triclinic–Cubic Phase Transition and Negative Expansion in the Actinide IV (Th, U, Np, Pu) Diphosphates Gilles Wallez, Philippe E. Raison, Nicolas Dacheux, Nicolas Clavier, Denis Bykov, Laurent Delevoye, Karin Popa, Damien Bregiroux, Andrew N. Fitch, and Rudy J. M. Konings pp 4314–4322 DOI: 10.1021/ic300036y

Synthesis, Structure, and Magnetic Properties of Regular Alternating μ-bpm/di-μ-X Copper(II) Chains (bpm = 2,2′-bipyrimidine; X = OH, F) Nadia Marino, Donatella Armentano, Giovanni De Munno, Joan Cano, Francesc Lloret, and Miguel Julve pp 4323–4334 DOI: 10.1021/ic202740b

Ruthenium-Phenothiazine Electron Transfer Dyad with a Photoswitchable Dithienylethene Bridge: Flash-Quench Studies with Methylviologen Bice He and Oliver S. Wenger pp 4335–4342 DOI: 10.1021/ic300048r

Biscyclometalated Ruthenium Complexes Bridged by 3,3′,5,5′-Tetrakis(N-methylbenzimidazol-2-yl)biphenyl: Synthesis and Spectroscopic and Electronic Coupling Studies Jiang-Yang Shao, Wen-Wen Yang, Jiannian Yao, and Yu-Wu Zhong pp 4343–4351 DOI: 10.1021/ic300054j

Molten Salt Synthesis of a Mixed-Valent Lanthanide(III/IV) Oxychloride with an Unprecedented Sillen X24 Structure: Ce1.3Nd0.7O3Cl Jean-François Vigier, Catherine Renard, Natacha Henry, Annabelle Laplace, and Francis Abraham pp 4352–4358 DOI: 10.1021/ic3000558

Selective Two-Step Oxidation of μ2-S Ligands in Trigonal Prismatic Unit {Re3(μ6-C)(μ2-S)3Re3} of the Bioctahedral Cluster Anion [Re12CS17(CN)6]6– Yuri V. Mironov, Yakov M. Gayfulin, Svetlana G. Kozlova, Anton I. Smolentsev, Maria S. Tarasenko, Anton S. Nizovtsev, and Vladimir E. Fedorov pp 4359–4367 DOI: 10.1021/ic300051w

From a Cycloheptatrienylzirconium Allyl Complex to a Cycloheptatrienylzirconium Imidazolin-2-iminato “Pogo Stick” Complex with Imido-Type Reactivity Andreas Glöckner, Thomas Bannenberg, Constantin G. Daniliuc, Peter G. Jones, and Matthias Tamm pp 4368–4378 DOI: 10.1021/ic300129z

Complexes of Lanthanide Nitrates with Tri Tert Butylphosphine Oxide Allen Bowden, Simon J. Coles, Mateusz B. Pitak, and Andrew W. G. Platt pp 4379–4389 DOI: 10.1021/ic300142r

9-Oxidophenalenone: A Noninnocent β-Diketonate Ligand? Amit Das, Thomas Michael Scherer, Shaikh M. Mobin, Wolfgang Kaim, and Goutam Kumar Lahiri pp 4390–4397 DOI: 10.1021/ic300207d

Halogenated Xenon Cyanides ClXeCN, ClXeNC, and BrXeCN Teemu Arppe, Leonid Khriachtchev, Antti Lignell, Alexandra V. Domanskaya, and Markku Räsänen pp 4398–4402 DOI: 10.1021/ic3002543

Combination of Magnetic Susceptibility and Electron Paramagnetic Resonance to Monitor the 1D to 2D Solid State Transformation in Flexible Metal–Organic Frameworks of Co(II) and Zn(II) with 1,4-Bis(triazol-1-ylmethyl)benzene Eugenio Coronado, Mónica Giménez-Marqués, and Guillermo Mínguez Espallargas pp 4403–4410 DOI: 10.1021/ic300276q

Issue 08

[Gallium(III) protoporphyrin IX]2: A Soluble Diamagnetic Model for Malaria Pigment D. Scott Bohle and Erin L. Dodd pp 4411–4413 DOI: 10.1021/ic2027303

Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg–In–S–Cl Chalcohalide: Hg7InS6Cl5 Yi Liu, Fengxia Wei, Sing Ning Yeo, Fu Min Lee, Christian Kloc, Qingyu Yan, Huey Hoon Hng, Jan Ma, and Qichun Zhang pp 4414–4416 DOI: 10.1021/ic202746y

First Ruthenium(II) Polypyridyl Complex As a True Molecular “Light Switch” for Triplex RNA Structure: [Ru(phen)2(mdpz)]2+ Enhances the Stability of Poly(U)·Poly(A)*Poly(U) Li-Feng Tan, Jing Liu, Jian-Liang Shen, Xiao-hua Liu, Le-Li Zeng, and Lian-He Jin pp 4417–4419 DOI: 10.1021/ic300093h

Organic Vapor Triggered Repeatable On–Off Crystalline-State Luminescence Switching Kensuke Naka, Takuji Kato, Seiji Watase, and Kimihiro Matsukawa pp 4420–4422 DOI: 10.1021/ic300173t

Porous Double-Walled Metal Triazolate Framework Based upon a Bifunctional Ligand and a Pentanuclear Zinc Cluster Exhibiting Selective CO2 Uptake Wen-Yang Gao, Wuming Yan, Rong Cai, Le Meng, Andrea Salas, Xi-Sen Wang, Lukasz Wojtas, Xiaodong Shi, and Shengqian Ma pp 4423–4425 DOI: 10.1021/ic3002256

The Intercalation of N,N,N′,N′-Tetramethyl-ethane-1,2-diamine (tmeda) into C6Li and C12Li Mark J. Henderson, Takatoshi Nishimura, and John W. White pp 4426–4428 DOI: 10.1021/ic300269n

Probing Electrostatic Potential by NMR with the Use of a Paramagnetic Lanthanide(III) Chelate Eva M. López-Vidal, Martín Regueiro-Figueroa, Marcos D. García, Carlos Platas-Iglesias, Carlos Peinador, and José M. Quintela pp 4429–4431 DOI: 10.1021/ic300288j

Mixed-Valent Uranium(IV,VI) Diphosphonate: Synthesis, Structure, and Spectroscopy Juan Diwu and Thomas E. Albrecht-Schmitt pp 4432–4434 DOI: 10.1021/ic300391p

Cation-Induced Synthesis of New Polyoxopalladates Zheng-Guo Lin, Bo Wang, Jie Cao, Bao-Kuan Chen, Yuan-Zhe Gao, Ying-Nan Chi, Chong Xu, Xian-Qiang Huang, Ruo-Dan Han, Shuang-Yue Su, and Chang-Wen Hu pp 4435–4437 DOI: 10.1021/ic300428g

Novel Tailormade Bi4MO4(PO4)2 Structural Type (M = Mg, Zn) Diana Endara, Marie Colmont, Marielle Huvé, Grégory Tricot, Laurent Carpentier, and Olivier Mentré pp 4438–4447 DOI: 10.1021/ic201572y

Half-Integer Spin Heptanuclear Single-Molecule Magnet with an Unusual MnIII6MnII Exchange-Coupled Core Siou-Yin Chen, Christopher C. Beedle, Pei-Rung Gan, Gene-Hsian Lee, Stephen Hill, and En-Che Yang pp 4448–4457 DOI: 10.1021/ic2019154

The Modulation of Jahn–Teller Coupling by Elastic and Binding Strain Perturbations—A Novel View on an Old Phenomenon and Examples from Solid-State Chemistry Dirk Reinen pp 4458–4472 DOI: 10.1021/ic202209c

Ferric Complexes of 3-Hydroxy-4-pyridinones Characterized by Density Functional Theory and Raman and UV–vis Spectroscopies Jaroslav Šebestík, Martin Šafařík, and Petr Bouř pp 4473–4481 DOI: 10.1021/ic202004d

Spectroscopic Characterization of Active-Site Variants of the PduO-type ATP:Corrinoid Adenosyltransferase from Lactobacillus reuteri: Insights into the Mechanism of Four-Coordinate Co(II)corrinoid Formation Kiyoung Park, Paola E. Mera, Jorge C. Escalante-Semerena, and Thomas C. Brunold pp 4482–4494 DOI: 10.1021/ic202096x

Synthesis, Structure, and Magnetic Properties of a New Eight-Connected Metal–Organic Framework (MOF) based on Co4 Clusters Debajit Sarma, Partha Mahata, Srinivasan Natarajan, Pierre Panissod, Guillaume Rogez, and Marc Drillon pp 4495–4501 DOI: 10.1021/ic2020989

Control of Intramolecular π–π Stacking Interaction in Cationic Iridium Complexes via Fluorination of Pendant Phenyl Rings Lei He, Dongxin Ma, Lian Duan, Yongge Wei, Juan Qiao, Deqiang Zhang, Guifang Dong, Liduo Wang, and Yong Qiu pp 4502–4510 DOI: 10.1021/ic2021325

Influence of Second Coordination Sphere Hydroxyl Groups on the Reactivity of Copper(I) Complexes Christopher S. Letko, Thomas B. Rauchfuss, Xiaoyuan Zhou, and Danielle L. Gray pp 4511–4520 DOI: 10.1021/ic202207e

Direct Synthesis of Aqueous Quantum Dots through 4,4′-Bipyridine-Based Twin Ligand Strategy Mausam Kalita, Sreeram Cingarapu, Santanu Roy, Seok Chan Park, Daniel Higgins, Ryszard Jankowiak, Viktor Chikan, Kenneth J. Klabunde, and Stefan H. Bossmann pp 4521–4526 DOI: 10.1021/ic202252m

Influencing the Size and Anion Selectivity of Dimeric Ln3+[15-Metallacrown-5] Compartments through Systematic Variation of the Host Side Chains and Central Metal Joseph Jankolovits, Choong-Sun Lim, Gellert Mezei, Jeff W. Kampf, and Vincent L. Pecoraro pp 4527–4538 DOI: 10.1021/ic202347j

Rigid, Perdeuterated Lanthanoid Cryptates: Extraordinarily Bright Near-IR Luminophores. Christine Doffek, Nicola Alzakhem, Mariusz Molon, and Michael Seitz pp 4539–4545 DOI: 10.1021/ic202376k

Site-Selective X-ray Spectroscopy on an Asymmetric Model Complex of the [FeFe] Hydrogenase Active Site Nils Leidel, Petko Chernev, Kajsa G. V. Havelius, Salah Ezzaher, Sascha Ott, and Michael Haumann pp 4546–4559 DOI: 10.1021/ic2024154

Crystal and Electronic Structure and Magnetic Properties of Divalent Europium Perovskite Oxides EuMO3 (M = Ti, Zr, and Hf): Experimental and First-Principles Approaches Hirofumi Akamatsu, Koji Fujita, Hiroyuki Hayashi, Takahiro Kawamoto, Yu Kumagai, Yanhua Zong, Koji Iwata, Fumiyasu Oba, Isao Tanaka, and Katsuhisa Tanaka pp 4560–4567 DOI: 10.1021/ic2024567

Ba2(BO3)1–x(CO3)xCl1+x: A Mixed Borate and Carbonate Chloride Crystallized from High-Temperature Solution Jing Zhao and R. K. Li pp 4568–4571 DOI: 10.1021/ic3005135

Platinum(II) Diimine Complexes with Halide/Pseudohalide Ligands and Dangling Trialkylamine or Ammonium Groups Sayandev Chatterjee, Jeanette A. Krause, Kumudu Madduma-Liyanage, and William B. Connick pp 4572–4587 DOI: 10.1021/ic202462a

Diverse Closed Cavities in Condensed Rare Earth Metal–Chalcogenide Matrixes: Cs[Lu7Q11] and (ClCs6)[RE21Q34] (RE = Dy, Ho; Q = S, Se, Te) Hua Lin, Long-Hua Li, and Ling Chen pp 4588–4596 DOI: 10.1021/ic202494w

Theoretical Study on the Transition-Metal Oxoboryl Complex: M–BO Bonding Nature, Mechanism of the Formation Reaction, and Prediction of a New Oxoboryl Complex Guixiang Zeng and Shigeyoshi Sakaki pp 4597–4605 DOI: 10.1021/ic202499u

Molecular Magnetism of M6 Hexagon Ring in D3d Symmetric [(MCl)6(XW9O33)2]12– (M = CuII and MnII, X = SbIII and AsIII) Toshihiro Yamase, Hirofumi Ishikawa, Hiroko Abe, Keisuke Fukaya, Hiroyuki Nojiri, and Hideo Takeuchi pp 4606–4619 DOI: 10.1021/ic202513q

Influence of the Solvent and Metal Center on Supramolecular Chirality Induction with Bisporphyrin Tweezer Receptors. Strong Metal Modulation of Effective Molarity Values Inmaculada C. Pintre, Simon Pierrefixe, Alex Hamilton, Virginia Valderrey, Carles Bo, and Pablo Ballester pp 4620–4635 DOI: 10.1021/ic202515v

Molybdenum 1,4-Diazabuta-1,3-diene Tricarbonyl Solvento Complexes Revisited: From Solvatochromism to Attractive Ligand–Ligand Interaction Benjamin Oelkers, Alexander Venker, and Jörg Sundermeyer pp 4636–4643 DOI: 10.1021/ic202517w

A Homochiral Luminescent 2D Porous Coordination Polymer with Collagen-Type Triple Helices Showing Selective Guest Inclusion Biplab Joarder, Abhijeet K. Chaudhari, and Sujit K. Ghosh pp 4644–4649 DOI: 10.1021/ic2025389

Addition of Aluminum and Gallium Species to Aromatic and Alkyl-Substituted 1,4-Diaza-1,3-butadiene Ligands Ana M. Felix, Diane A. Dickie, Ian S. Horne, Giang Page, and Richard A. Kemp pp 4650–4662 DOI: 10.1021/ic202583w

New Iron(II) Spin Crossover Coordination Polymers [Fe(μ-atrz)3]X2·2H2O (X = ClO4¯, BF4¯) and [Fe(μ-atrz)(μ-pyz)(NCS)2]·4H2O with an Interesting Solvent Effect Yu-Chun Chuang, Chi-Tsun Liu, Chou-Fu Sheu, Wei-Lun Ho, Gene-Hsiang Lee, Chih-Cheh Wang, and Yu Wang pp 4663–4671 DOI: 10.1021/ic202626c

Dihydrogen Complexes of Iridium and Rhodium Michael Findlater, Katherine M. Schultz, Wesley H. Bernskoetter, Alison Cartwright-Sykes, D. Michael Heinekey, and Maurice Brookhart pp 4672–4678 DOI: 10.1021/ic202630x

Lanthanide Coordination Polymers with Tetrafluoroterephthalate as a Bridging Ligand: Thermal and Optical Properties Christiane Seidel, Chantal Lorbeer, Joanna Cybińska, Anja-Verena Mudring, and Uwe Ruschewitz pp 4679–4688 DOI: 10.1021/ic202655d

Non-Centrosymmetric Coordination Polymer with a Highly Hindered Octahedral Copper Center Bridged by Mandelate Makoto Moriya, Shingo Tominaga, Takayoshi Hashimoto, Kazuki Tanifuji, Tsuyoshi Matsumoto, Yasuhiro Ohki, Kazuyuki Tatsumi, Junichi Kaneshiro, Yoshiaki Uesu, Wataru Sakamoto, and Toshinobu Yogo pp 4689–4693 DOI: 10.1021/ic202669r

Nonprecious Metal Catalysts for Fuel Cell Applications: Electrochemical Dioxygen Activation by a Series of First Row Transition Metal Tris(2-pyridylmethyl)amine Complexes Ashleigh L. Ward, Lior Elbaz, John B. Kerr, and John Arnold pp 4694–4706 DOI: 10.1021/ic2026957

Infrared Multiple-Photon Dissociation Spectroscopy of Tripositive Ions: Lanthanum–Tryptophan Complexes Udo H. Verkerk, Junfang Zhao, Irine S. Saminathan, Justin Kai-Chi Lau, Jos Oomens, Alan C. Hopkinson, and K.W. Michael Siu pp 4707–4710 DOI: 10.1021/ic2026973

Ni, Pd, Pt, and Ru Complexes of Phosphine-Borate Ligands Stephanie L. Granville, Gregory C. Welch, and Douglas W. Stephan pp 4711–4721 DOI: 10.1021/ic2026895

Oxygen Kinetic Isotope Effects upon Catalytic Water Oxidation by a Monomeric Ruthenium Complex Alfredo M. Angeles-Boza and Justine P. Roth pp 4722–4729 DOI: 10.1021/ic202745n

Synthesis, Crystal Structure, and Physical Properties of the Type-I Clathrate Ba8−δNix□ySi46–x–y U. Aydemir, C. Candolfi, A. Ormeci, H. Borrmann, U. Burkhardt, Y. Oztan, N. Oeschler, M. Baitinger, F. Steglich, and Yu. Grin pp 4730–4741 DOI: 10.1021/ic2027626

Environmentally Friendly, One-Pot Synthesis of Ag Nanoparticle-Decorated Reduced Graphene Oxide Composites and Their Application to Photocurrent Generation Jingqi Tian, Sen Liu, Yingwei Zhang, Haiyan Li, Lei Wang, Yonglan Luo, Abdullah M. Asiri, Abdulrahman O. Al-Youbi, and Xuping Sun pp 4742–4746 DOI: 10.1021/ic300332x

Photochemistry of Tetrasulfur Tetranitride: Laser Flash Photolysis and Quantum Chemical Study Elena A. Pritchina, Daria S. Terpilovskaya, Yuri P. Tsentalovich, Matthew S. Platz, and Nina P. Gritsan pp 4747–4755 DOI: 10.1021/ic3000153

Understanding Ion Sensing in Zn(II) Porphyrins: Spectroscopic and Computational Studies of Nitrite/Nitrate Binding Christi L. Whittington, William A. Maza, H. Lee Woodcock, and Randy W. Larsen pp 4756–4762 DOI: 10.1021/ic300039v

Morphology-Controlled Synthesis of W18O49 Nanostructures and Their Near-Infrared Absorption Properties Chongshen Guo, Shu Yin, Mei Yan, Makoto Kobayashi, Masato Kakihana, and Tsugio Sato pp 4763–4771 DOI: 10.1021/ic300049j

Copper(I) and Silver(I) 2-Methylimidazolates: Extended Isomerism, Isomerization, and Host–Guest Properties Yu Wang, Chun-Ting He, Yi-Jiang Liu, Tian-Qi Zhao, Xiao-Min Lu, Wei-Xiong Zhang, Jie-Peng Zhang, and Xiao-Ming Chen pp 4772–4778 DOI: 10.1021/ic300083k

K3[TbxEu1–xGe3O8(OH)2] (x = 1, 0.88, 0.67, 0): 2D-Layered Lanthanide Germanates with Tunable Photoluminescent Properties Xi Wang, Yu Wang, Qiong Liu, Yi Li, Jihong Yu, and Ruren Xu pp 4779–4783 DOI: 10.1021/ic3005129

Chiral Ni(II) Coordination Polymers: Structure-Driven Effects of Temperature and Polyvinylpyrrolidone Yan-Yan Yin, Jian-Gong Ma, Zheng Niu, Xiao-Chang Cao, Wei Shi, and Peng Cheng pp 4784–4790 DOI: 10.1021/ic300106k

Coordination Chemistry of 4-Methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane: Preparation and Characterization of Ru(II) Complexes Evan E. Joslin, Claire L. McMullin, T. Brent Gunnoe, Thomas R. Cundari, Michal Sabat, and William H. Myers pp 4791–4801 DOI: 10.1021/ic300109b

Crystal Structural, Magnetic, and Transport Properties of Layered Cobalt Oxyfluorides, Sr2CoO3+xF1–x (0 ≤ x ≤ 0.15) Yoshihiro Tsujimoto, Clastin I. Sathish, Kun-Pyo Hong, Kengo Oka, Masaki Azuma, Yanfeng Guo, Yoshitaka Matsushita, Kazunari Yamaura, and Eiji Takayama-Muromachi pp 4802–4809 DOI: 10.1021/ic300116h

Synthesis, Crystal Structure, Chemical Bonding, and Physical Properties of the Ternary Na/Mg Stannide Na2MgSn Takahiro Yamada, Volker L. Deringer, Richard Dronskowski, and Hisanori Yamane pp 4810–4816 DOI: 10.1021/ic300184d

Coordination-Driven Self-Assembly of 2D-Metallamacrocycles Using a New Carbazole-Based Dipyridyl Donor: Synthesis, Characterization, and C60 Binding Study Sankarasekaran Shanmugaraju, Vaishali Vajpayee, Sunmi Lee, Ki-Whan Chi, Peter J. Stang, and Partha Sarathi Mukherjee pp 4817–4823 DOI: 10.1021/ic300199j

Coulombic Aggregations of MnIII salen-Type Complexes and Keggin-Type Polyoxometalates: Isolation of Mn2 Single-Molecule Magnets Yuki Sawada, Wataru Kosaka, Yoshihito Hayashi, and Hitoshi Miyasaka pp 4824–4832 DOI: 10.1021/ic300215q

Influence of Charge on Anion Receptivity in Amide-Based Macrocycles Md. Alamgir Hossain, Sung Ok Kang, Jerry Alan Kut, Victor W. Day, and Kristin Bowman-James pp 4833–4840 DOI: 10.1021/ic300260g

Theoretical Study of Bond Distances and Dissociation Energies of Actinide Oxides AnO and AnO2 Attila Kovács, Peter Pogány, and Rudy J. M. Konings pp 4841–4849 DOI: 10.1021/ic300275y

Simplest Homoleptic Metal-Centered Tetrahedrons, [M(OH2)4]2+, in 1-Ethyl-3-methylimidazolium Tetrafluoroborate Ionic Liquid (M = Co, Ni, Cu) Koichiro Takao, Yurina Tone, Christoph Hennig, Shohei Inoue, and Taro Tsubomura pp 4850–4854 DOI: 10.1021/ic3003433

Dirhodium Paddlewheel with Functionalized Carboxylate Bridges: New Building Block for Self-Assembly and Immobilization on Solid Support D. Krishna Kumar, Alexander S. Filatov, Margaret Napier, Jinyu Sun, Evgeny V. Dikarev, and Marina A. Petrukhina pp 4855–4861 DOI: 10.1021/ic300382j

Two Acentric Mononuclear Molecular Complexes with Unusual Magnetic and Ferroelectric Properties Fang-Hua Zhao, Yun-Xia Che, and Ji-Min Zheng , Fernande Grandjean and Gary J. Long pp 4862–4868 DOI: 10.1021/ic300394c

Steric Effects on Uranyl Complexation: Synthetic, Structural, and Theoretical Studies of Carbamoyl Pyrazole Compounds of the Uranyl(VI) Ion Debasish Das, Shanmugaperumal Kannan, Dilip K. Maity, and Michael G. B. Drew pp 4869–4876 DOI: 10.1021/ic300398a

Reduction of Nitrous Acid with a Macrocyclic Rhodium Complex That Acts As a Functional Model of Nitrite Reductase Kathleen E. Kristian and Andreja Bakac pp 4877–4882 DOI: 10.1021/ic300597n

Correction to Binding and Removal of Sulfate, Phosphate, Arsenate, Tetrachloromercurate, and Chromate in Aqueous Solution by Means of an Activated Carbon Functionalized with a Pyrimidine-Based Anion Receptor (HL). Crystal Structures of [H3L(HgCl4)]·H2O and [H3L(HgBr4)]·H2O Showing Anion−π Interactions Paloma Arranz, Antonio Bianchi, Rafael Cuesta, Claudia Giorgi, M. Luz Godino, M. D. Gutiérrez, Rafael López, and Antonio Santiago pp 4883–4883 DOI: 10.1021/ic300549r

Issue 09

Uranyl Heteropolyoxometalate: Synthesis, Structure, and Spectroscopic Properties Pius O. Adelani, Allen G. Oliver, and Thomas E. Albrecht-Schmitt pp 4885–4887 DOI: 10.1021/ic300035n

Two Novel Heterometallic Chains Featuring MnII and NaI Ions in Trigonal-Prismatic Geometries Alternately Linked to Octahedral MnIV Ions: Synthesis, Structures, and Magnetic Behavior Sandip Mukherjee, Yogesh P. Patil, and Partha Sarathi Mukherjee pp 4888–4890 DOI: 10.1021/ic300209y

Terbium(III), Europium(III), and Mixed Terbium(III)–Europium(III) Mucicate Frameworks: Hydrophilicity and Stoichiometry-Dependent Color Tunability Sudip Mohapatra, Sangita Adhikari, Hiranya Riju, and Tapas Kumar Maji pp 4891–4893 DOI: 10.1021/ic300237e

Structure and Dynamics of Dodecaborate Clusters in Water Khadga Karki, Detlef Gabel, and Danilo Roccatano pp 4894–4896 DOI: 10.1021/ic300223z

A Polyoxometalate–Cyanometalate Multilayered Coordination Network Jean-Daniel Compain, Koji Nakabayashi, and Shin-ichi Ohkoshi pp 4897–4899 DOI: 10.1021/ic300263f

Monomeric Platinum(II) Hydroxides Supported by Sterically Dominant α-Diimine Ligands Tracy L. Lohr, Warren E. Piers, and Masood Parvez pp 4900–4902 DOI: 10.1021/ic300337a

Syntheses and Structures of Three Complexes of Formulas [L3Co(μ2-O2P(Bn)2)3CoL′][L″], Featuring Octahedral and Tetrahedral Cobalt(II) Geometries; Variable-Temperature Magnetic Susceptibility Measurement and Analysis on [(py)3Co(μ2-O2PBn2)3Co(py)][ClO4] John S. Maass, Matthias Zeller, Tanya M. Breault, Bart M. Bartlett, Hiroshi Sakiyama, and Rudy L. Luck pp 4903–4905 DOI: 10.1021/ic3004799

[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes Maria-Gabriela Alexandru, Diana Visinescu, Augustin M. Madalan, Francesc Lloret, Miguel Julve, and Marius Andruh pp 4906–4908 DOI: 10.1021/ic300544m

Oxidation of Phenol by Tris(1,10-phenanthroline)osmium(III) Na Song and David M. Stanbury pp 4909–4911 DOI: 10.1021/ic300562u

Grid Expansion: a Rhombiclike [L4Fe2(Ag2)2] Complex Containing Ag2 Dumbbells at Two Vertices Benjamin Schneider, Serhiy Demeshko, Sebastian Dechert, and Franc Meyer pp 4912–4914 DOI: 10.1021/ic300563s

β-Technetium Trichloride: Formation, Structure, and First-Principles Calculations Frederic Poineau, Erik V. Johnstone, Philippe F. Weck, Paul M. Forster, Eunja Kim, Kenneth R. Czerwinski, and Alfred P. Sattelberger pp 4915–4917 DOI: 10.1021/ic300612k

Gaseous Vanadium Molybdate and Tungstates: Thermodynamic Properties and Structures Anastasia O. Gunina, Sergey I. Lopatin, and Sergey M. Shugurov pp 4918–4924 DOI: 10.1021/ic201644f

From Lithium Bis(trimethylsilyl)amide with Cyanoamine into Triazine Compounds: Synthesis and Structures of Lithium 6-((Trimethylsilyl)amido)-2,4-bis(dimethylamino)[1,3,5]triazines and Their Manganese and Cobalt Complexes Meisu Zhou, Xiaoli Qiao, Hongbo Tong, Tao Gong, Mei Fan, Qiaokun Yang, Qingchen Dong, Jianbin Chao, Zhiqiang Guo, and Diansheng Liu pp 4925–4930 DOI: 10.1021/ic201629a

New P2 Compound with Brucite-Like Layers: Potassium Lithiostannate Igor L. Shukaev and Vera V. Butova pp 4931–4937 DOI: 10.1021/ic201952x

Mechanism of Water Oxidation to Molecular Oxygen with Osmocene as Photocatalyst: A Theoretical Study Yue Chen, Juan Han, and Wei-Hai Fang pp 4938–4946 DOI: 10.1021/ic202097c

Triple Framework Interpenetration and Immobilization of Open Metal Sites within a Microporous Mixed Metal–Organic Framework for Highly Selective Gas Adsorption Zhangjing Zhang, Shengchang Xiang, Kunlun Hong, Madhab, C. Das, Hadi D. Arman, Maya Garcia, Jalal U. Mondal, K. Mark Thomas, and Banglin Chen pp 4947–4953 DOI: 10.1021/ic2021275

High Spin Co(I): High-Frequency and -Field EPR Spectroscopy of CoX(PPh3)3 (X = Cl, Br) J. Krzystek, Andrew Ozarowski, S. A. Zvyagin, and Joshua Telser pp 4954–4964 DOI: 10.1021/ic202185x

On the Structure of β-Molybdenum Dichloride Frederic Poineau, Erik V. Johnstone, Philippe F. Weck, Eunja Kim, Steven D. Conradson, Alfred P. Sattelberger, and Kenneth R. Czerwinski pp 4965–4971 DOI: 10.1021/ic202680j

Speciation of Copper(II) Complexes in an Ionic Liquid Based on Choline Chloride and in Choline Chloride/Water Mixtures Peter De Vreese, Neil R. Brooks, Kristof Van Hecke, Luc Van Meervelt, Edward Matthijs, Koen Binnemans, and Rik Van Deun pp 4972–4981 DOI: 10.1021/ic202341m

Preparations, Crystal Structures, and Magnetic Properties of N,N-Dipyridylaminoxyl as a New Magnetic Coupler and Its One-Dimensional Cobalt(II) Chains Kensuke Murashima, Takeaki Watanabe, Shinji Kanegawa, Daisuke Yoshihara, Yuji Inagaki, Satoru Karasawa, and Noboru Koga pp 4982–4993 DOI: 10.1021/ic202397m

Imino–Phenolic–Pyridyl Conjugates of Calix[4]arene (L1 and L2) as Primary Fluorescence Switch-on Sensors for Zn2+ in Solution and in HeLa Cells and the Recognition of Pyrophosphate and ATP by [ZnL2] Rakesh Kumar Pathak, Vijaya Kumar Hinge, Ankit Rai, Dulal Panda, and Chebrolu Pulla Rao pp 4994–5005 DOI: 10.1021/ic202426v

Role of Fe(IV)-Oxo Intermediates in Stoichiometric and Catalytic Oxidations Mediated by Iron Pyridine-Azamacrocycles Wanhua Ye, Douglas M. Ho, Simone Friedle, Taryn D. Palluccio, and Elena V. Rybak-Akimova pp 5006–5021 DOI: 10.1021/ic202435r

Polarized Micropores in a Novel 3D Metal–Organic Framework for Selective Adsorption Properties Chengli Jiao, Jian Zhang, Shuang Wang, Xiaoliang Si, Wansheng You, Zhangpeng Li, Zhonggang Wang, Hao Yu, Zelimir Gabelica, Huai-Ying Zhou, Lixian Sun, and Fen Xu pp 5022–5025 DOI: 10.1021/ic202769e

Preparation, Structure, and Properties of Tetranuclear Vanadium(III) and (IV) Complexes Bridged by Diphenyl Phosphate or Phosphate Kyouhei Sato, Tetsuya Ohnuki, Haruka Takahashi, Yoshitaro Miyashita, Koichi Nozaki, and Kan Kanamori pp 5026–5036 DOI: 10.1021/ic2024617

Synthesis and Photophysical Properties of Cyclometalated Platinum(II) 1,2-Benzenedithiolate Complexes and Heterometallic Derivatives Obtained from the Addition of [Au(PCy3)]+ Units Fabio Juliá, Peter G. Jones, and Pablo González-Herrero pp 5037–5049 DOI: 10.1021/ic202465k

Synthesis, Crystal Structure, and Luminescent Properties of 2-(2,2,2-Trifluoroethyl)-1-indone Lanthanide Complexes Jingya Li, Hongfeng Li, Pengfei Yan, Peng Chen, Guangfeng Hou, and Guangming Li pp 5050–5057 DOI: 10.1021/ic202473b

Di- and Tetra-Nuclear Copper(II), Nickel(II), and Cobalt(II) Complexes of Four Bis-Tetradentate Triazole-Based Ligands: Synthesis, Structure, and Magnetic Properties Juan Olguín, Marguerite Kalisz, Rodolphe Clérac, and Sally Brooker pp 5058–5069 DOI: 10.1021/ic202537c

Sensitivity of Silver(I) Complexes of a Pyrimidine–Hydrazone Ligand to Solvent, Counteranion, and Metal-to-Ligand Ratio Changes Daniel J. Hutchinson, Scott A. Cameron, Lyall R. Hanton, and Stephen C. Moratti pp 5070–5081 DOI: 10.1021/ic2025582

Effect of Axially Projected Oligothiophene Pendants and Nitro-Functionalized Diimine Ligands on the Lowest Excited State in Cationic Ir(III) bis-Cyclometalates Kyle R. Schwartz, Raghu Chitta, Jon N. Bohnsack, Darren J. Ceckanowicz, Pere Miró, Christopher J. Cramer, and Kent R. Mann pp 5082–5094 DOI: 10.1021/ic202573y

Magnetic Interactions in A-Site-Ordered Perovskites LnCu3(Ge3/4Ga1/4)4O12 (Ln = La, Dy) Takashi Saito, Ryuta Yamada, and Yuichi Shimakawa pp 5095–5098 DOI: 10.1021/ic202582z

Mononuclear Gold(I) Acetylide Complexes with Urea Group: Synthesis, Characterization, Photophysics, and Anion Sensing Properties Yu-Peng Zhou, Mei Zhang, Yu-Hao Li, Qi-Rui Guan, Fang Wang, Zhuo-Jia Lin, Chi-Keung Lam, Xiao-Long Feng, and Hsiu-Yi Chao pp 5099–5109 DOI: 10.1021/ic202608r

Cluster-Based Networks: 1D and 2D Coordination Polymers Based on {MnFe2(μ3-O)}-Type Clusters Galina M. Dulcevscaia, Irina G. Filippova, Manfred Speldrich, Jan van Leusen, Victor Ch. Kravtsov, Svetlana G. Baca, Paul Kögerler, Shi-Xia Liu, and Silvio Decurtins pp 5110–5117 DOI: 10.1021/ic202644t

Metal–Organic Frameworks with Phosphotungstate Incorporated for Hydrolytic Cleavage of a DNA-Model Phosphodiester Qiuxia Han, Lejie Zhang, Cheng He, Jiangyang Niu, and Chunying Duan pp 5118–5127 DOI: 10.1021/ic202685e

Measured and Calculated Oxidation Potentials of 1-X-12-Y-CB11Me10– Anions Abdul Wahab, Brian Stepp, Christos Douvris, Michal Valášek, Jan Štursa, Jiřı́ Klı́ma, Mari-Carmen Piqueras, Raül Crespo, Jiřı́ Ludvı́k, and Josef Michl pp 5128–5137 DOI: 10.1021/ic2026939

Titanium(IV) Complexes of Disulfide-Linked Schiff Bases Alberto Donzelli, Imir Metushi, and Pierre G. Potvin pp 5138–5145 DOI: 10.1021/ic202709x

Mo-Substituted Keggin Tungstosilicate Microtubes: Preparation and Characterization Yan Shen, Jun Peng, Huanqiu Zhang, Xia Yu, and Alan M. Bond pp 5146–5151 DOI: 10.1021/ic2027412

Halogen Oxidation and Halogen Photoelimination Chemistry of a Platinum–Rhodium Heterobimetallic Core Timothy R. Cook, Brian D. McCarthy, Daniel A. Lutterman, and Daniel G. Nocera pp 5152–5163 DOI: 10.1021/ic300004x

Low-Temperature Diffusion of Oxygen through Ordered Carbon Vacancies in Zr2Cx: The Formation of Ordered Zr2CxOy Wentao Hu, Jianyong Xiang, Shaocun Liu, Yang Zhang, Cankun Chen, Pang Wang, Haitao Wang, Fusheng Wen, Bo Xu, Julong He, Dongli Yu, Yongjun Tian, and Zhongyuan Liu pp 5164–5172 DOI: 10.1021/ic300014a

Model Studies of Methyl CoM Reductase: Methane Formation via CH3–S Bond Cleavage of Ni(I) Tetraazacyclic Complexes Having Intramolecular Methyl Sulfide Pendants Jun-ichi Nishigaki, Tsuyoshi Matsumoto, and Kazuyuki Tatsumi pp 5173–5187 DOI: 10.1021/ic300017k

Solid-State Ligand-Driven Light-Induced Spin Change at Ambient Temperatures in Bis(dipyrazolylstyrylpyridine)iron(II) Complexes Kazuhiro Takahashi, Yuta Hasegawa, Ryota Sakamoto, Michihiro Nishikawa, Shoko Kume, Eiji Nishibori, and Hiroshi Nishihara pp 5188–5198 DOI: 10.1021/ic300030b

2,6-Bis(5-(2,2-dimethylpropyl)-1H-pyrazol-3-yl)pyridine as a Ligand for Efficient Actinide(III)/Lanthanide(III) Separation Antje Bremer, Christian M. Ruff, Denise Girnt, Udo Müllich, Jörg Rothe, Peter W. Roesky, Petra J. Panak, Alexei Karpov, Thomas J. J. Müller, Melissa A. Denecke, and Andreas Geist pp 5199–5207 DOI: 10.1021/ic3000526

Tunable Fluorescent/Phosphorescent Platinum(II) Porphyrin–Fluorene Copolymers for Ratiometric Dual Emissive Oxygen Sensing Haifeng Xiang, Li Zhou, Yan Feng, Jinghui Cheng, Di Wu, and Xiangge Zhou pp 5208–5212 DOI: 10.1021/ic300040n

Synthesis, Structure, and Reactivity of Dinuclear Nickel Amino-Thiophenolate Complexes Bearing Bridging VO2(OH)2–and VO2(OR)2– Coligands Vasile Lozan, Jochen Lach, and Berthold Kersting pp 5213–5223 DOI: 10.1021/ic300085f

Topologically Unique Heterometallic CuII/Li Coordination Polymers Self-Assembled from N,N-bis(2-Hydroxyethyl)-2-aminoethanesulfonic Acid Biobuffer: Versatile Catalyst Precursors for Mild Hydrocarboxylation of Alkanes to Carboxylic Acids Marina V. Kirillova, Alexander M. Kirillov, André N. C. Martins, Claudia Graiff, Antonio Tiripicchio, and Armando J. L. Pombeiro pp 5224–5234 DOI: 10.1021/ic300123d

Novel Coordination Frameworks Incorporating the 4,4′-Bipyrazolyl Ditopic Ligand Claudio Pettinari, Aurel Tăbăcaru, Ishtvan Boldog, Konstantin V. Domasevitch, Simona Galli, and Norberto Masciocchi pp 5235–5245 DOI: 10.1021/ic3001416

A New Partially Deprotonated Mixed-Valence Manganese(II,III) Hydroxide–Arsenate with Electronic Conductivity: Magnetic Properties of High- and Room-Temperature Sarkinite Imanol de Pedro, Jose M. Rojo, Jordi Rius, Oriol Vallcorba, Idoia Ruiz de Larramendi, Jesús Rodríguez Fernández, Luis Lezama, and Teofilo Rojo pp 5246–5256 DOI: 10.1021/ic3001569

Direct Evidence from Electron Paramagnetic Resonance for Additional Configurations in Uncommon Paddlewheel Re27+ Units Surrounded by an Unsymmetrical Bicyclic Guanidinate Gina M. Chiarella, F. Albert Cotton, Naresh S. Dalal, Carlos A. Murillo, Zhenxing Wang, and Mark D. Young pp 5257–5263 DOI: 10.1021/ic300169f

Reversible Interconversion of a Divalent Vanadium Bronze between δ and β Quasi-1D Structures Peter M. Marley and Sarbajit Banerjee pp 5264–5269 DOI: 10.1021/ic300191y

Where Does the Metal Cation Stay in Gd@C2v(9)-C82? A Single-Crystal X-ray Diffraction Study Mitsuaki Suzuki, Xing Lu, Satoru Sato, Hidefumi Nikawa, Naomi Mizorogi, Zdenek Slanina, Takahiro Tsuchiya, Shigeru Nagase, and Takeshi Akasaka pp 5270–5273 DOI: 10.1021/ic300186y

Preparation, Stability, and Structural Characterization of Plutonium(VII) in Alkaline Aqueous Solution Mark R. Antonio, C. W. Williams, James A. Sullivan, S. Skanthakumar, Yung-Jin Hu, and L. Soderholm pp 5274–5281 DOI: 10.1021/ic300205h

Mechanism of Atmospheric CO2 Fixation in the Cavities of a Dinuclear Cryptate Morad M. El-Hendawy, Niall J. English, and Damian A. Mooney pp 5282–5288 DOI: 10.1021/ic300224w

Compression of Silver Sulfide: X-ray Diffraction Measurements and Total-Energy Calculations David Santamarı́a-Pérez, Miriam Marqués, Raquel Chuliá-Jordán, José M. Menendez, Oscar Gomis, Javier Ruiz-Fuertes, Juan A. Sans, Daniel Errandonea, and José M. Recio pp 5289–5298 DOI: 10.1021/ic300236p

Crystal Structure and Physical Properties of the New One-Dimensional Metal Ba2Cu7–xTe6 Bryan A. Kuropatwa, Abdeljalil Assoud, and Holger Kleinke pp 5299–5304 DOI: 10.1021/ic300239c

Nitrogen-Rich 5-(1-Methylhydrazinyl)tetrazole and its Copper and Silver Complexes Guo-Hong Tao, Damon A. Parrish, and Jean’ne M. Shreeve pp 5305–5312 DOI: 10.1021/ic300242e

Na2/7Gd4/7MoO4: a Modulated Scheelite-Type Structure and Conductivity Properties V. Morozov, A. Arakcheeva, B. Redkin, V. Sinitsyn, S. Khasanov, E. Kudrenko, M. Raskina, O. Lebedev, and G. Van Tendeloo pp 5313–5324 DOI: 10.1021/ic300221m

Structure and Magnetism of the Topotactically Reduced Oxychloride Sr4Mn3O6.5Cl2 Fabio Denis Romero and Michael A. Hayward pp 5325–5331 DOI: 10.1021/ic300258f

A Ferromagnetic Methoxido-Bridged Mn(III) Dimer and a Spin-Canted Metamagnetic μ1,3-Azido-Bridged Chain Subrata Naiya, Saptarshi Biswas, Michael G. B. Drew, Carlos J. Gómez-García, and Ashutosh Ghosh pp 5332–5341 DOI: 10.1021/ic300274n

Photoinduced Electron Transfer in Os(terpyridine)-biphenylene-(bi)pyridinium Assemblies Jérôme Fortage, Fausto Puntoriero, Fabien Tuyèras, Grégory Dupeyre, Antonino Arrigo, Ilaria Ciofini, Philippe P. Lainé, and Sebastiano Campagna pp 5342–5352 DOI: 10.1021/ic300297p

Transmission of Electronic Effects through the {closo-1-CB9} and {closo-1-CB11} Cages: Apparent Dissociation Constants for Series of [closo-1-CB9H8-1-COOH-10-X] and [closo-1-CB11H10-1-COOH-12-X] Acids Jacek G. Pecyna, Bryan Ringstrand, and Piotr Kaszyński pp 5353–5359 DOI: 10.1021/ic300298e

Synthesis and Physical Properties of K4[Fe(C5O5)2(H2O)2](HC5O5)2·4H2O (C5O52– = Croconate): A Rare Example of Ferromagnetic Coupling via H-bonds Matteo Atzori, Elisa Sessini, Flavia Artizzu, Luca Pilia, Angela Serpe, Carlos J. Gómez-García, Carlos Giménez-Saiz, Paola Deplano, and Maria Laura Mercuri pp 5360–5367 DOI: 10.1021/ic300331e

Amorphous/Crystalline (A/C) Thermodynamic “Rules of Thumb”: Estimating Standard Thermodynamic Data for Amorphous Materials Using Standard Data for Their Crystalline Counterparts Diane Holland and H. Donald Brooke Jenkins pp 5368–5376 DOI: 10.1021/ic300346t

New Layered Compounds with Honeycomb Ordering: Li3Ni2BiO6, Li3NiM′BiO6 (M′ = Mg, Cu, Zn), and the Delafossite Ag3Ni2BiO6 Romain Berthelot, Whitney Schmidt, Sean Muir, James Eilertsen, Laetitia Etienne, A. W. Sleight, and M. A. Subramanian pp 5377–5385 DOI: 10.1021/ic300351t

Photoisomerization and Proton-Coupled Electron Transfer (PCET) Promoted Water Oxidation by Mononuclear Cyclometalated Ruthenium Catalysts Sumanta Kumar Padhi, Ryoichi Fukuda, Masahiro Ehara, and Koji Tanaka pp 5386–5392 DOI: 10.1021/ic3003542

Influence of the Cation Size on the Framework Structures and Space Group Centricities in AMo2O5(SeO3)2 (A = Sr, Pb, and Ba) Seung-Jin Oh, Dong Woo Lee, and Kang Min Ok pp 5393–5399 DOI: 10.1021/ic3003564

Nitric Oxide Turn-on Fluorescent Probe Based on Deamination of Aromatic Primary Monoamines Tsun-Wei Shiue, Yen-Hao Chen, Chi-Ming Wu, Gyan Singh, Hsing-Yin Chen, Chen-Hsiung Hung, Wen-Feng Liaw, and Yun-Ming Wang pp 5400–5408 DOI: 10.1021/ic300379u

Dinuclear Cu(II) Complexes of Isomeric Bis-(3-acetylacetonate)benzene Ligands: Synthesis, Structure, and Magnetic Properties Marzio Rancan, Alessandro Dolmella, Roberta Seraglia, Simonetta Orlandi, Silvio Quici, Lorenzo Sorace, Dante Gatteschi, and Lidia Armelao pp 5409–5416 DOI: 10.1021/ic3003806

Liquid-Crystalline Zinc(II) and Iron(II) Alkyltriazoles One-Dimensional Coordination Polymers Pauline Grondin, Diana Siretanu, Olivier Roubeau, Marie-France Achard, and Rodolphe Clérac pp 5417–5426 DOI: 10.1021/ic300404r

Ruthenium(II) Thiol and H2S Complexes: Synthesis, Characterization, and Thermodynamic Properties Erin S. F. Ma, Steven J. Rettig, Brian O. Patrick, and Brian R. James pp 5427–5434 DOI: 10.1021/ic3004118

Fluoride Bridges as Structure-Directing Motifs in 3d-4f Cluster Chemistry Torben Birk, Kasper S. Pedersen, Christian Aa. Thuesen, Thomas Weyhermüller, Magnus Schau-Magnussen, Stergios Piligkos, Högni Weihe, Susanne Mossin, Marco Evangelisti, and Jesper Bendix pp 5435–5443 DOI: 10.1021/ic300421x

Structural Basis for Bifunctional Zinc(II) Macrocyclic Complex Recognition of Thymine Bulges in DNA Imee Marie A. del Mundo, Kevin E. Siters, Matthew A. Fountain, and Janet R. Morrow pp 5444–5457 DOI: 10.1021/ic3004245

Femtomolar Ln(III) Affinity in Peptide-Based Ligands Containing Unnatural Chelating Amino Acids Agnieszka Niedźwiecka, Federico Cisnetti, Colette Lebrun, and Pascale Delangle pp 5458–5464 DOI: 10.1021/ic300448y

Organophosphazenes. 26. Factors Controlling the Pathways Observed in the Reactions of Ethynyl Lithium Reagents with Hexafluorocyclotriphosphazene Maneesh Bahadur and Christopher W. Allen pp 5465–5470 DOI: 10.1021/ic300481e

Expanding the Steric Coverage Offered by Bis(amidosilyl) Chelates: Isolation of Low-Coordinate N-Heterocyclic Germylene Complexes Sean K. Liew, S. M. Ibrahim Al-Rafia, James T. Goettel, Paul A. Lummis, Sean M. McDonald, Leah J. Miedema, Michael J. Ferguson, Robert McDonald, and Eric Rivard pp 5471–5480 DOI: 10.1021/ic300495k

Giant Core–Shell Nanospherical Clusters Composed of 32 Co or 32 Ni Atoms Held by 6 p-tert-Butylthiacalix[4]arene Units Alexandre Gehin, Sylvie Ferlay, Jack M. Harrowfield, D. Fenske, Nathalie Kyritsakas, and Mir Wais Hosseini pp 5481–5486 DOI: 10.1021/ic300550v

Exchange Coupling Mediated by N–H···Cl Hydrogen Bonds: Experimental and Theoretical Study of the Frustrated Magnetic System in Bis(o-phenylenediamine)nickel(II) Chloride Roger D. Willett, Carlos J. Gómez-García, Brendan Twamley, Silvia Gómez-Coca, and Eliseo Ruiz pp 5487–5493 DOI: 10.1021/ic3007124

Correction to Volume-Based Thermoelasticity: Consequences of the (Near) Proportionality of Isothermal Compressibility to Formula-Unit Volume H. Donald Brooke Jenkins, Leslie Glasser, and Joe Lee pp 5494–5494 DOI: 10.1021/ic300693q

Issue 10

Remembering Herb Richard Eisenberg pp 5495–5496 DOI: 10.1021/ic3007348

Cobalt Complexes Appended with p- and m-Carboxylates: Two Unique {Co3+–Cd2+} Networks and Their Regioselective and Size-Selective Heterogeneous Catalysis Girijesh Kumar and Rajeev Gupta pp 5497–5499 DOI: 10.1021/ic202594s

Gold(III) Diazonium Complexes for Electrochemical Reductive Grafting Atiya T. Overton and Ahmed A. Mohamed pp 5500–5502 DOI: 10.1021/ic300307z

High Nuclearity in Azido/Oximate Chemistry: Ni14 and Ni13 Clusters with S = 6 and 9 Ground States Jordi Esteban, Laura Alcázar, Maria Torres-Molina, Montserrat Monfort, Mercè Font-Bardia, and Albert Escuer pp 5503–5505 DOI: 10.1021/ic3004036

Hierarchical Helix of Helix in the Crystal: Formation of Variable-Pitch Helical π-Stacked Array of Single-Helical Dinuclear Metal Complexes Shigehisa Akine, Hiroki Nagumo, and Tatsuya Nabeshima pp 5506–5508 DOI: 10.1021/ic3004273

Dumbbells of Five-Connected Ge Atoms and Superconductivity in CaGe3 Walter Schnelle, Alim Ormeci, Aron Wosylus, Katrin Meier, Yuri Grin, and Ulrich Schwarz pp 5509–5511 DOI: 10.1021/ic300576a

Mixed Ligand Copper(II) Complexes of N,N-Bis(benzimidazol-2-ylmethyl)amine (BBA) with Diimine Co-Ligands: Efficient Chemical Nuclease and Protease Activities and Cytotoxicity Rangasamy Loganathan, Sethu Ramakrishnan, Eringathodi Suresh, Anvarbatcha Riyasdeen, Mohamad Abdulkadhar Akbarsha, and Mallayan Palaniandavar pp 5512–5532 DOI: 10.1021/ic2017177

Co2+/Co+ Redox Tuning in Methyltransferases Induced by a Conformational Change at the Axial Ligand Manoj Kumar, Neeraj Kumar, Hajime Hirao, and Pawel M. Kozlowski pp 5533–5538 DOI: 10.1021/ic201970k

Isostructural Dinuclear Phenoxo-/Acetato-Bridged Manganese(II), Cobalt(II), and Zinc(II) Complexes with Labile Sites: Kinetics of Transesterification of 2-Hydroxypropyl-p-nitrophenylphosphate Himanshu Arora, Suman K. Barman, Francesc Lloret, and Rabindranath Mukherjee pp 5539–5553 DOI: 10.1021/ic201971t

Lithium Storage Mechanisms and Effect of Partial Cobalt Substitution in Manganese Carbonate Electrodes Shadi Mirhashemihaghighi, Bernardo León, Carlos Pérez Vicente, José L. Tirado, Radostina Stoyanova, Meglena Yoncheva, Ekaterina Zhecheva, Regino Sáez Puche, Elena M. Arroyo, and Julio Romero de Paz pp 5554–5560 DOI: 10.1021/ic3004382

Computational Studies of the Metal-Binding Site of the Wild-Type and the H46R Mutant of the Copper, Zinc Superoxide Dismutase Raúl Mera-Adasme, Fernando Mendizábal, Mauricio Gonzalez, Sebastián Miranda-Rojas, Claudio Olea-Azar, and Dage Sundholm pp 5561–5568 DOI: 10.1021/ic202416d

Vapochromic and Mechanochromic Phosphorescence Materials Based on a Platinum(II) Complex with 4-Trifluoromethylphenylacetylide Xu Zhang, Jin-Yun Wang, Jun Ni, Li-Yi Zhang, and Zhong-Ning Chen pp 5569–5579 DOI: 10.1021/ic202421d

A Series of Oxyimine-Based Macrocyclic Dinuclear Zinc(II) Complexes Enhances Phosphate Ester Hydrolysis, DNA Binding, DNA Hydrolysis, and Lactate Dehydrogenase Inhibition and Induces Apoptosis Sellamuthu Anbu, Subban Kamalraj, Babu Varghese, Johnpaul Muthumary, and Muthusamy Kandaswamy pp 5580–5592 DOI: 10.1021/ic202451e

Computational Insight into a Gold(I) N-Heterocyclic Carbene Mediated Alkyne Hydroamination Reaction Madanakrishna Katari, Mitta Nageswar Rao, Gopalan Rajaraman, and Prasenjit Ghosh pp 5593–5604 DOI: 10.1021/ic2024605

Multicomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages Vadapalli Chandrasekhar, Loganathan Nagarajan, Sakiat Hossain, Kandasamy Gopal, Surajit Ghosh, and Sandeep Verma pp 5605–5616 DOI: 10.1021/ic202510d

New Metal-Only Lewis Pairs: Elucidating the Electronic Influence of N-Heterocyclic Carbenes and Phosphines on the Dative Pt-Al Bond Jürgen Bauer, Rüdiger Bertermann, Holger Braunschweig, Katrin Gruss, Florian Hupp, and Thomas Kramer pp 5617–5626 DOI: 10.1021/ic300531b

Photochromic Metal Complexes: Photoregulation of both the Nonlinear Optical and Luminescent Properties Lucie Ordronneau, Hiroyuki Nitadori, Isabelle Ledoux, Anu Singh, J. A. Gareth Williams, Munetaka Akita, Véronique Guerchais, and Hubert Le Bozec pp 5627–5636 DOI: 10.1021/ic2025457

Nitrosation, Thiols, and Hemoglobin: Energetics and Kinetics Willem H. Koppenol pp 5637–5641 DOI: 10.1021/ic202561f

Metal Ions as Cofactors for Aggregation of Therapeutic Peptide Salmon Calcitonin Neeraj Rastogi, Kalyan Mitra, Dinesh Kumar, and Raja Roy pp 5642–5650 DOI: 10.1021/ic202604v

Ferrocene-Decorated (Phthalocyaninato)(Porphyrinato) Double- and Triple-Decker Rare Earth Complexes: Synthesis, Structure, and Electrochemical Properties Peihua Zhu, Xiuwen Zhang, Hailong Wang, Yuexing Zhang, Yongzhong Bian, and Jianzhuang Jiang pp 5651–5659 DOI: 10.1021/ic202613r

Ground-State and Excited-State Structures of Tungsten–Benzylidyne Complexes Benjamin M. Lovaasen, Jenny V. Lockard, Brian W. Cohen, Shujiang Yang, Xiaoyi Zhang, Cheslan K. Simpson, Lin X. Chen, and Michael D. Hopkins pp 5660–5670 DOI: 10.1021/ic202622s

Single-Atom Ligand Changes Affect Breathing in an Extended Metal–Organic Framework Phuong V. Dau, Min Kim, Sergio J. Garibay, Frédéric H. L. Münch, Curtis E. Moore, and Seth M. Cohen pp 5671–5676 DOI: 10.1021/ic202683s

Chemical Modeling of Mixed Occupations and Site Preferences in Anisotropic Crystal Structures: Case of Complex Intermetallic Borides Volker L. Deringer, Christian Goerens, Marco Esters, Richard Dronskowski, and Boniface P. T. Fokwa pp 5677–5685 DOI: 10.1021/ic300023t

Low-Dimensional Porous Coordination Polymers Based on 1,2-Bis(4-pyridyl)hydrazine: From Structure Diversity to Ultrahigh CO2/CH4 Selectivity Xiao-Min Liu, Rui-Biao Lin, Jie-Peng Zhang, and Xiao-Ming Chen pp 5686–5692 DOI: 10.1021/ic300097y

MIIIDyIII3 (M = FeIII, CoIII) Complexes: Three-Blade Propellers Exhibiting Slow Relaxation of Magnetization Gong-Feng Xu, Patrick Gamez, Jinkui Tang, Rodolphe Clérac, Yun-Nan Guo, and Yang Guo pp 5693–5698 DOI: 10.1021/ic300126q

Nickel(II)-Induced Excimer Formation of a Naphthalene-Based Fluorescent Probe for Living Cell Imaging Arnab Banerjee, Animesh Sahana, Subarna Guha, Sisir Lohar, Ipsit Hauli, Subhra Kanti Mukhopadhyay, Jesús Sanmartín Matalobos, and Debasis Das pp 5699–5704 DOI: 10.1021/ic300130y

Structures of d4 MH3X: a Computational Study of the Influence of the Metal and the Ligands Amalia I. Poblador-Bahamonde, Christophe Raynaud, and Odile Eisenstein pp 5705–5715 DOI: 10.1021/ic3001448

Computational Mechanistic Study of the Hydrogenation of Carbonate to Methanol Catalyzed by the RuIIPNN Complex Haixia Li, Mingwei Wen, and Zhi-Xiang Wang pp 5716–5727 DOI: 10.1021/ic300175b

Synthesis and Structure of (Ph4P)2MCl6 (M = Ti, Zr, Hf, Th, U, Np, Pu) Stefan G. Minasian, Kevin S. Boland, Russell K. Feller, Andrew J. Gaunt, Stosh A. Kozimor, Iain May, Sean D. Reilly, Brian L. Scott, and David K. Shuh pp 5728–5736 DOI: 10.1021/ic300179d

New Family of Thiocyanate-Bridged Re(IV)-SCN-M(II) (M = Ni, Co, Fe, and Mn) Heterobimetallic Compounds: Synthesis, Crystal Structure, and Magnetic Properties Ricardo González, Alvaro Acosta, Raúl Chiozzone, Carlos Kremer, Donatella Armentano, Giovanni De Munno, Miguel Julve, Francesc Lloret, and Juan Faus pp 5737–5747 DOI: 10.1021/ic300200k

Magnetic Circular Dichroism Spectrum of the Molybdenum(V) Complex [Mo(O)Cl3dppe]: C-Term Signs and Intensities for Multideterminant Excited Doublet States Anne Westphal, Henning Broda, Philipp Kurz, Frank Neese, and Felix Tuczek pp 5748–5763 DOI: 10.1021/ic300201t

Synthesis, Characterization, and Lactide Polymerization Activity of Group 4 Metal Complexes Containing Two Bis(phenolate) Ligands Andreas Sauer, Jean-Charles Buffet, Thomas P. Spaniol, Haruki Nagae, Kazushi Mashima, and Jun Okuda pp 5764–5770 DOI: 10.1021/ic300271h

A5Sn2As6 (A = Sr, Eu). Synthesis, Crystal and Electronic Structure, and Thermoelectric Properties Jian Wang, Sheng-Qing Xia, and Xu-Tang Tao pp 5771–5778 DOI: 10.1021/ic300308w

High-Pressure Investigation of Li2MnSiO4 and Li2CoSiO4 Electrode Materials for Lithium-Ion Batteries D. Santamaría-Pérez, U. Amador, J. Tortajada, R. Dominko, and M. E. Arroyo- de Dompablo pp 5779–5786 DOI: 10.1021/ic300320r

Synthesis and Characterization of N-[2-P(i-Pr)2-4-methylphenyl]2– (PNP) Pincer Tin(IV) and Tin(II) Complexes Jens Henning, Hartmut Schubert, Klaus Eichele, Florian Winter, Rainer Pöttgen, Hermann A. Mayer, and Lars Wesemann pp 5787–5794 DOI: 10.1021/ic300324s

Dicarboxylate-Bridged Ruthenium Complexes as Building Blocks for Molecular Nanostructures Benan Kilbas, Sebastian Mirtschin, Thomas Riis-Johannessen, Rosario Scopelliti, and Kay Severin pp 5795–5804 DOI: 10.1021/ic300330p

Photoluminescence Properties, Molecular Structures, and Theoretical Study of Heteroleptic Silver(I) Complexes Containing Diphosphine Ligands Satoshi Igawa, Masashi Hashimoto, Isao Kawata, Mikio Hoshino, and Masahisa Osawa pp 5805–5813 DOI: 10.1021/ic300333c

Structural Study on 2,2′-(Methylimino)bis(N,N-Dioctylacetamide) Complex with Re(VII)O4– and Tc(VII)O4– by 1H NMR, EXAFS, and IR Spectroscopy Morihisa Saeki , Yuji Sasaki , Ayaka Nakai and Akira Ohashi , Dipanjan Banerjee, Andreas C. Scheinost, and Harald Foerstendorf pp 5814–5821 DOI: 10.1021/ic3003405

Electronic Excitations and Lattice Dynamics of Coordinatively “Unsaturated” Complex Transition Metal Compounds Dana E. Gheorghe, Alexander P. Litvinchuk, and Angela Möller pp 5822–5830 DOI: 10.1021/ic300348b

On the Influence of the Vacancy Distribution on the Structure and Ionic Conductivity of A-Site-Deficient LixSrxLa2/3–xTiO3 Perovskites Wilmer Bucheli, Teresa Durán, Ricardo Jimenez, Jesús Sanz, and Alejandro Varez pp 5831–5838 DOI: 10.1021/ic300365q

Synthesis, Structure, and Properties of Li2In2MQ6 (M = Si, Ge; Q = S, Se): A New Series of IR Nonlinear Optical Materials Wenlong Yin, Kai Feng, Wenyu Hao, Jiyong Yao, and Yicheng Wu pp 5839–5843 DOI: 10.1021/ic300373z

Structure and Properties of One-Dimensional Heterobimetallic Polymers Containing Dicyanoaurate and Dirhodium(II) Fragments Pilar Amo-Ochoa, Salomé Delgado, Almudena Gallego, Carlos J. Gómez-García, Reyes Jiménez-Aparicio, Gonzalo Martínez, Josefina Perles, and M. Rosario Torres pp 5844–5849 DOI: 10.1021/ic3004307

Enantioselective Manganese-Porphyrin-Catalyzed Epoxidation and C–H Hydroxylation with Hydrogen Peroxide in Water/Methanol Solutions Hassan Srour, Paul Le Maux, and Gerard Simonneaux pp 5850–5856 DOI: 10.1021/ic300457z

Family of Carboxylate- and Nitrate-diphenoxo Triply Bridged Dinuclear NiIILnIII Complexes (Ln = Eu, Gd, Tb, Ho, Er, Y): Synthesis, Experimental and Theoretical Magneto-Structural Studies, and Single-Molecule Magnet Behavior Enrique Colacio, José Ruiz, Antonio J. Mota, María A. Palacios, Eduard Cremades, Eliseo Ruiz, Fraser J. White, and Euan K. Brechin pp 5857–5868 DOI: 10.1021/ic3004596

Solvent-Driven Room-Temperature Synthesis of Nanoparticles BiPO4:Eu3+ Chaochao Fu, Guangshe Li, Minglei Zhao, Liusai Yang, Jing Zheng, and Liping Li pp 5869–5880 DOI: 10.1021/ic300465r

NMR and Electron Paramagnetic Resonance Studies of [Gd(CH3CN)9]3+ and [Eu(CH3CN)9]2+: Solvation and Solvent Exchange Dynamics in Anhydrous Acetonitrile Gabriella Bodizs and Lothar Helm pp 5881–5888 DOI: 10.1021/ic300478c

Alkali Metal and Zinc Complexes of a Bridging 2,5-Diamino-1,4-Benzoquinonediimine Ligand Yuanting Su, Yanxia Zhao, Jing Gao, Qingsong Dong, Biao Wu, and Xiao-Juan Yang pp 5889–5896 DOI: 10.1021/ic3004867

First Structural Characterization of Neutral, Base-Stabilized Group 15-Pentaazides: Single Crystal X-ray Structures of dmap-As(N3)5 and dmap-Sb(N3)5 Benjamin Lyhs, Dieter Bläser, Christoph Wölper, Stephan Schulz, and Georg Jansen pp 5897–5902 DOI: 10.1021/ic300523k

New Palladium-Catalyzed Cross-Coupling Routes to Carbon Functionalized Metallatricarbadecaboranes Ariane Perez-Gavilan, Patrick J. Carroll, and Larry G. Sneddon pp 5903–5910 DOI: 10.1021/ic300528h

Heptanuclear Heterometallic [Cu6Ln] Clusters: Trapping Lanthanides into Copper Cages with Artificial Amino Acids George J. Sopasis, Angelos B. Canaj, Aggelos Philippidis, Milosz Siczek, Tadeusz Lis, James R. O’Brien, Manolis M. Antonakis, Spiros A. Pergantis, and Constantinos J. Milios pp 5911–5918 DOI: 10.1021/ic300538q

Resorcinol Based Acyclic Dimeric and Cyclic Di- and Tetrameric Cyclodiphosphazanes: Synthesis, Structural Studies, and Transition Metal Complexes Guddekoppa S. Ananthnag, Seema Kuntavalli, Joel T. Mague, and Maravanji S. Balakrishna pp 5919–5930 DOI: 10.1021/ic300541n

Rational Synthesis and Characterization of the Mixed-Metal Organometallic Polyoxometalates [Cp*MoxW6–xO18]− (x = 0, 1, 5, 6) Gülnur Taban-Çalışkan, Daniel Mesquita Fernandes, Jean-Claude Daran, Dominique Agustin, Funda Demirhan, and Rinaldo Poli pp 5931–5940 DOI: 10.1021/ic300578g

Crystal Chemistry of Melilite [CaLa]2[Ga]2[Ga2O7]2: a Five Dimensional Solid Electrolyte Fengxia Wei, Tom Baikie, Tao An, Christian Kloc, Jun Wei, and Tim White pp 5941–5949 DOI: 10.1021/ic300585t

Amidoximes Provide Facile Platinum(II)-Mediated Oxime–Nitrile Coupling Dmitrii S. Bolotin, Nadezhda A. Bokach, Matti Haukka, and Vadim Yu. Kukushkin pp 5950–5964 DOI: 10.1021/ic3006019

Supramolecular Control of Hetero-multinuclear Polytopic Binding of Metal Ions (ZnII, CuI) at a Single Calix[6]arene-Based Scaffold Jean-Noël Rebilly, Olivia Bistri, Benoit Colasson, and Olivia Reinaud pp 5965–5974 DOI: 10.1021/ic300632q

N–H and N–C Bond Activation of Pyrimidinic Nucleobases and Nucleosides Promoted by an Osmium Polyhydride Miguel A. Esteruelas, Jorge García-Raboso, Montserrat Oliván, and Enrique Oñate pp 5975–5984 DOI: 10.1021/ic300639j

Issue 11

Click Chemistry on a Ruthenium Polypyridine Complex. An Efficient and Versatile Synthetic Route for the Synthesis of Photoactive Modular Assemblies Aurélie Baron, Christian Herrero, Annamaria Quaranta, Marie-France Charlot, Winfried Leibl, Boris Vauzeilles, and Ally Aukauloo pp 5985–5987 DOI: 10.1021/ic300227j

Magnetic Nanosized {MII24}-Wheel-Based (M = Co, Ni) Coordination Polymers Jia Li, Jun Tao, Rong-Bin Huang, and Lan-Sun Zheng pp 5988–5990 DOI: 10.1021/ic300487a

Long Hydrogen-Bonded Rod of Molecular Oxide: A Hexatantalate Tetramer Miki Matsumoto, Yoshiki Ozawa, and Atsushi Yagasaki pp 5991–5993 DOI: 10.1021/ic3004883

A Dodecanuclear Dysprosium Wheel Assembled by Six Vertex-Sharing Dy3 Triangles Exhibiting Slow Magnetic Relaxation Lang Zhao, Shufang Xue, and Jinkui Tang pp 5994–5996 DOI: 10.1021/ic3005807

Electron Delocalization from the Fullerene Attachment to the Diiron Core within the Active-Site Mimics of [FeFe]Hydrogenase Yu-Chiao Liu, Tao-Hung Yen, Yu-Jan Tseng, Ching-Han Hu, Gene-Hsiang Lee, and Ming-Hsi Chiang pp 5997–5999 DOI: 10.1021/ic3007298

Simple Ligand-Field Theory of d4 and d6 Transition Metal Complexes with a C3 Symmetry Axis Bruce R. McGarvey , Joshua Telser pp 6000–6010 DOI: 10.1021/ic201189a

Low-Spin versus High-Spin Ground State in Pseudo-Octahedral Iron Complexes David N. Bowman and Elena Jakubikova pp 6011–6019 DOI: 10.1021/ic202344w

(Ni,Mg)3Si2O5(OH)4 Solid-Solution Nanotubes Supported by Sub-0.06 wt % Palladium as a Robust High-Efficiency Catalyst for Suzuki–Miyaura Cross-Coupling Reactions Wancheng Zhu, Yan Yang, Shi Hu, Guolei Xiang, Biao Xu, Jing Zhuang, and Xun Wang pp 6020–6031 DOI: 10.1021/ic2024378

Influence of Sequential Thiolate Oxidation on a Nitrile Hydratase Mimic Probed by Multiedge X-ray Absorption Spectroscopy Jason Shearer, Paige E. Callan, César A. Masitas, and Craig A. Grapperhaus pp 6032–6045 DOI: 10.1021/ic202453c

Magnetooptical and Structural Investigations of Five Dimeric Cobalt(II) Complexes Mimicking Metalloenzyme Active Sites Z. Tomkowicz, S. Ostrovsky, S. Foro, V. Calvo-Perez, and W. Haase pp 6046–6055 DOI: 10.1021/ic202529p

pH-Specific Structural Speciation of the Ternary V(V)–Peroxido–Betaine System: A Chemical Reactivity-Structure Correlation C. Gabriel, E. Kioseoglou, J. Venetis, V. Psycharis, C. P. Raptopoulou, A. Terzis, G. Voyiatzis, M. Bertmer, C. Mateescu, and A. Salifoglou pp 6056–6069 DOI: 10.1021/ic2025878

Coordination versus Coupling of Dicyanamide in Molybdenum and Manganese Pyrazole Complexes Marta Arroyo, Patricia Gómez-Iglesias, Jose Miguel Martín-Alvarez, Celedonio M. Alvarez, Daniel Miguel, and Fernando Villafañe pp 6070–6080 DOI: 10.1021/ic202631c

Theoretical Study on Polynuclear Superalkali Cations with Various Functional Groups as the Central Core Jing Tong, Ying Li, Di Wu, and Zhi-Jian Wu pp 6081–6088 DOI: 10.1021/ic202675j

Synthesis and Properties of New Multinary Silicides R5Mg5Fe4AlxSi18–x (R = Gd, Dy, Y, x ≈ 12) Grown in Mg/Al Flux Xiaowei Ma, Banghao Chen, and Susan E. Latturner pp 6089–6095 DOI: 10.1021/ic202735b

Substitutional Mechanism of Ni into the Wide-Band-Gap Semiconductor InTaO4 and Its Implications for Water Splitting Activity in the Wolframite Structure Type Andrew C. Malingowski, Peter W. Stephens, Ashfia Huq, Qingzhen Huang, Syed Khalid, and Peter G. Khalifah pp 6096–6103 DOI: 10.1021/ic202715c

Design of a Dinuclear Nickel(II) Bioinspired Hydrolase to Bind Covalently to Silica Surfaces: Synthesis, Magnetism, and Reactivity Studies Clovis Piovezan, Jaqueline M. R. Silva, Ademir Neves, Adailton J. Bortoluzzi, Wolfgang Haase, Zbigniew Tomkowicz, Eduardo E. Castellano, Tessa C. S. Hough, and Liane M. Rossi pp 6104–6115 DOI: 10.1021/ic300018t

Improvements in Estimated Entropies and Related Thermodynamic Data for Aqueous Metal Ions David A. Johnson , Peter G. Nelson pp 6116–6128 DOI: 10.1021/ic3000334

Electrochemical Behavior of α1/α2-[Fe(H2O)P2W17O61]7– Isomers in Solution: Experimental and DFT Studies Neus Vilà, Pablo A. Aparicio, Francis Sécheresse, Josep M. Poblet, Xavier López, and Israël M. Mbomekallé pp 6129–6138 DOI: 10.1021/ic300090f

Effect of Thermal Annealing on the Kinetics of Rehydroxylation of Eu3+:La2O3 Nanocrystals Maria Méndez, Yolanda Cesteros, Lluís Francesc Marsal, Alexandre Giguère, Dominique Drouin, Pilar Salagre, Pilar Formentı́n, Josep Pallarès, Magdalena Aguiló, Francesc Dı́az, and Joan Josep Carvajal pp 6139–6146 DOI: 10.1021/ic300108f

Sodium Periodate as a Primary Oxidant for Water-Oxidation Catalysts Alexander R. Parent, Timothy P. Brewster, Wendy De Wolf, Robert H. Crabtree, and Gary W. Brudvig pp 6147–6152 DOI: 10.1021/ic300154x

Oxidation State of Uranium in A6Cu12U2S15 (A = K, Rb, Cs) Compounds Christos D. Malliakas, Jiyong Yao, Daniel M. Wells, Geng Bang Jin, S. Skanthakumar, Eun Sang Choi, Mahalingam Balasubramanian, L. Soderholm, Donald E. Ellis, Mercouri G. Kanatzidis, and James A. Ibers pp 6153–6163 DOI: 10.1021/ic300172k

Structural Characterization of Moganite-Type AlPO4 by NMR and Powder X-ray Diffraction Masami Kanzaki and Xianyu Xue pp 6164–6172 DOI: 10.1021/ic300167k

Partial Halogenation of Cyclic and Branched Perhydropentasilanes Harald Stueger, Thomas Mitterfellner, Roland Fischer, Christoph Walkner, Matthias Patz, and Stephan Wieber pp 6173–6179 DOI: 10.1021/ic300214y

Solid-State Syntheses of Coordination Polymers by Thermal Conversion of Molecular Building Blocks and Polymeric Precursors Daniel Lässig, Jörg Lincke, Renata Gerhardt, and Harald Krautscheid pp 6180–6189 DOI: 10.1021/ic300235s

Observation of the Inverse Trans Influence (ITI) in a Uranium(V) Imide Coordination Complex: An Experimental Study and Theoretical Evaluation Oanh P. Lam, Sebastian M. Franke, Hidetaka Nakai, Frank W. Heinemann, Wolfgang Hieringer, and Karsten Meyer pp 6190–6199 DOI: 10.1021/ic300273d

Electrochemistry of Platinum(II) Porphyrins: Effect of Substituents and π-Extension on Redox Potentials and Site of Electron Transfer Ping Chen, Olga S. Finikova, Zhongping Ou, Sergei A. Vinogradov, and Karl M. Kadish pp 6200–6210 DOI: 10.1021/ic3003367

Study on the Reversible Electrode Reaction of Na1–xNi0.5Mn0.5O2 for a Rechargeable Sodium-Ion Battery Shinichi Komaba, Naoaki Yabuuchi, Tetsuri Nakayama, Atsushi Ogata, Toru Ishikawa, and Izumi Nakai pp 6211–6220 DOI: 10.1021/ic300357d

Collapsed Cu(II)-Hydroxamate Metallacrowns Irina A. Golenya, Elzbieta Gumienna-Kontecka, Alexander N. Boyko, Matti Haukka, and Igor O. Fritsky pp 6221–6227 DOI: 10.1021/ic300387e

Layered Graphitic Carbon Host Formation during Liquid-free Solid State Growth of Metal Pyrophosphates Carlos Díaz, María Luisa Valenzuela, Vladimir Lavayen, and Colm O’Dwyer pp 6228–6236 DOI: 10.1021/ic300767h

Filling Gaps in the Series of Noninnocent Hetero-1,3-diene Chelate Ligands: Ruthenium Complexes of Redox-Active α-Azocarbonyl and α-Azothiocarbonyl Ligands RNNC(R′)E, E = O or S Fabian Ehret, Martina Bubrin, Ralph Hübner, David Schweinfurth, Ingo Hartenbach, Stanislav Záliš, and Wolfgang Kaim pp 6237–6244 DOI: 10.1021/ic300439h

A Templated Method to Bi2WO6 Hollow Microspheres and Their Conversion to Double-Shell Bi2O3/Bi2WO6 Hollow Microspheres with Improved Photocatalytic Performance Xiaona Li, Renkun Huang, Yanhua Hu, Yongjuan Chen, Wenjun Liu, Rusheng Yuan, and Zhaohui Li pp 6245–6250 DOI: 10.1021/ic300454q

Effects of Hydration during Strontium Exchange into Nanoporous Hydrogen Niobium Titanium Silicate Samantha Kramer and Aaron J. Celestian pp 6251–6258 DOI: 10.1021/ic300463w

Metallopolymeric Films Based on a Biscyclometalated Ruthenium Complex Bridged by 1,3,6,8-Tetra(2-pyridyl)pyrene: Applications in Near-Infrared Electrochromic Windows Chang-Jiang Yao, Jiannian Yao, and Yu-Wu Zhong pp 6259–6263 DOI: 10.1021/ic3004646

An Integrated Approach (Thermodynamic, Structural, and Computational) to the Study of Complexation of Alkali-Metal Cations by a Lower-Rim Calix[4]arene Amide Derivative in Acetonitrile Gordan Horvat, Vladimir Stilinović, Tomica Hrenar, Branko Kaitner, Leo Frkanec, and Vladislav Tomišić pp 6264–6278 DOI: 10.1021/ic300474s

Evaluation of the H2dedpa Scaffold and its cRGDyK Conjugates for Labeling with 64Cu Eszter Boros, Jacqueline F. Cawthray, Cara L. Ferreira, Brian O. Patrick, Michael J. Adam, and Chris Orvig pp 6279–6284 DOI: 10.1021/ic300482x

Lead(II) Complex Formation with Glutathione Vicky Mah and Farideh Jalilehvand pp 6285–6298 DOI: 10.1021/ic300496t

Optical Spectroscopy Study of Organic-Phase Lanthanide Complexes in the TALSPEAK Separations Process Travis S. Grimes, Guoxin Tian, Linfeng Rao, and Kenneth L. Nash pp 6299–6307 DOI: 10.1021/ic300503p

Insertion of Functional Groups into a Nd3+ Metal–Organic Framework via Single-Crystal-to-Single-Crystal Coordinating Solvent Exchange Manolis J. Manos, Eleni J. Kyprianidou, Giannis S. Papaefstathiou, and Anastasios J. Tasiopoulos pp 6308–6314 DOI: 10.1021/ic3005085

Synthesis, Structure, Magnetic Behavior, and Theoretical Analysis of Diazine-Bridged Magnetic Ladders: Cu(quinoxoline)X2 and Cu(2,3-dimethylpyrazine)X2 (X = Cl, Br) Joaquim Jornet-Somoza, Núria Codina-Castillo, Mercè Deumal, Fernando Mota, and Juan J. Novoa , Robert T. Butcher and Mark M. Turnbull , Brian Keith and Christopher P. Landee , Jan L. Wikaira pp 6315–6325 DOI: 10.1021/ic3005147

Crystal Structure of YbCu6In6 and Mixed Valence Behavior of Yb in YbCu6–xIn6+x (x = 0, 1, and 2) Solid Solution Udumula Subbarao and Sebastian C. Peter pp 6326–6332 DOI: 10.1021/ic300552w

Photoinduced Electron Transfer in Linear Triarylamine–Photosensitizer–Anthraquinone Triads with Ruthenium(II), Osmium(II), and Iridium(III) Jihane Hankache, Marja Niemi, Helge Lemmetyinen, and Oliver S. Wenger pp 6333–6344 DOI: 10.1021/ic300558s

Cyclopentadienyl–Silsesquioxane Titanium Complexes: Highly Active Catalysts for Epoxidation of Alkenes with Aqueous Hydrogen Peroxide María Ventura, Marta E. G. Mosquera, Tomás Cuenca, Beatriz Royo, and Gerardo Jiménez pp 6345–6349 DOI: 10.1021/ic300583g

Fluoride-Ion Acceptor Properties of WSF4: Synthesis, Characterization, and Computational Study of the WSF5– and W2S2F9– Anions and 19F NMR Spectroscopic Characterization of the W2OSF9– Anion Jared Nieboer, Ralf Haiges, William Hillary, Xin Yu, Tyler Richardet, Hélène P. A. Mercier, and Michael Gerken pp 6350–6359 DOI: 10.1021/ic3005882

Single-Ion Heat Capacities, Cp(298)ion, of Solids: with a Novel Route to Heat-Capacity Estimation of Complex Anions Leslie Glasser , H. Donald Brooke Jenkins pp 6360–6366 DOI: 10.1021/ic300591f

Metal-Mediated Dihydrogen Activation. What Determines the Transition-State Geometry? Deepa Devarajan and Daniel H. Ess pp 6367–6375 DOI: 10.1021/ic3006426

Large Improvement in the Catalytic Activity Due to Small Changes in the Diimine Ligands: New Mechanistic Insight into the Dirhodium(II,II) Complex-Based Photocatalytic H2 Production Jingfan Xie, Chao Li, Qianxiong Zhou, Weibo Wang, Yuanjun Hou, Baowen Zhang, and Xuesong Wang pp 6376–6384 DOI: 10.1021/ic300655x

Group 13 β-Ketoiminate Compounds: Gallium Hydride Derivatives As Molecular Precursors to Thin Films of Ga2O3 David Pugh, Peter Marchand, Ivan P. Parkin, and Claire J. Carmalt pp 6385–6395 DOI: 10.1021/ic3006794

Tetranuclear [Co–Gd]2 Complexes: Aiming at a Better Understanding of the 3d-Gd Magnetic Interaction Verónica Gómez, Laure Vendier, Montserrat Corbella, and Jean- Pierre Costes pp 6396–6404 DOI: 10.1021/ic300711h

A Tripodal Ruthenium–Gadolinium Metallostar as a Potential αvβ3 Integrin Specific Bimodal Imaging Contrast Agent Peter Verwilst, Svetlana V. Eliseeva, Luce Vander Elst, Carmen Burtea, Sophie Laurent, Stéphane Petoud, Robert N. Muller, Tatjana N. Parac-Vogt, and Wim M. De Borggraeve pp 6405–6411 DOI: 10.1021/ic300717m

Solid-State Synthesis of Molybdenum and Tungsten Porphyrins and Aerial Oxidation of Coordinated Benzenethiolate to Benzenesulfonate Goutam Nandi and Sabyasachi Sarkar pp 6412–6420 DOI: 10.1021/ic3008377

Novel Synthesis and Structural Analysis of Ferrihydrite Stacey J. Smith, Katharine Page, Hyunjeong Kim, Branton J. Campbell, Juliana Boerio-Goates, and Brian F. Woodfield pp 6421–6424 DOI: 10.1021/ic300937f

Issue 12

Peculiar Field-Dependent Magnetic Behavior of Cyano-Bridged Coordination Polymer Er(H2O)4[W(CN)8] Marine Perrier, Jêrôme Long, Filipe A. Almeida Paz, Yannick Guari, and Joulia Larionova pp 6425–6427 DOI: 10.1021/ic2024988

An Amide-Linked Chromophore–Catalyst Assembly for Water Oxidation Dennis L. Ashford, David J. Stewart, Christopher R. Glasson, Robert A. Binstead, Daniel P. Harrison, Michael R. Norris, Javier J. Concepcion, Zhen Fang, Joseph L. Templeton, and Thomas J. Meyer pp 6428–6430 DOI: 10.1021/ic300061u

Rapid Synthesis of Radioactive Transition-Metal Carbonyl Complexes at Ambient Conditions Julia Even, Alexander Yakushev, Christoph E. Düllmann, Jan Dvorak, Robert Eichler, Oliver Gothe, Daniel Hild, Egon Jäger, Jadambaa Khuyagbaatar, Jens V. Kratz, Jörg Krier, Lorenz Niewisch, Heino Nitsche, Inna Pysmenetska, Matthias Schädel, Brigitta Schausten, Andreas Türler, Norbert Wiehl, and David Wittwer pp 6431–6433 DOI: 10.1021/ic300305m

Conversion of a Cyclotriphosphazene to a Cyclohexaphosphazene by Ring Expansion Serap Beşli, Fatma Yuksel, David B. Davies, and Adem Kılıç pp 6434–6436 DOI: 10.1021/ic300728j

Isomers of Metal–Organic Complex Arrays Alejandro M. Fracaroli, Kentaro Tashiro, and Omar M. Yaghi pp 6437–6439 DOI: 10.1021/ic300744x

A Heterometallic (NiII–CuII) Decanuclear Cluster Containing Two Distorted Cubane-like Pentanuclear Cores: Synthesis, Structure, and Magnetic Properties Anindita Chakraborty, Barindra Kumar Ghosh, Jordi Ribas-Arino, Joan Ribas, and Tapas Kumar Maji pp 6440–6442 DOI: 10.1021/ic300756g

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks William Morris, Boris Volosskiy, Selcuk Demir, Felipe Gándara, Psaras L. McGrier, Hiroyasu Furukawa, Duilio Cascio, J. Fraser Stoddart, and Omar M. Yaghi pp 6443–6445 DOI: 10.1021/ic300825s

Rapid, Covalent Addition of Phosphine to Dithiolene in a Molybdenum Tris(dithiolene). A New Structural Model for Dimethyl Sulfoxide Reductase Neilson Nguyen, Alan J. Lough, and Ulrich Fekl pp 6446–6448 DOI: 10.1021/ic301031b

Synthesis and Structural Diversity of Barium (N,N-Dimethylamino)diboranates Scott R. Daly, Brian J. Bellott, Mark A. Nesbit, and Gregory S. Girolami pp 6449–6459 DOI: 10.1021/ic2016879

Aluminum Chloride Activation of Chloro-Boronsubphthalocyanine: a Rapid and Flexible Method for Axial Functionalization with an Expanded Set of Nucleophiles Graham E. Morse and Timothy P. Bender pp 6460–6467 DOI: 10.1021/ic2016935

Ruthenium Terpyridine Complexes Containing a Pyrrole-Tagged 2,2′-Dipyridylamine Ligand—Synthesis, Crystal Structure, and Electrochemistry Kwong-Chak Cheung, Peng Guo, Ming-Him So, Zhong-Yuan Zhou, Lawrence Yoon Suk Lee, and Kwok-Yin Wong pp 6468–6475 DOI: 10.1021/ic202459g

Nona-Coordinated Chiral Eu(III) Complexes with Stereoselective Ligand–Ligand Noncovalent Interactions for Enhanced Circularly Polarized Luminescence Takashi Harada, Hiroyuki Tsumatori, Katsura Nishiyama, Junpei Yuasa, Yasuchika Hasegawa, and Tsuyoshi Kawai pp 6476–6485 DOI: 10.1021/ic202467f

Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond Igor E. Golub, Oleg A. Filippov, Evgenii I. Gutsul, Natalia V. Belkova, Lina M. Epstein, Andrea Rossin, Maurizio Peruzzini, and Elena S. Shubina pp 6486–6497 DOI: 10.1021/ic202598c

Synthesis, Structures, and Properties of Two Three-Dimensional Metal–Organic Frameworks, Based on Concurrent Ligand Extension Dabin Shi, Yanwei Ren, Huanfeng Jiang, Bowei Cai, and Jiaxian Lu pp 6498–6506 DOI: 10.1021/ic202624e

Relativistic Density Functional Study on Uranium(IV) and Thorium(IV) Oxide Clusters of Zonohedral Geometry Grigory A. Shamov pp 6507–6516 DOI: 10.1021/ic2026522

Neutral Mononuclear, Dinuclear, Tetranuclear d7/d10 Metal Complexes Containing bis-Pyrazole/Pyridine Ligands Supported by 2,6-bis(3-Pyrazolyl)Pyridine: Synthesis, Structure, Spectra, and Catalytic Activity Lijuan Wan, Caishun Zhang, Yongheng Xing, Zhen Li, Na Xing, Liying Wan, and Hui Shan pp 6517–6528 DOI: 10.1021/ic202678s

Synthesis and Photocatalytic Activity of Single-Crystalline Hollow rh-In2O3 Nanocrystals Jiefu Yin and Huaqiang Cao pp 6529–6536 DOI: 10.1021/ic300005c

Photoinduced Charge Transfer in Short-Distance Ferrocenylsubphthalocyanine Dyads Pavlo V. Solntsev, Katelynn L. Spurgin, Jared R. Sabin, Ahmed A. Heikal, and Victor N. Nemykin pp 6537–6547 DOI: 10.1021/ic3000608

Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates Eric M. Villa, Connor J. Marr, Laurent J. Jouffret, Evgeny V. Alekseev, Wulf Depmeier, and Thomas E. Albrecht-Schmitt pp 6548–6558 DOI: 10.1021/ic3000735

Perovskite-to-Postperovskite Transitions in NaNiF3 and NaCoF3 and Disproportionation of NaCoF3 Postperovskite under High Pressure and High Temperature Hitoshi Yusa, Yuichi Shirako, Masaki Akaogi, Hiroshi Kojitani, Naohisa Hirao, Yasuo Ohishi, and Takumi Kikegawa pp 6559–6566 DOI: 10.1021/ic300118d

Synthesis and Structures of Cuprous Triptycylthiolate Complexes Skylar J. Ferrara, Joel T. Mague, and James P. Donahue pp 6567–6576 DOI: 10.1021/ic300124n

Hydrido Copper Clusters Supported by Dithiocarbamates: Oxidative Hydride Removal and Neutron Diffraction Analysis of [Cu7(H){S2C(aza-15-crown-5)}6] Ping-Kuei Liao, Ching-Shiang Fang, Alison J. Edwards, Samia Kahlal, Jean-Yves Saillard, and C. W. Liu pp 6577–6591 DOI: 10.1021/ic300135w

Investigating the Role of the Outer-Coordination Sphere in [Ni(PPh2NPh-R2)2]2+ Hydrogenase Mimics Avijita Jain, Matthew L. Reback, Mary Lou Lindstrom, Colleen E. Thogerson, Monte L. Helm, Aaron M. Appel, and Wendy J. Shaw pp 6592–6602 DOI: 10.1021/ic300149x

Gas-Phase Uranyl, Neptunyl, and Plutonyl: Hydration and Oxidation Studied by Experiment and Theory Daniel Rios, Maria C. Michelini, Ana F. Lucena, Joaquim Marçalo, Travis H. Bray, and John K. Gibson pp 6603–6614 DOI: 10.1021/ic3001625

Thermodynamics of Axial Substitution and Kinetics of Reactions with Amino Acids for the Paddlewheel Complex Tetrakis(acetato)chloridodiruthenium(II,III) Rodrigo L. S. R. Santos, Rudi van Eldik, and Denise de Oliveira Silva pp 6615–6625 DOI: 10.1021/ic300168t

Oxidation of Phosphorus Centers by Ferrate(VI): Spectral Observation of an Intermediate Shaun M. Hightower, Bret B. Lorenz, Jonathan G. Bernard, and Michael D. Johnson pp 6626–6632 DOI: 10.1021/ic3001812

Characterization and Dioxygen Reactivity of a New Series of Coordinatively Unsaturated Thiolate-Ligated Manganese(II) Complexes Michael K. Coggins, Santiago Toledo, Erika Shaffer, Werner Kaminsky, Jason Shearer, and Julie A. Kovacs pp 6633–6644 DOI: 10.1021/ic300192q

Condensation of a Nickel Tetranuclear Cubane into a Heptanuclear Single-Molecule Magnet Sarah Petit, Petr Neugebauer, Guillaume Pilet, Guillaume Chastanet, Anne-Laure Barra, Arlei B. Antunes, Wolfgang Wernsdorfer, and Dominique Luneau pp 6645–6654 DOI: 10.1021/ic3001637

Trialkylphosphine-Stabilized Copper(I) Gallium(III) Phenylchalcogenolate Complexes: Crystal Structures and Generation of Ternary Semiconductors by Thermolysis Oliver Kluge and Harald Krautscheid pp 6655–6666 DOI: 10.1021/ic300278v

Synthesis and Coordination Chemistry of Phosphine Oxide Decorated Dibenzofuran Platforms Daniel Rosario-Amorin, Eileen N. Duesler, Robert T. Paine, Benjamin P. Hay, Lætitia H. Delmau, Sean D. Reilly, Andrew J. Gaunt, and Brian L. Scott pp 6667–6681 DOI: 10.1021/ic300301d

New Nonlinear Optical Crystal: NaBa4Al2B8O18Cl3 Jianxiu Zhang, Shufeng Zhang, Yicheng Wu, and Jiyang Wang pp 6682–6686 DOI: 10.1021/ic300306v

Electronic Structures of Ruthenium and Osmium Complexes of 9,10-Phenanthrenequinone Manas Kumar Biswas, Sarat Chandra Patra, Amarendra Nath Maity, Shyue-Chu Ke, Nirmal Das Adhikary, and Prasanta Ghosh pp 6687–6699 DOI: 10.1021/ic300327x

Rhenium(I) Tricarbonyl Complexes of 5,10,15,20-Tetraphenyl-21-thia and 21-Oxaporphyrins Avijit Ghosh and Mangalampalli Ravikanth pp 6700–6709 DOI: 10.1021/ic300344g

Theory of Late-Transition-Metal Alkyl and Heteroatom Bonding: Analysis of Pt, Ru, Ir, and Rh Complexes Deepa Devarajan, T. Brent Gunnoe, and Daniel H. Ess pp 6710–6718 DOI: 10.1021/ic300350k

Unraveling the Electronic Structures of Low-Valent Naphthalene and Anthracene Iron Complexes: X-ray, Spectroscopic, and Density Functional Theory Studies Eva-Maria Schnöckelborg, Marat M. Khusniyarov, Bas de Bruin, František Hartl, Thorsten Langer, Matthias Eul, Stephen Schulz, Rainer Pöttgen, and Robert Wolf pp 6719–6730 DOI: 10.1021/ic300366m

Rates of Water Exchange on the [Fe4(OH)2(hpdta)2(H2O)4]0 Molecule and Its Implications for Geochemistry Adele F. Panasci, C. André Ohlin, Stephen J. Harley, and William H. Casey pp 6731–6738 DOI: 10.1021/ic300370q

Nitrogen-rich Compounds of the Actinoids: Dioxouranium(VI) 5,5′-Azobis[tetrazolide] Pentahydrate and Its Unusually Small Uranyl Angle Georg Steinhauser, Gerald Giester, Christoph Wagner, Peter Weinberger, Bernhard Zachhuber, Georg Ramer, Mario Villa, and Bernhard Lendl pp 6739–6745 DOI: 10.1021/ic300377j

A QMCF-MD Investigation of the Structure and Dynamics of Ce4+ in Aqueous Solution Oliver M. D. Lutz, Thomas S. Hofer, Bernhard R. Randolf, Alexander K. H. Weiss, and Bernd M. Rode pp 6746–6752 DOI: 10.1021/ic300385s

Bis(imidazolin-2-iminato) Rare Earth Metal Complexes: Synthesis, Structural Characterization, and Catalytic Application Alexandra G. Trambitas, Daniel Melcher, Larissa Hartenstein, Peter W. Roesky, Constantin Daniliuc, Peter G. Jones, and Matthias Tamm pp 6753–6761 DOI: 10.1021/ic300407u

Theoretical Insight into the Structural Stability of KZnB3O6 Polymorphs with Different BOx Polyhedral Networks Lei Yang, Weiliu Fan, Yanlu Li, Honggang Sun, Lei Wei, Xiufeng Cheng, and Xian Zhao pp 6762–6770 DOI: 10.1021/ic300469s

Architecture of CuS/PbS Heterojunction Semiconductor Nanowire Arrays for Electrical Switches and Diodes Xuemin Qian, Huibiao Liu, Nan Chen, Haiqing Zhou, Lianfeng Sun, Yongjun Li, and Yuliang Li pp 6771–6775 DOI: 10.1021/ic300471j

An N-Heterocyclic Carbene Containing a Bithiophene Backbone: Synthesis and Coordination Chemistry Jacquelyn T. Price, Nathan D. Jones, and Paul J. Ragogna pp 6776–6783 DOI: 10.1021/ic300494g

Different Rotamer States of Cytosine Nucleobases in Heteronuclear PtPd-, PtPd2, and Pt2Pd2Ag Complexes Derived from [Pt(2,2′-bpy)(1-MeC-N3)2]2+ (1-MeC = 1-Methylcytosine): First Examples of Species with Head–Head Oriented 1-MeC– Ligands Lu Yin, Pablo J. Sanz Miguel, Wolf Hiller, and Bernhard Lippert pp 6784–6793 DOI: 10.1021/ic3005097

Water-Soluble Mo3S4 Clusters Bearing Hydroxypropyl Diphosphine Ligands: Synthesis, Crystal Structure, Aqueous Speciation, and Kinetics of Substitution Reactions Manuel G. Basallote, M. Jesús Fernández-Trujillo, Jose Ángel Pino-Chamorro, Tomás F. Beltrán, Carolina Corao, Rosa Llusar, Maxim Sokolov, and Cristian Vicent pp 6794–6802 DOI: 10.1021/ic300517g

Toward a Small Molecule, Biomimetic Carbonic Anhydrase Model: Theoretical and Experimental Investigations of a Panel of Zinc(II) Aza-Macrocyclic Catalysts Lucas Koziol, Carlos A. Valdez, Sarah E. Baker, Edmond Y. Lau, William C. Floyd, III, Sergio E. Wong, Joe H. Satcher, Jr., Felice C. Lightstone, and Roger D. Aines pp 6803–6812 DOI: 10.1021/ic300526b

Two Metal–Organic Frameworks Constructed from One-Dimensional Cobalt(II) Ferrimagnetic Chains with Alternating Antiferromagnetic/Ferromagnetic and AF/AF/FM Interaction: Synthesis, Structures, and Magnetic Properties Fen Yang, Baiyan Li, Wei Xu, Guanghua Li, Qi Zhou, Jia Hua, Zhan Shi, and Shouhua Feng pp 6813–6820 DOI: 10.1021/ic300546z

Synthesis, Crystal Chemistry, and Magnetic Properties of RE7Li8Ge10 and RE11Li12Ge16 (RE = La–Nd, Sm): New Members of the [REGe2]n[RELi2Ge]m Homologous Series Sheng-Ping Guo, Tae-Soo You, Ya-Ho Jung, and Svilen Bobev pp 6821–6829 DOI: 10.1021/ic300566x

Combined Theoretical and Computational Study of Interstrand DNA Guanine–Guanine Cross-Linking by trans-[Pt(pyridine)2] Derived from the Photoactivated Prodrug trans,trans,trans-[Pt(N3)2(OH)2(pyridine)2] Hui-Chung Tai, Ralf Brodbeck, Jana Kasparkova, Nicola J. Farrer, Viktor Brabec, Peter J. Sadler, and Robert J. Deeth pp 6830–6841 DOI: 10.1021/ic3005745

Hexanuclear Copper(II) Cages Built on a Central {μ3–O···H···μ3–O} Moiety, 1,3-Bis(dimethylamino)-2-propanolato and Capping R-phosphonates: Crystal Structures, Magnetic Behavior, and DFT Studies Saskia Speed, Ramon Vicente, Daniel Aravena, Eliseo Ruiz, Olivier Roubeau, Simon J. Teat, and M. Salah El Fallah pp 6842–6850 DOI: 10.1021/ic300589h

{4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2Sn}2: An Intramolecularly Coordinated Organotin(I) Compound with a Sn–Sn Single Bond, Its Disproportionation toward a Diorganostannylene and Elemental Tin, and Its Oxidation with PhI(OAc)2 Michael Wagner, Christina Dietz, Stefan Krabbe, Stephan G. Koller, Carsten Strohmann, and Klaus Jurkschat pp 6851–6859 DOI: 10.1021/ic3005954

Syntheses, Structures, Optical and Magnetic Properties of Ba2MLnSe5 (M = Ga, In; Ln = Y, Nd, Sm, Gd, Dy, Er) Wenlong Yin, Kai Feng, Wendong Wang, Youguo Shi, Wenyu Hao, Jiyong Yao, and Yicheng Wu pp 6860–6867 DOI: 10.1021/ic300604a

High-Pressure Synthesis, Crystal Structure, and Electromagnetic Properties of CdRh2O4: an Analogous Oxide of the Postspinel Mineral MgAl2O4 Xia Wang, Yanfeng Guo, Youguo Shi, Alexei A. Belik, Yoshihiro Tsujimoto, Wei Yi, Ying Sun, Yuichi Shirako, Masao Arai, Masaki Akaogi, Yoshitaka Matsushita, and Kazunari Yamaura pp 6868–6875 DOI: 10.1021/ic300628m

New Twists on the Perovskite Theme: Crystal Structures of the Elusive Phases R and S of NaNbO3 Martin D. Peel, Stephen P. Thompson, Aziz Daoud-Aladine, Sharon E. Ashbrook, and Philip Lightfoot pp 6876–6889 DOI: 10.1021/ic3006585

Spin Reorientation in the Square-Lattice Antiferromagnets RMnAsO (R = Ce, Nd): Density Functional Analysis of the Spin-Exchange Interactions between the Rare-Earth and Transition-Metal Ions Changhoon Lee, Erjun Kan, Hongjun Xiang, Reinhard K. Kremer, Seung-Hun Lee, Zenji Hiroi, and Myung-Hwan Whangbo pp 6890–6897 DOI: 10.1021/ic300685d

M–M Bond-Stretching Energy Landscapes for M2(dimen)42+ (M = Rh, Ir; dimen = 1,8-Diisocyanomenthane) Complexes Bryan M. Hunter, Randy M. Villahermosa, Christopher L. Exstrom, Michael G. Hill, Kent R. Mann, and Harry B. Gray pp 6898–6905 DOI: 10.1021/ic300716q

Periodic Trends in Lanthanide and Actinide Phosphonates: Discontinuity between Plutonium and Americium Juan Diwu, Daniel J. Grant, Shuao Wang, Laura Gagliardi, and Thomas E. Albrecht-Schmitt pp 6906–6915 DOI: 10.1021/ic300742p

Monopicolinate Cyclen and Cyclam Derivatives for Stable Copper(II) Complexation Luís M. P. Lima, David Esteban-Gómez, Rita Delgado, Carlos Platas-Iglesias, and Raphaël Tripier pp 6916–6927 DOI: 10.1021/ic300784v

β-Nitro-5,10,15-tritolylcorroles Manuela Stefanelli, Giuseppe Pomarico, Luca Tortora, Sara Nardis, Frank R. Fronczek, Gregory T. McCandless, Kevin M. Smith, Machima Manowong, Yuanyuan Fang, Ping Chen, Karl M. Kadish, Angela Rosa, Giampaolo Ricciardi, and Roberto Paolesse pp 6928–6942 DOI: 10.1021/ic3007926

Density Functional Theory Investigation of the Redox Properties of Tricyclopentadienyl- and Phospholyluranium(IV) Chloride Complexes Aziz Elkechai, Yamina Mani, Abdou Boucekkine, and Michel Ephritikhine pp 6943–6952 DOI: 10.1021/ic300811m

Strategic Design and Refinement of Lewis Acid–Base Catalysis by Rare-Earth-Metal-Containing Polyoxometalates Kosuke Suzuki, Midori Sugawa, Yuji Kikukawa, Keigo Kamata, Kazuya Yamaguchi, and Noritaka Mizuno pp 6953–6961 DOI: 10.1021/ic3008365

Amine-Templated Polymeric Lanthanide Formates: Synthesis, Characterization, and Applications in Luminescence and Magnetism Andrea Rossin, Giuliano Giambastiani, Maurizio Peruzzini, and Roberta Sessoli pp 6962–6968 DOI: 10.1021/ic300854b

Scrutinizing Low-Spin Cr(II) Complexes Christopher C. Scarborough, Stephen Sproules, Christian J. Doonan, Karl S. Hagen, Thomas Weyhermüller, and Karl Wieghardt pp 6969–6982 DOI: 10.1021/ic300882r

Infrared Spectroscopic and Theoretical Investigations of the OUF2 and OThF2 Molecules with Triple Oxo Bond Character Yu Gong, Xuefeng Wang, Lester Andrews, Tobias Schlöder, and Sebastian Riedel pp 6983–6991 DOI: 10.1021/ic3009128

Survey on the Phase Transitions and Their Effect on the Ion-Exchange and on the Proton-Conduction Properties of a Flexible and Robust Zr Phosphonate Coordination Polymer Ferdinando Costantino, Anna Donnadio, and Mario Casciola pp 6992–7000 DOI: 10.1021/ic3009656

Issue 13

Electrical Properties and Behaviors of Cuprous Oxide Cubes under High Pressure Cai-Long Liu, Yong-Ming Sui, Wan-Bin Ren, Bo-Heng Ma, Yan Li, Ning-Ning Su, Qing-Lin Wang, Yu-Qiang Li, Jun-Kai Zhang, Yong-Hao Han, Yan-Zhang Ma, and Chun-Xiao Gao pp 7001–7003 DOI: 10.1021/ic3007662

Hydrotris(triazolyl)borate Complexes as Functional Models for Cu Nitrite Reductase: The Electronic Influence of Distal Nitrogens Mukesh Kumar, Natalie A. Dixon, Anna C. Merkle, Matthias Zeller, Nicolai Lehnert, and Elizabeth T. Papish pp 7004–7006 DOI: 10.1021/ic300160c

Quaternary Tellurides with Different Valent Ge Centers: Cs2Ge3M6Te14 (M = Ga, In) Cheng-Yi Zhang, Liu-Jiang Zhou, and Ling Chen pp 7007–7009 DOI: 10.1021/ic300599q

Diphenoxo-Bridged NiIILnIII Dinuclear Complexes as Platforms for Heterotrimetallic (LnIIINiII)2RuIII Systems with a High-Magnetic-Moment Ground State: Synthesis, Structure, and Magnetic Properties María A. Palacios, Antonio J. Mota, José Ruiz, Mikko M. Hänninen, Reijo Sillanpää, and Enrique Colacio pp 7010–7012 DOI: 10.1021/ic3008443

Increased Antenna Effect of the Lanthanide Complexes by Control of a Number of Terdentate N-Donor Pyridine Ligands Yuk-Wang Yip, Hongli Wen, Wing-Tak Wong, Peter A. Tanner, and Ka-Leung Wong pp 7013–7015 DOI: 10.1021/ic300916e

Cation–Cation Interactions between Neptunyl(VI) Units Shuao Wang, Juan Diwu, Evgeny V. Alekseev, Laurent J. Jouffret, Wulf Depmeier, and Thomas E. Albrecht-Schmitt pp 7016–7018 DOI: 10.1021/ic3009305

Solid-State Aggregation of Metallacyclophane-Based MnIICuII One-Dimensional Ladders Jesús Ferrando-Soria, Thais Grancha, Jorge Pasán, Catalina Ruiz-Pérez, Laura Cañadillas-Delgado, Yves Journaux, Miguel Julve, Joan Cano, Francesc Lloret, and Emilio Pardo pp 7019–7021 DOI: 10.1021/ic300953n

Anion-Controlled Circular Dichroism Spectral Changes in Hg2+ Complexes with a Chiral Bidentate Ligand Mari Ikeda, Shunsuke Kuwahara, Shim Sung Lee, and Yoichi Habata pp 7022–7024 DOI: 10.1021/ic301140z

Revisiting the Polyoxometalate-Based Late-Transition-Metal-Oxo Complexes: The “Oxo Wall” Stands Kevin P. O’Halloran, Chongchao Zhao, Nicole S. Ando, Arthur J. Schultz, Thomas F. Koetzle, Paula M. B. Piccoli, Britt Hedman, Keith O. Hodgson, Elena Bobyr, Martin L. Kirk, Sushilla Knottenbelt, Ezra C. Depperman, Benjamin Stein, Travis M. Anderson, Rui Cao, Yurii V. Geletii, Kenneth I. Hardcastle, Djamaladdin G. Musaev, Wade A. Neiwert, Xikui Fang, Keiji Morokuma, Shaoxiong Wu, Paul Kögerler, and Craig L. Hill pp 7025–7031 DOI: 10.1021/ic2008914

Excitonic Luminescence of Hemiporphyrazines Sabrina M. Huber, Martin S. Seyfried, Anthony Linden, and Nathan W. Luedtke pp 7032–7038 DOI: 10.1021/ic2017566

Syntheses, Structures, and Luminescent Properties of Dipyridylamine-Functionalized Anthracene and Its Complexes Runyu Tan, Zhi-Bin Wang, Yu Li, Daniel J. Kozera, Zheng-Hong Lu, and Datong Song pp 7039–7049 DOI: 10.1021/ic201757r

Lanthanide N,N-Dimethylaminodiboranates as a New Class of Highly Volatile Chemical Vapor Deposition Precursors Scott R. Daly, Do Young Kim, and Gregory S. Girolami pp 7050–7065 DOI: 10.1021/ic201852j

Three Novel Isomeric Zinc Metal–Organic Frameworks from a Tetracarboxylate Linker Yun-Xia Hu, Hai-Bo Ma, Bo Zheng, Wen-Wei Zhang, Shengchang Xiang, Lu Zhai, Li-Feng Wang, Banglin Chen, Xiao-Ming Ren, and Junfeng Bai pp 7066–7074 DOI: 10.1021/ic202085j

Rapid and Highly Sensitive Dual-Channel Detection of Cyanide by Bis-heteroleptic Ruthenium(II) Complexes Snehadrinarayan Khatua, Debabrata Samanta, Jan W. Bats, and Michael Schmittel pp 7075–7086 DOI: 10.1021/ic2022853

Combined Experimental–Theoretical Characterization of the Hydrido-Cobaloxime [HCo(dmgH)2(PnBu3)] Anirban Bhattacharjee, Murielle Chavarot-Kerlidou, Eugen. S. Andreiadis, Marc Fontecave, Martin J. Field, and Vincent Artero pp 7087–7093 DOI: 10.1021/ic2024204

Effect of Axial Ligand on the Electronic Configuration, Spin States, and Reactivity of Iron Oxophlorin Mahin Gheidi, Nasser Safari, and Mansour Zahedi pp 7094–7102 DOI: 10.1021/ic202527u

Three-Dimensional Metal–Organic Framework with Highly Polar Pore Surface: H2 and CO2 Storage Characteristics Kolleboyina Jayaramulu, Sandeep Kumar Reddy, Arpan Hazra, Sundaram Balasubramanian, and Tapas Kumar Maji pp 7103–7111 DOI: 10.1021/ic202601y

Case of a Strong Antiferromagnetic Exchange Coupling Induced by Spin Polarization of a Mn–Mn Partial Single Bond Hélène Bolvin and Frank R. Wagner pp 7112–7118 DOI: 10.1021/ic2027237

Enhancement of Cytotoxicity by Combining Pyrenyl-Dendrimers and Arene Ruthenium Metallacages Anaïs Pitto-Barry, Olivier Zava, Paul J. Dyson, Robert Deschenaux, and Bruno Therrien pp 7119–7124 DOI: 10.1021/ic202739d

Heteropolytopic Arsanylarylthiolato Ligands: Cis–Trans Isomerism of Nickel(II), Palladium(II), and Platinum(II) Complexes of 1-AsPh2-2-SHC6H4 Alexandra Hildebrand, Imola Sárosi, Peter Lönnecke, Luminiţa Silaghi-Dumitrescu, Menyhárt B. Sárosi, Ioan Silaghi-Dumitrescu, and Evamarie Hey-Hawkins pp 7125–7133 DOI: 10.1021/ic300002p

Lanthanide Amido Complexes Incorporating Amino-Coordinate-Lithium Bridged Bis(indolyl) Ligands: Synthesis, Characterization, and Catalysis for Hydrophosphonylation of Aldehydes and Aldimines Xiancui Zhu, Shaowu Wang, Shuangliu Zhou, Yun Wei, Lijun Zhang, Fenhua Wang, Zhijun Feng, Liping Guo, and Xiaolong Mu pp 7134–7143 DOI: 10.1021/ic300137r

Chiral Conducting Salts of Nickel Dithiolene Complexes Julien Lieffrig, Olivier Jeannin, Pascale Auban-Senzier, and Marc Fourmigué pp 7144–7152 DOI: 10.1021/ic300146s

Novel Oximato-Bridged Platinum(II) Di- and Trimer(s): Synthetic, Structural, and in Vitro Anticancer Activity Studies Yulia Yu. Scaffidi-Domianello, Anton A. Legin, Michael A. Jakupec, Alexander Roller, Vadim Yu. Kukushkin, Markus Galanski, and Bernhard K. Keppler pp 7153–7163 DOI: 10.1021/ic300148e

Nanostructured Ti1-xSxO2-yNy Heterojunctions for Efficient Visible-Light-Induced Photocatalysis Vinodkumar Etacheri, Michael K. Seery, Steven J. Hinder, and Suresh C. Pillai pp 7164–7173 DOI: 10.1021/ic3001653

Selective Recognition of Cyanide Anion via Formation of Multipoint NH and Phenyl CH Hydrogen Bonding with Acyclic Ruthenium Bipyridine Imidazole Receptors in Water Hao-Jun Mo, Yong Shen, and Bao-Hui Ye pp 7174–7184 DOI: 10.1021/ic300217v

(UO2)2[UO4(trz)2](OH)2: A U(VI) Coordination Intermediate between a Tetraoxido Core and a Uranyl Ion with Cation–Cation Interactions Zhehui Weng, Shuao Wang, Jie Ling, Jessica M. Morrison, and Peter C. Burns pp 7185–7191 DOI: 10.1021/ic300240s

Oxygen Reduction Reactions of Monometallic Rhodium Hydride Complexes Thomas S. Teets and Daniel G. Nocera pp 7192–7201 DOI: 10.1021/ic300279z

Novel Red-Emitting Ba2Tb(BO3)2Cl:Eu Phosphor with Efficient Energy Transfer for Potential Application in White Light-Emitting Diodes Zhiguo Xia, Jiaqing Zhuang, and Libing Liao pp 7202–7209 DOI: 10.1021/ic300401z

Relaxometric Investigations and MRI Evaluation of a Liposome-Loaded pH-Responsive Gadolinium(III) Complex E. Gianolio, S. Porto, R. Napolitano, S. Baroni, G.B. Giovenzana, and S. Aime pp 7210–7217 DOI: 10.1021/ic300447n

Investigating Magnetostructural Correlations in the Pseudooctahedral trans-[NiII{(OPPh2)(EPPh2)N}2(sol)2] Complexes (E = S, Se; sol = DMF, THF) by Magnetometry, HFEPR, and ab Initio Quantum Chemistry Dimitrios Maganas, J. Krzystek, Eleftherios Ferentinos, Alexander M. Whyte, Neil Robertson, Vassilis Psycharis, Aris Terzis, Frank Neese, and Panayotis Kyritsis pp 7218–7231 DOI: 10.1021/ic300453y

Neutron Diffraction Study of Unusual Phase Separation in the Antiperovskite Nitride Mn3ZnN Ying Sun, Cong Wang, Qingzhen Huang, Yanfeng Guo, Lihua Chu, Masao Arai, and Kazunari Yamaura pp 7232–7236 DOI: 10.1021/ic300978x

Successive Heterolytic Cleavages of H2 Achieve N2 Splitting on Silica-Supported Tantalum Hydrides: A DFT Proposed Mechanism Xavier Solans-Monfort, Catherine Chow, Eric Gouré, Yasemin Kaya, Jean-Marie Basset, Mostafa Taoufik, Elsje Alessandra Quadrelli, and Odile Eisenstein pp 7237–7249 DOI: 10.1021/ic300498b

Single Electron Transfer-Mediated Selective endo- and exocyclic Bond Cleavage Processes in Azaphosphiridine Chromium(0) Complexes: A Computational Study Arturo Espinosa, Celia Gómez, and Rainer Streubel pp 7250–7256 DOI: 10.1021/ic300522g

Aerobic and Hydrolytic Decomposition of Pseudotetrahedral Nickel Phenolate Complexes Tapash Deb, Gregory T. Rohde, Victor G. Young, Jr., and Michael P. Jensen pp 7257–7270 DOI: 10.1021/ic300551z

New Monodentate Amidine Superbasic Ligands with a Single Configuration in fac-[Re(CO)3(5,5′- or 6,6′-Me2bipyridine)(amidine)]BF4 Complexes Pramuditha Abhayawardhana, Patricia A. Marzilli, Theshini Perera, Frank R. Fronczek, and Luigi G. Marzilli pp 7271–7283 DOI: 10.1021/ic300625n

Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P) Fernanda Cimadevilla, M. Esther García, Daniel García-Vivó, Miguel A. Ruiz, Claudia Graiff, and Antonio Tiripicchio pp 7284–7295 DOI: 10.1021/ic300626y

Effect of the Axial Ligand on the Reactivity of the Oxoiron(IV) Porphyrin π-Cation Radical Complex: Higher Stabilization of the Product State Relative to the Reactant State Akihiro Takahashi, Daisuke Yamaki, Kenichiro Ikemura, Takuya Kurahashi, Takashi Ogura, Masahiko Hada, and Hiroshi Fujii pp 7296–7305 DOI: 10.1021/ic3006597

Cationic Cryptand Complexes of Tin(II) Jessica C. Avery, Margaret A. Hanson, Rolfe H. Herber, Kamila J. Bladek, Paul A. Rupar, Israel Nowik, Yining Huang, and Kim M. Baines pp 7306–7316 DOI: 10.1021/ic3006713

Exploration of Mid-Temperature Alkali-Metal-Ion Extraction Route Using PTFE (AEP): Transformation of α-NaFeO2-Type Layered Oxides into Rutile-Type Binary Oxides Tadashi C. Ozawa and Takayoshi Sasaki pp 7317–7323 DOI: 10.1021/ic3006986

Photoinduced Water Oxidation by a Tetraruthenium Polyoxometalate Catalyst: Ion-pairing and Primary Processes with Ru(bpy)32+ Photosensitizer Mirco Natali, Michele Orlandi, Serena Berardi, Sebastiano Campagna, Marcella Bonchio, Andrea Sartorel, and Franco Scandola pp 7324–7331 DOI: 10.1021/ic300703f

Nickel(II) 3,4;9,10-Perylenediimide bis-Phosphonate Pentahydrate: A Metal–Organic Ferromagnetic Dye Carlo Bellitto, Guido Righini, Carlos J. Gómez-García, Ruggero Caminiti, Marilena Carbone, Roberto Matassa, and Elvira M. Bauer pp 7332–7339 DOI: 10.1021/ic300706h

Mechanistic Insight from Activation Parameters for the Reaction of a Ruthenium Hydride Complex with CO2 in Conventional Solvents and an Ionic Liquid Simon Kern and Rudi van Eldik pp 7340–7345 DOI: 10.1021/ic300718v

Zinc Thiolate Reactivity toward Nitrogen Oxides: Insights into the Interaction of Zn2+ with S-Nitrosothiols and Implications for Nitric Oxide Synthase Julia Kozhukh and Stephen J. Lippard pp 7346–7353 DOI: 10.1021/ic3007684

Aerobic Oxidation Reactions Catalyzed by Vanadium Complexes of Bis(Phenolate) Ligands Guoqi Zhang, Brian L. Scott, Ruilian Wu, L. A. “Pete” Silks, and Susan K. Hanson pp 7354–7361 DOI: 10.1021/ic3007525

Time Resolved Infrared Spectroscopy: Kinetic Studies of Weakly Binding Ligands in an Iron–Iron Hydrogenase Model Compound Sohail Muhammad, Salvador Moncho, Edward N. Brothers, Marcetta Y. Darensbourg, Donald J. Darensbourg, and Ashfaq A. Bengali pp 7362–7369 DOI: 10.1021/ic300785z

Room-Temperature Synthesis, Hydrothermal Recrystallization, and Properties of Metastable Stoichiometric FeSe F. Nitsche, T. Goltz, H.-H. Klauss, A. Isaeva, U. Müller, W. Schnelle, P. Simon, Th. Doert, and M. Ruck pp 7370–7376 DOI: 10.1021/ic300798p

Molecular Vibration Spectroscopy Studies on Novel Trinuclear Rhodium-7-Hydride Complexes of the General Type {[Rh(PP*)X]3(μ2-X)3(μ3-X)}(BF4)2 (X = H, D) Christina Kohrt, Sven Hansen, Hans-Joachim Drexler, Uwe Rosenthal, Axel Schulz, and Detlef Heller pp 7377–7383 DOI: 10.1021/ic300802d

QTAIM Analysis of the Bonding in Mo–Mo Bonded Dimolybdenum Complexes Juan F. Van der Maelen and Javier A. Cabeza pp 7384–7391 DOI: 10.1021/ic300845g

Intensely Luminescent Homoleptic Alkynyl Decanuclear Gold(I) Clusters and Their Cationic Octanuclear Phosphine Derivatives Igor O. Koshevoy, Yuh-Chia Chang, Antti J. Karttunen, Stanislav I. Selivanov, Janne Jänis, Matti Haukka, Tapani Pakkanen, Sergey P. Tunik, and Pi-Tai Chou pp 7392–7403 DOI: 10.1021/ic300856h

[C7H10N][In3Se5]: A Layered Selenide with Two Indium Coordination Environments Sarah J. Ewing, Anthony V. Powell, and Paz Vaqueiro pp 7404–7409 DOI: 10.1021/ic300861h

Oxozinc Carboxylate Complexes: A New Synthetic Approach and the Carboxylate Ligand Effect on the Noncovalent-Interactions-Driven Self-Assembly Wojciech Bury, Iwona Justyniak, Daniel Prochowicz, Anna Rola-Noworyta, and Janusz Lewiński pp 7410–7414 DOI: 10.1021/ic300864n

OMS, OM(η2-SO), and OM(η2-SO)(η2-SO2) Molecules (M = Ti, Zr, Hf): Infrared Spectra and Density Functional Calculations Xing Liu, Xuefeng Wang, Qiang Wang, and Lester Andrews pp 7415–7424 DOI: 10.1021/ic3008987

Solvothermal Synthesis, Crystal Growth, and Structure Determination of Sodium and Potassium Guanidinate Peter Klaus Sawinski and Richard Dronskowski pp 7425–7430 DOI: 10.1021/ic301005x

Steric Modifications Tune the Regioselectivity of the Alkane Oxidation Catalyzed by Non-Heme Iron Complexes Yu He, John D. Gorden, and Christian R. Goldsmith pp 7431–7431 DOI: 10.1021/ic301242p

Issue 14

Two-Dimensional 3d–4f Networks Containing Planar Co4Ln2 Clusters with Single-Molecule-Magnet Behaviors Yue Liu, Zhi Chen, Jia Ren, Xiao-Qing Zhao, Peng Cheng, and Bin Zhao pp 7433–7435 DOI: 10.1021/ic300372v

Role of the Alkali-Metal Cation Size in the Self-Assembly of Polyoxometalate-Monolayer Shells on Gold Nanoparticles Yifeng Wang, Offer Zeiri, Shelly Sharet, and Ira A. Weinstock pp 7436–7438 DOI: 10.1021/ic300431a

A μ9-Iodide in a Tricapped Trigonal-Prismatic Geometry Yi-Juan Li, Camille Latouche, Samia Kahlal, Jian-Hong Liao, Rajendra Singh Dhayal, Jean-Yves Saillard, and C. W. Liu pp 7439–7441 DOI: 10.1021/ic3007475

Bis[tetraruthenium(IV)]-Containing Polyoxometalates: [{RuIV4O6(H2O)9}2Sb2W20O68(OH)2]4– and [{RuIV4O6(H2O)9}2{Fe(H2O)2}2{β-TeW9O33}2H]− Irina V. Kalinina, Natalya V. Izarova, and Ulrich Kortz pp 7442–7444 DOI: 10.1021/ic300849b

Regular High-Nuclearity Species from Square Building Blocks: A Triangular 3 × [2 × 2] Ni12 Complex Generated by the Self-assembly of Three [2 × 2] Ni4 Molecular Grids Yurii S. Moroz, Serhiy Demeshko, Matti Haukka, Andriy Mokhir, Utpal Mitra, Michael Stocker, Paul Müller, Franc Meyer, and Igor O. Fritsky pp 7445–7447 DOI: 10.1021/ic300902z

Iron(II) Complexes Containing Octadentate Tetraazamacrocycles as ParaCEST Magnetic Resonance Imaging Contrast Agents Sarina J. Dorazio and Janet R. Morrow pp 7448–7450 DOI: 10.1021/ic301001u

A Strongly Blue-Emitting Heptametallic [DyIII7] Centered-Octahedral Single-Molecule Magnet Angelos B. Canaj, Demetrios I. Tzimopoulos, Aggelos Philippidis, George E. Kostakis, and Constantinos J. Milios pp 7451–7453 DOI: 10.1021/ic301038q

Targeted Synthesis of Heterobimetallic Compounds Containing a Discrete Vanadium(V)−μ-Oxygen–Iron(III) Core Kisholoy Bhattacharya, Manoranjan Maity, Dhrubajyoti Mondal, Akira Endo, and Muktimoy Chaudhury pp 7454–7456 DOI: 10.1021/ic301054r

Synthesis and Characterization of a Neutral Titanium Tris(iminosemiquinone) Complex Featuring Redox-Active Ligands Kensha Marie Clark, Jesper Bendix, Alan F. Heyduk, and Joseph W. Ziller pp 7457–7459 DOI: 10.1021/ic301059p

A [24-MC-6] Zinc Metallacoronate with a Nonsteroidal Antiinflammatory Drug as the Constructing Ligand Alketa Tarushi, Filippos Kastanias, Vassilis Psycharis, Catherine P. Raptopoulou, George Psomas, and Dimitris P. Kessissoglou pp 7460–7462 DOI: 10.1021/ic3010757

Mixed-Valence Uranium Germanate and Silicate: Csx(UVO)(UIV/VO)2(Ge2O7)2 (x = 3.18) and Cs4(UVO)(UIV/VO)2(Si2O7)2 Chun-Liang Chen, Quang Bac Nguyen, Chih-Shan Chen, and Kwang-Hwa Lii pp 7463–7465 DOI: 10.1021/ic301091f

Biomimetic Models for the Active Site of [Fe]Hydrogenase Featuring an Acylmethyl(hydroxymethyl)pyridine Ligand Li-Cheng Song, Zhao-Jun Xie, Miao-Miao Wang, Gao-Yu Zhao, and Hai-Bin Song pp 7466–7468 DOI: 10.1021/ic301146u

K4Fe4P5O20: A New Mixed Valence Microporous Compound with Elliptical Eight-Ring Channels Zhangzhen He, Weilong Zhang, Wendan Cheng, Atsushi Okazawa, and Norimichi Kojima pp 7469–7471 DOI: 10.1021/ic301245c

TM7TM′6B8 (TM = Ta, Nb; TM′ = Ru, Rh, Ir): New Compounds with [B6] Ring Polyanions Qiang Zheng, Miroslav Kohout, Roman Gumeniuk, Nikolay Abramchuk, Horst Borrmann, Yurii Prots, Ulrich Burkhardt, Walter Schnelle, Lev Akselrud, Hui Gu, Andreas Leithe-Jasper, and Yuri Grin pp 7472–7483 DOI: 10.1021/ic201978n

Solvent-Induced Controllable Synthesis, Single-Crystal to Single-Crystal Transformation and Encapsulation of Alq3 for Modulated Luminescence in (4,8)-Connected Metal–Organic Frameworks Ya-Qian Lan, Hai-Long Jiang, Shun-Li Li, and Qiang Xu pp 7484–7491 DOI: 10.1021/ic202635a

Structural Influence on the Photochromic Response of a Series of Ruthenium Mononitrosyl Complexes Benoit Cormary, Sonia Ladeira, Kane Jacob, Pascal G. Lacroix, Theo Woike, Dominik Schaniel, and Isabelle Malfant pp 7492–7501 DOI: 10.1021/ic202702r

Homochiral 1D Helical Chain Based on an Achiral Cu(II) Complex Chihiro Kachi-Terajima, Megumi Ishii, Toshiaki Saito, Chikahide Kanadani, Takunori Harada, and Reiko Kuroda pp 7502–7507 DOI: 10.1021/ic202708e

Vapor-Controlled Linkage Isomerization of a Vapochromic Bis(thiocyanato)platinum(II) Complex: New External Stimuli To Control Isomerization Behavior Atsushi Kobayashi, Yuki Fukuzawa, Ho-Chol Chang, and Masako Kato pp 7508–7519 DOI: 10.1021/ic202734f

[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F···H···F– Bridges in a One-Dimensional Polymeric Chain Jamie L. Manson, Adora G. Baldwin, Brian L. Scott, Jesper Bendix, Rico E. Del Sesto, Paul A. Goddard, Yoshimitsu Kohama, Hope E. Tran, Saman Ghannadzadeh, John Singleton, Tom Lancaster, Johannes S. Möller, Stephen J. Blundell, Francis L. Pratt, Vivien S. Zapf, Jinhee Kang, Changhoon Lee, Myung-Hwan Whangbo, and Christopher Baines pp 7520–7528 DOI: 10.1021/ic300111k

Synthesis, Structures, and Magnetic Properties of Three Fluoride-Bridged Lanthanide Compounds: Effect of Bridging Fluoride Ions on Magnetic Behaviors Qi Zhou, Fen Yang, Dan Liu, Yu Peng, Guanghua Li, Zhan Shi, and Shouhua Feng pp 7529–7536 DOI: 10.1021/ic300125y

Luminescent Cyclometalated Alkynylgold(III) Complexes with 6-Phenyl-2,2′-Bipyridine Derivatives: Synthesis, Characterization, Electrochemistry, Photophysics, and Computational Studies Vonika Ka-Man Au, Wai Han Lam, Wing-Tak Wong, and Vivian Wing-Wah Yam pp 7537–7545 DOI: 10.1021/ic300140w

Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation Travis M. Figg, Patrick L. Holland, and Thomas R. Cundari pp 7546–7550 DOI: 10.1021/ic300150u

Probing Ni[S2PR2]2 Electronic Structure to Generate Insight Relevant to Minor Actinide Extraction Chemistry Scott R. Daly, Jason M. Keith, Enrique R. Batista, Kevin S. Boland, Stosh A. Kozimor, Richard L. Martin, and Brian L. Scott pp 7551–7560 DOI: 10.1021/ic3001587

Diruthenium(III,III) Ethynyl-phenyleneimine Molecular Wires: Preparation via On-Complex Schiff Base Condensation Steven P. Cummings, Zhi Cao, Phillip E. Fanwick, Anastasia Kharlamova, and Tong Ren pp 7561–7568 DOI: 10.1021/ic300182h

Trends in the Electronic Structure of Extended Gold Compounds: Implications for Use of Gold in Heterogeneous Catalysis Mao-Sheng Miao, Joshua A. Kurzman, Nisha Mammen, Shobhana Narasimhan, and Ram Seshadri pp 7569–7578 DOI: 10.1021/ic3002674

An Isomorphous Series of Cubic, Copper-Based Triazolyl Isophthalate MOFs: Linker Substitution and Adsorption Properties Jörg Lincke, Daniel Lässig, Merten Kobalz, Jens Bergmann, Marcel Handke, Jens Möllmer, Marcus Lange, Christian Roth, Andreas Möller, Reiner Staudt, and Harald Krautscheid pp 7579–7586 DOI: 10.1021/ic3003228

Two Triazole-Based Metal–Organic Frameworks Constructed from Nanosized Cu20 and Cu30 Wheels Chan-Zi Ruan, Ru Wen, Min-Xia Liang, Xiang-Jian Kong, Yan-Ping Ren, La-Sheng Long, Rong-Bin Huang, and Lan-Sun Zheng pp 7587–7591 DOI: 10.1021/ic3003299

Capped-Tetrahedrally Coordinated Fe(II) and Co(II) Complexes Using a “Click”-Derived Tripodal Ligand: Geometric and Electronic Structures David Schweinfurth, Serhiy Demeshko, Marat M. Khusniyarov, Sebastian Dechert, Venkatanarayana Gurram, Michael R. Buchmeiser, Franc Meyer, and Biprajit Sarkar pp 7592–7597 DOI: 10.1021/ic300392e

Mixed Metallic Ba(Co,Fe)X0.2O3−δ (X = F, Cl) Hexagonal Perovskites: Drastic Effect of Fe-Incorporation on Structural and Electronic Features Mihaela Iorgulescu, Pascal Roussel, Nathalie Tancret, Nicolas Renault, Florence Porcher, Gilles André, Houria Kabbour, and Olivier Mentré pp 7598–7608 DOI: 10.1021/ic3004068

Hypoelectronic Dirhenaboranes Having Eight to Twelve Vertices: Internal Versus Surface Rhenium–Rhenium Bonding Alexandru Lupan and R. Bruce King pp 7609–7616 DOI: 10.1021/ic300458w

Enhanced High-Temperature Thermoelectric Performance of Yb14–xCaxMnSb11 Catherine A. Uvarov, Francisco Ortega-Alvarez, and Susan M. Kauzlarich pp 7617–7624 DOI: 10.1021/ic300567c

Shuttling of Nickel Oxidation States in N4S2 Coordination Geometry versus Donor Strength of Tridentate N2S Donor Ligands Sudip K. Chatterjee, Suprakash Roy, Suman Kumar Barman, Ram Chandra Maji, Marilyn M. Olmstead, and Apurba K. Patra pp 7625–7635 DOI: 10.1021/ic300606g

Correlation between Photophysical Parameters and Gold–Gold Distances in Gold(I) (4-Pyridyl)ethynyl Complexes Laura Rodríguez, Montserrat Ferrer, Ramon Crehuet, Josep Anglada, and João Carlos Lima pp 7636–7641 DOI: 10.1021/ic300609f

Dioxomolybdenum(VI) Complexes with Pyrazole Based Aryloxide Ligands: Synthesis, Characterization and Application in Epoxidation of Olefins Jörg A. Schachner, Pedro Traar, Chris Sala, Michaela Melcher, Bastian N. Harum, Alexander F. Sax, Manuel Volpe, Ferdinand Belaj, and Nadia C. Mösch-Zanetti pp 7642–7649 DOI: 10.1021/ic300648p

High-Pressure Synthesis, Crystal Structure, and Properties of BiPd2O4 with Pd2+ and Pd4+ Ordering and PbPd2O4 Wei Yi, Yoshitaka Matsushita, Masahiko Tanaka, and Alexei A. Belik pp 7650–7656 DOI: 10.1021/ic3006579

Are N-Heterocyclic Carbenes “Better” Ligands than Phosphines in Main Group Chemistry? A Theoretical Case Study of Ligand-Stabilized E2 Molecules, L-E-E-L (L = NHC, phosphine; E = C, Si, Ge, Sn, Pb, N, P, As, Sb, Bi) David J. D. Wilson, Shannon A. Couchman, and Jason L. Dutton pp 7657–7668 DOI: 10.1021/ic300686n

Cadmium(II) Complexes: Mimics of Organophosphate Pesticide Degrading Enzymes and Metallo-β-lactamases Lena J. Daumann, Lawrence. R. Gahan, Peter Comba, and Gerhard Schenk pp 7669–7681 DOI: 10.1021/ic300687y

Gold(I) Complexes of Brominated Azadipyrromethene Ligands Lei Gao, Nihal Deligonul, and Thomas G. Gray pp 7682–7688 DOI: 10.1021/ic300709n

High Proton Conductivity in a Flexible, Cross-Linked, Ultramicroporous Magnesium Tetraphosphonate Hybrid Framework Rosario M. P. Colodrero, Pascual Olivera-Pastor, Enrique R. Losilla, Daniel Hernández-Alonso, Miguel A. G. Aranda, Laura Leon-Reina, Jordi Rius, Konstantinos D. Demadis, Bernard Moreau, Didier Villemin, Miguel Palomino, Fernando Rey, and Aurelio Cabeza pp 7689–7698 DOI: 10.1021/ic3007316

First Palladium(II) and Platinum(II) Complexes from Employment of 2,6-Diacetylpyridine Dioxime: Synthesis, Structural and Spectroscopic Characterization, and Biological Evaluation Evangelia S. Koumousi, Marianthi Zampakou, Catherine P. Raptopoulou, Vassilis Psycharis, Christine M. Beavers, Simon J. Teat, George Psomas, and Theocharis C. Stamatatos pp 7699–7710 DOI: 10.1021/ic300739x

Three Alkali-Metal–Gold–Gallium Systems. Ternary Tunnel Structures and Some Problems with Poorly Ordered Cations Volodymyr Smetana, Gordon J. Miller, and John D. Corbett pp 7711–7721 DOI: 10.1021/ic300740u

Photophysical and Photoredox Characteristics of a Novel Tricarbonyl Rhenium(I) Complex Having an Arylborane-Appended Aromatic Diimine Ligand Akitaka Ito, Yuanyuan Kang, Shota Saito, Eri Sakuda, and Noboru Kitamura pp 7722–7732 DOI: 10.1021/ic3007469

NiO@ZnO Heterostructured Nanotubes: Coelectrospinning Fabrication, Characterization, and Highly Enhanced Gas Sensing Properties Lin Xu, Ruifang Zheng, Shuhai Liu, Jian Song, Jiansheng Chen, Biao Dong, and Hongwei Song pp 7733–7740 DOI: 10.1021/ic300749a

Aqueous Complexation of Thorium(IV), Uranium(IV), Neptunium(IV), Plutonium(III/IV), and Cerium(III/IV) with DTPA M. Alex Brown, Alena Paulenova, and Artem V. Gelis pp 7741–7748 DOI: 10.1021/ic300757k

Comparison of Amorphous Iridium Water-Oxidation Electrocatalysts Prepared from Soluble Precursors James D. Blakemore, Nathan D. Schley, Maxwell N. Kushner-Lenhoff, Andrew M. Winter, Francis D’Souza, Robert H. Crabtree, and Gary W. Brudvig pp 7749–7763 DOI: 10.1021/ic300764f

Nanostructured SnO2–ZnO Heterojunction Photocatalysts Showing Enhanced Photocatalytic Activity for the Degradation of Organic Dyes Md. Tamez Uddin, Yohann Nicolas, Céline Olivier, Thierry Toupance, Laurent Servant, Mathis M. Müller, Hans-Joachim Kleebe, Jürgen Ziegler, and Wolfram Jaegermann pp 7764–7773 DOI: 10.1021/ic300794j

Fluorinated Hydrotalcites: The Addition of Highly Electronegative Species in Layered Double Hydroxides To Tune Basicity Enrique Lima, María de Jesús Martínez-Ortiz, Renata Isabel Gutiérrez Reyes, and Marco Vera pp 7774–7781 DOI: 10.1021/ic300799e

Chalcogeno[bis(phosphaalkenyl)] Germanium and Tin Compounds Tibor-Gabor Kocsor, Dimitri Matioszek, Gabriela Nemeş, Annie Castel, Jean Escudié, Petronela M. Petrar, Nathalie Saffon, and Ionel Haiduc pp 7782–7787 DOI: 10.1021/ic300810q

Phase Relationships in the BaO–Ga2O3–Ta2O5 System and the Structure of Ba6Ga21TaO40 Jiang Cao, Xiaodi Yu, Xiaojun Kuang, and Qiang Su pp 7788–7793 DOI: 10.1021/ic3008238

Analysis of the Putative Cr–Cr Quintuple Bond in Ar′CrCrAr′ (Ar′ = C6H3-2,6(C6H3-2,6-Pri2)2 Based on the Combined Natural Orbitals for Chemical Valence and Extended Transition State Method Sylvester Ndambuki and Tom Ziegler pp 7794–7800 DOI: 10.1021/ic300824u

Synthesis of a Uranyl Persulfide Complex and Quantum Chemical Studies of Formation and Topologies of Hypothetical Uranyl Persulfide Cage Clusters Daniel J. Grant, Zhehui Weng, Laurent J. Jouffret, Peter C. Burns, and Laura Gagliardi pp 7801–7809 DOI: 10.1021/ic3008574

Dimolybdenum Cyclopentadienyl Complexes with Bridging Chalcogenophosphinidene Ligands Belén Alvarez, M. Angeles Alvarez, Inmaculada Amor, M. Esther García, Daniel García-Vivó, Jaime Suárez, and Miguel A. Ruiz pp 7810–7824 DOI: 10.1021/ic300869z

Preparation of a Family of Hexanuclear Rhenium Cluster Complexes Containing 5-(Phenyl)tetrazol-2-yl Ligands and Alkylation of 5-Substituted Tetrazolate Ligands Jessica L. Durham, Joan N. Tirado, Stanley A. Knott, Meghan K. Oh, Robert McDonald, and Lisa F. Szczepura pp 7825–7836 DOI: 10.1021/ic300877r

General Pathway of Sulfur-Chain Breakage of Polythionates by Iodine Confirmed by the Kinetics and Mechanism of the Pentathionate–Iodine Reaction Li Xu, György Csekö, Tamás Kégl, and Attila K. Horváth pp 7837–7843 DOI: 10.1021/ic300895c

Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)4 Dong Woo Lee, Dan-bee Bak, Saet Byeol Kim, Jiwon Kim, and Kang Min Ok pp 7844–7850 DOI: 10.1021/ic300909s

Effect of Chelate Ring Expansion on Jahn–Teller Distortion and Jahn–Teller Dynamics in Copper(II) Complexes Katharina Mack, Anica Wünsche von Leupoldt, Christoph Förster, Maria Ezhevskaya, Dariush Hinderberger, Karl W. Klinkhammer, and Katja Heinze pp 7851–7858 DOI: 10.1021/ic300929g

Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates Matthew J. Polinski, Shuao Wang, Justin N. Cross, Evgeny V. Alekseev, Wulf Depmeier, and Thomas E. Albrecht-Schmitt pp 7859–7866 DOI: 10.1021/ic3009317

Varying the Lewis Base Coordination of the Y2N2 Core in the Reduced Dinitrogen Complexes {[(Me3Si)2N]2(L)Y}2(μ-η2:η2-N2) (L = Benzonitrile, Pyridines, Triphenylphosphine Oxide, and Trimethylamine N-Oxide) Jordan F. Corbey, Joy H. Farnaby, Jefferson E. Bates, Joseph W. Ziller, Filipp Furche, and William J. Evans pp 7867–7874 DOI: 10.1021/ic300934g

Synthetic Control to Achieve Lanthanide(III)/Pyrimidine-4,6-dicarboxylate Compounds by Preventing Oxalate Formation: Structural, Magnetic, and Luminescent Properties Javier Cepeda, Rolindes Balda, Garikoitz Beobide, Oscar Castillo, Joaquín Fernández, Antonio Luque, Sonia Pérez-Yáñez, and Pascual Román pp 7875–7888 DOI: 10.1021/ic3009392

2D Corrugated Magnesium Carboxyphosphonate Materials: Topotactic Transformations and Interlayer “Decoration” with Ammonia Konstantinos D. Demadis, Nikos Famelis, Aurelio Cabeza, Miguel A.G. Aranda, Rosario M. P. Colodrero, and Antonia Infantes-Molina pp 7889–7896 DOI: 10.1021/ic300941t

Insights into the Mechanisms of Amyloid Formation of ZnII-Ab11-28: pH-Dependent Zinc Coordination and Overall Charge as Key Parameters for Kinetics and the Structure of ZnII-Ab11-28 Aggregates Bruno Alies, Giovanni LaPenna, Stéphanie Sayen, Emmanuel Guillon, Christelle Hureau, and Peter Faller pp 7897–7902 DOI: 10.1021/ic300972j

Oxidation Products of Calcium and Strontium Bis(diphenylphosphanide) Tareq M. A. Al-Shboul, Gritt Volland, Helmar Görls, Sven Krieck, and Matthias Westerhausen pp 7903–7912 DOI: 10.1021/ic300975s

Selective and Reversible Base-Induced Elimination of a Ruthenium Dithioether Yields a Vinyl Metallosulfonium Complex Rajat Chauhan, Mark S. Mashuta, and Craig A. Grapperhaus pp 7913–7920 DOI: 10.1021/ic300983x

Polyoxometalates Functionalized by Bisphosphonate Ligands: Synthesis, Structural, Magnetic, and Spectroscopic Characterizations and Activity on Tumor Cell Lines Hani El Moll, Wei Zhu, Eric Oldfield, L. Marleny Rodriguez-Albelo, Pierre Mialane, Jérôme Marrot, Neus Vila, Israel Martyr Mbomekallé, Eric Rivière, Carole Duboc, and Anne Dolbecq pp 7921–7931 DOI: 10.1021/ic3010079

Reversible Deprotonation and Protonation Behaviors of a Tetra-Protonated γ-Keggin Silicodecatungstate Kosei Sugahara, Shinjiro Kuzuya, Tomohisa Hirano, Keigo Kamata, and Noritaka Mizuno pp 7932–7939 DOI: 10.1021/ic3010773

Oxidation State Delineation via U LIII-Edge XANES in a Series of Isostructural Uranium Coordination Complexes Boris Kosog, Henry S. La Pierre, Melissa A. Denecke, Frank W. Heinemann, and Karsten Meyer pp 7940–7944 DOI: 10.1021/ic3011234

Issue 15

Solvent-Mediated Room Temperature Synthesis of Highly Crystalline Cu9S5 (Cu1.8S), CuSe, PbS, and PbSe from Their Elements Prashant Kumar, Meenakshi Gusain, and Rajamani Nagarajan pp 7945–7947 DOI: 10.1021/ic301422x

Fluorescence Detection of Adenosine Triphosphate in an Aqueous Solution Using a Combination of Copper(II) Complexes Evgeny Kataev, René Arnold, Tobias Rüffer, and Heinrich Lang pp 7948–7950 DOI: 10.1021/ic300805q

O-Atom Exchange between H2O and CO2 Mediated by a Bis(dithiolene)tungsten Complex Junhyeok Seo and Eunsuk Kim pp 7951–7953 DOI: 10.1021/ic300906j

A Robust Metal–Organic Framework Constructed from Alkoxo-Bridged Binuclear Nodes and Hexamethylenetetramine Spacers: Crystal Structure and Sorption Studies Elena Ilyes, Mihaela Florea, Augustin M. Madalan, Ionel Haiduc, Vasile I. Parvulescu, and Marius Andruh pp 7954–7956 DOI: 10.1021/ic301139j

Metal Coordination Induced π-Extension and Triplet State Production in Diketopyrrolopyrrole Chromophores Catherine E. McCusker, Delphine Hablot, Raymond Ziessel, and Felix N. Castellano pp 7957–7959 DOI: 10.1021/ic301238e

Mass Spectral Studies Reveal the Structure of Aβ1–16–Cu2+ Complex Resembling ATCUN Motif Yamini P. Ginotra, Shefali N. Ramteke, Rapole Srikanth, and Prasad P. Kulkarni pp 7960–7962 DOI: 10.1021/ic301244x

Phase-Change Materials Exhibiting Tristability: Interconverting Forms of Crystalline α-, β-, and Glassy K2ZnSn3S8 Zohreh Hassanzadeh Fard and Mercouri G. Kanatzidis pp 7963–7965 DOI: 10.1021/ic301276y

Halide and Hydroxide Linearly Bridged Bimetallic Copper(II) Complexes: Trends in Strong Antiferromagnetic Superexchange Interactions Daniel L. Reger, Andrea E. Pascui, Mark D. Smith, Julia Jezierska, and Andrew Ozarowski pp 7966–7968 DOI: 10.1021/ic301321r

Dioxygen Oxidation Cu(II) → Cu(III) in the Copper Complex of cyclo(Lys-dHis-βAla-His): A Case Study by EXAFS and XANES Approach Alessandro Pratesi, Gabriele Giuli, Maria Rita Cicconi, Stefano Della Longa, Tsu-Chien Weng, and Mauro Ginanneschi pp 7969–7976 DOI: 10.1021/ic201469h

Syntheses and Luminescent Properties of 3,5-Diphenylpyrazolato-Bridged Heteropolynuclear Platinum Complexes. The Influence of Chloride Ligands on the Emission Energy Revealed by the Systematic Replacement of Chloride Ligands by 3,5-Dimethylpyrazolate Seiji Akatsu, Yasunori Kanematsu, Taka-aki Kurihara, Shota Sueyoshi, Yasuhiro Arikawa, Masayoshi Onishi, Shoji Ishizaka, Noboru Kitamura, Yoshihide Nakao, Shigeyoshi Sakaki, and Keisuke Umakoshi pp 7977–7992 DOI: 10.1021/ic202663q

Synthesis, Crystal Structures, Magnetic Properties and Catecholase Activity of Double Phenoxido-Bridged Penta-Coordinated Dinuclear Nickel(II) Complexes Derived from Reduced Schiff-Base Ligands: Mechanistic Inference of Catecholase Activity Apurba Biswas, Lakshmi Kanta Das, Michael G. B. Drew, Guillem Aromí, Patrick Gamez, and Ashutosh Ghosh pp 7993–8001 DOI: 10.1021/ic202748m

Density Functional Theory Studies on the Oxidation of 5′-dGMP and 5′-dAMP by a Platinum(IV) Complex Alireza Ariafard, Elham S. Tabatabaie, Simin Aghmasheh, Sahar Najaflo, and Brian F. Yates pp 8002–8013 DOI: 10.1021/ic300038m

Observation of an Organic Acid Mediated Spin State Transition in a Co(II)–Schiff Base Complex: An EPR, HYSCORE, and DFT Study Evi Vinck, Emma Carter, Damien M. Murphy, and Sabine Van Doorslaer pp 8014–8024 DOI: 10.1021/ic300058p

AgI/VV Heterobimetallic Frameworks Generated from Novel-Type {Ag2(VO2F2)2(triazole)4} Secondary Building Blocks: A New Aspect in the Design of SVOF Hybrids Ganna A. Senchyk, Valeriy O. Bukhan’ko, Andrey B. Lysenko, Harald Krautscheid, Eduard B. Rusanov, Alexandr N. Chernega, Miroslaw Karbowiak, and Konstantin V. Domasevitch pp 8025–8033 DOI: 10.1021/ic3000894

Enhanced Guest Affinity and Enantioselectivity through Variation of the Gd3+[15-Metallacrown-5] Side Chain Joseph T. Grant, Joseph Jankolovits, and Vincent L. Pecoraro pp 8034–8041 DOI: 10.1021/ic300110g

Isostructural Series of Nine-Coordinate Chiral Lanthanide Complexes Based on Triazacyclononane James W. Walton, Rachel Carr, Nicholas H. Evans, Alexander M. Funk, Alan M. Kenwright, David Parker, Dmitry S. Yufit, Mauro Botta, Sara De Pinto, and Ka-Leung Wong pp 8042–8056 DOI: 10.1021/ic300147p

Photochemical Production of NADH Using Cobaloxime Catalysts and Visible-Light Energy Jin Ah Kim, Soojin Kim, Jungha Lee, Jin-Oog Baeg, and Jinheung Kim pp 8057–8063 DOI: 10.1021/ic300185n

Accommodating Unwelcome Guests in Inorganic Layered Hosts: Inclusion of Chloranil in a Layered Double Hydroxide Dipak Dutta and Sukumaran Vasudevan pp 8064–8072 DOI: 10.1021/ic3002948

Synthesis and Characterization of Li11Nd18Fe4O39−δ Yao-Chang Chen, Nik Reeves-McLaren, Paul A. Bingham, Susan D. Forder, and Anthony R. West pp 8073–8082 DOI: 10.1021/ic300296s

Fine Tuning the Reactivity of Corrole-Based Catalytic Antioxidants Zoya Okun and Zeev Gross pp 8083–8090 DOI: 10.1021/ic300408s

Comparative Study of CN and NC Type Cyclometalated Ruthenium Complexes with a NAD+/NADH Function Sumanta Kumar Padhi, Ryoichi Fukuda, Masahiro Ehara, and Koji Tanaka pp 8091–8102 DOI: 10.1021/ic300449q

η6-Hexahelicene Complexes of Iridium and Ruthenium: Running along the Helix Celedonio M. Álvarez, Héctor Barbero, Luis A. García-Escudero, Jose M. Martín-Alvarez, Cristina Martínez-Pérez, and Daniel Miguel pp 8103–8111 DOI: 10.1021/ic300462z

Single-Crystal Structures, Optical Absorptions, and Electronic Distributions of Thorium Oxychalcogenides ThOQ (Q = S, Se, Te) Lukasz A. Koscielski, Emilie Ringe, Richard P. Van Duyne, Donald E. Ellis, and James A. Ibers pp 8112–8118 DOI: 10.1021/ic300510x

Cd4Cu7As, The First Representative of a Fully Ordered, Orthorhombically Distorted MgCu2 Laves Phase Oliver Osters, Tom Nilges, Michael Schöneich, Peer Schmidt, Jan Rothballer, Florian Pielnhofer, and Richard Weihrich pp 8119–8127 DOI: 10.1021/ic3005213

Selenadiazolopyridine: A Synthon for Supramolecular Assembly and Complexes with Metallophilic Interactions Goutam Mukherjee, Puspendra Singh, Chandrasekhar Ganguri, Sagar Sharma, Harkesh B. Singh, Nidhi Goel, Udai P. Singh, and Ray J. Butcher pp 8128–8140 DOI: 10.1021/ic3005272

Reversible Solvatomagnetic Effect in Novel Tetranuclear Cubane-Type Ni4 Complexes and Magnetostructural Correlations for the [Ni4(μ3-O)4] Core Animesh Das, Felix J. Klinke, Serhiy Demeshko, Steffen Meyer, Sebastian Dechert, and Franc Meyer pp 8141–8149 DOI: 10.1021/ic300535d

A Rare Phenoxido/Acetato/Azido Bridged Trinuclear and an Unprecedented Phenoxido/Azido Bridged One-Dimensional Polynuclear Nickel(II) Complexes: Synthesis, Crystal Structure, and Magnetic Properties with Theoretical Investigations on the Exchange Mechanism Rituparna Biswas, Sandip Mukherjee, Paramita Kar, and Ashutosh Ghosh pp 8150–8160 DOI: 10.1021/ic300547w

Metastable 11 K Superconductor Na1–yFe2–xAs2 Gina M. Friederichs, Inga Schellenberg, Rainer Pöttgen, Viola Duppel, Lorenz Kienle, Jörn Schmedt auf der Günne, and Dirk Johrendt pp 8161–8167 DOI: 10.1021/ic3005618

Interaction between the Heme and a G-Quartet in a Heme–DNA Complex Kaori Saito, Hulin Tai, Hikaru Hemmi, Nagao Kobayashi, and Yasuhiko Yamamoto pp 8168–8176 DOI: 10.1021/ic3005739

Synthetic Approaches to (smif)2Ti (smif = 1,3-di-(2-pyridyl)-2-azaallyl) Reveal Redox Non-Innocence and C–C Bond-Formation Brenda A. Frazier, Peter T. Wolczanski, Ivan Keresztes, Serena DeBeer, Emil B. Lobkovsky, Aaron W. Pierpont, and Thomas R. Cundari pp 8177–8186 DOI: 10.1021/ic300590t

Synthesis and Characterization of Rhodium Complexes with Phosphine-Stabilized Germylenes Juan M. García, Edgar Ocando-Mavárez, Tsuyoshi Kato, David Santiago Coll, Alexander Briceño, Nathalie Saffon-Merceron, and Antoine Baceiredo pp 8187–8193 DOI: 10.1021/ic300600c

Theoretical Prediction of Spin-Crossover Temperatures in Ligand-Driven Light-Induced Spin Change Systems Jordi Cirera and Francesco Paesani pp 8194–8201 DOI: 10.1021/ic300750c

Spectroscopic and Electrochemical Study of the Interconversion and Decomplexation of Cobalt(II) Sandwich Polyoxometalates Based on a Dawson-Type Anion Laurent Ruhlmann, Delphine Schaming, Iftikhar Ahmed, Aimeric Courville, Jacqueline Canny, and René Thouvenot pp 8202–8211 DOI: 10.1021/ic3007603

Chlorine/Methyl Exchange Reactions in Silylated Aminostibanes: A New Route To Stibinostibonium Cations Christian Hering, Mathias Lehmann, Axel Schulz, and Alexander Villinger pp 8212–8224 DOI: 10.1021/ic300770b

Utilization of Phosphinoamide Ligands in Homobimetallic Fe and Mn Complexes: The Effect of Disparate Coordination Environments on Metal–Metal Interactions and Magnetic and Redox Properties Subramaniam Kuppuswamy, Mark W. Bezpalko, Tamara M. Powers, Mark M. Turnbull, Bruce M. Foxman, and Christine M. Thomas pp 8225–8240 DOI: 10.1021/ic300776y

Accessibility and Selective Stabilization of the Principal Spin States of Iron by Pyridyl versus Phenolic Ketimines: Modulation of the 6A1 ↔ 2T2 Ground-State Transformation of the [FeN4O2]+ Chromophore Musa S. Shongwe, Usama A. Al-Zaabi, Faizah Al-Mjeni, Carla S. Eribal, Ekkehard Sinn, Imaddin A. Al-Omari, Hussein H. Hamdeh, Dariusz Matoga, Harry Adams, Michael J. Morris, Arnold L. Rheingold, Eckhard Bill, and David J. Sellmyer pp 8241–8253 DOI: 10.1021/ic300732r

Synthesis and the Thermal and Catalytic Dehydrogenation Reactions of Amine-Thioboranes Alasdair P. M. Robertson, Mairi F. Haddow, and Ian Manners pp 8254–8264 DOI: 10.1021/ic3008188

Electronic Structure of Six-Membered N-Heterocyclic Carbenes and Its Heavier Analogues: Reactivity of the Lone Pair versus the Exocyclic Double Bond Vallyanga Chalil Rojisha, Susmita De, and Pattiyil Parameswaran pp 8265–8274 DOI: 10.1021/ic300821r

Proton-Coupled Electron Transfer between 4-Cyanophenol and Photoexcited Rhenium(I) Complexes with Different Protonatable Sites Catherine Bronner and Oliver S. Wenger pp 8275–8283 DOI: 10.1021/ic300834c

Phosphopeptide Selective Coordination Complexes as Promising Src Homology 2 Domain Mimetics Joel A. Drewry, Eugenia Duodu, Amir Mazouchi, Paul Spagnuolo , Steven Burger, Claudiu C. Gradinaru, Paul Ayers, Aaron D. Schimmer, and Patrick T. Gunning pp 8284–8291 DOI: 10.1021/ic3008393

Triple C–H Bond Activation of a Nickel-Bound Methyl Group: Synthesis and X-Ray Structure of a Carbide Cluster (NiCp)6(μ6-C) Włodzimierz Buchowicz, Beata Herbaczyńska, Lucjan B. Jerzykiewicz, Tadeusz Lis, Stanisław Pasynkiewicz, and Antoni Pietrzykowski pp 8292–8297 DOI: 10.1021/ic3008409

Copper(I) Complexes with Trispyrazolylmethane Ligands: Synthesis, Characterization, and Catalytic Activity in Cross-Coupling Reactions Estela Haldón, Eleuterio Álvarez, M. Carmen Nicasio, and Pedro J. Pérez pp 8298–8306 DOI: 10.1021/ic300843a

Toward an Iron(II) Spin-Crossover Grafted Phosphazene Polymer Ross J. Davidson, Eric W. Ainscough, Andrew M. Brodie, Geoffrey B. Jameson, Mark R. Waterland, Harry R. Allcock, Mark D. Hindenlang, Boujemaa Moubaraki, Keith S. Murray, Keith C. Gordon, Raphael Horvath, and Guy N. L. Jameson pp 8307–8316 DOI: 10.1021/ic300853f

Bistable Dynamic Coordination Polymer Showing Reversible Structural and Functional Transformations Sanjog S. Nagarkar, Raja Das, Pankaj Poddar, and Sujit K. Ghosh pp 8317–8321 DOI: 10.1021/ic301481p

Novel Class of Heterometallic Cubane and Boride Clusters Containing Heavier Group 16 Elements Arunabha Thakur, Soumik Sao, V. Ramkumar, and Sundargopal Ghosh pp 8322–8330 DOI: 10.1021/ic3008602

Evidence for the Formation of a Mo–H Intermediate in the Catalytic Cycle of Formate Dehydrogenase Matteo Tiberti, Elena Papaleo, Nino Russo, Luca De Gioia, and Giuseppe Zampella pp 8331–8339 DOI: 10.1021/ic300863d

Theoretical Investigation of Paramagnetic NMR Shifts in Transition Metal Acetylacetonato Complexes: Analysis of Signs, Magnitudes, and the Role of the Covalency of Ligand–Metal Bonding Ben Pritchard and Jochen Autschbach pp 8340–8351 DOI: 10.1021/ic300868v

Ligand Effects on Hydrogen Atom Transfer from Hydrocarbons to Three-Coordinate Iron Imides Ryan E. Cowley and Patrick L. Holland pp 8352–8361 DOI: 10.1021/ic300870y

Insight into the Electronic Structure, Optical Properties, And Redox Behavior of the Hybrid Phthalocyaninoclathrochelates from Experimental and Density Functional Theory Approaches Jared R. Sabin, Oleg A. Varzatskii, Yan Z. Voloshin, Zoya A. Starikova, Valentin V. Novikov, and Victor N. Nemykin pp 8362–8372 DOI: 10.1021/ic3008798

Tailoring the Exchange Interaction in Covalently Linked Basic Carboxylate Clusters through Bridging Ligand Selection Pablo Alborés, Christian Plenk, and Eva Rentschler pp 8373–8384 DOI: 10.1021/ic300911j

Synthesis, Structure, and Properties of the New Mixed-Valent Dodecahalogenotrimetallate In4Ti3Br12 and its Relation to Compounds A3Ti2X9 (A = K, In; X = Cl, Br) Melanie Schroeder, Sabina Hartwig, Karl W. Krämer, Silvio Decurtins, and Harald Hillebrecht pp 8385–8393 DOI: 10.1021/ic3009442

Arylgold(I) Complexes from Base-Assisted Transmetalation: Structures, NMR Properties, and Density-Functional Theory Calculations David V. Partyka, Matthias Zeller, Allen D. Hunter, and Thomas G. Gray pp 8394–8401 DOI: 10.1021/ic3009464

Novel (3,4,6)-Connected Metal–Organic Framework with High Stability and Gas-Uptake Capability Chao Hou, Qing Liu, Jian Fan, Yue Zhao, Peng Wang, and Wei-Yin Sun pp 8402–8408 DOI: 10.1021/ic300950h

An Unprecedented Structural Interconversion in Solution of Aggregate Zinc(II) Salen Schiff-Base Complexes Giuseppe Consiglio, Salvatore Failla, Paolo Finocchiaro, Ivan Pietro Oliveri, and Santo Di Bella pp 8409–8418 DOI: 10.1021/ic300954y

Syntheses, Structures, and Spectroscopic Properties of Plutonium and Americium Phosphites and the Redetermination of the Ionic Radii of Pu(III) and Am(III) Justin N. Cross, Eric M. Villa, Shuao Wang, Juan Diwu, Matthew J. Polinski, and Thomas E. Albrecht-Schmitt pp 8419–8424 DOI: 10.1021/ic300958z

The Syntheses and Electrochemical Studies of a Ferrocene Substituted Diiminopyridine Ligand and Its P, S, Se, and Te Complexes Eleanor Magdzinski, Pierangelo Gobbo, Caleb D. Martin, Mark S. Workentin, and Paul J. Ragogna pp 8425–8432 DOI: 10.1021/ic300974u

Electron Paramagnetic Resonance Analysis of La1–xMxMnO3+δ (M = Ce, Sr) Perovskite-Like Nanostructured Catalysts Cesare Oliva, Mattia Allieta, Marco Scavini, Cesare Biffi, Ilenia Rossetti, and Lucio Forni pp 8433–8440 DOI: 10.1021/ic300977e

Molecular [(Fe3)–(Fe3)] and [(Fe4)–(Fe4)] Coordination Cluster Pairs as Single or Composite Arrays E. Carolina Sañudo, Jorge Salinas Uber, Alba Pons Balagué, Olivier Roubeau, and Guillem Aromí pp 8441–8446 DOI: 10.1021/ic300995g

Synthesis, Spectral, and Electrochemical Characterization of the First Arsenic(V)-Phthalocyanines Hiroaki Isago and Yutaka Kagaya pp 8447–8454 DOI: 10.1021/ic301002s

Insight into the Dynamics of Lanthanide-DTPA Complexes As Revealed by Oxygen-17 NMR Luca Fusaro, Francesca Mocci, Robert N. Muller, and Michel Luhmer pp 8455–8461 DOI: 10.1021/ic3010085

Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides Erik V. Johnstone, Frederic Poineau, Paul M. Forster, Longzou Ma, Thomas Hartmann, Andrew Cornelius, Daniel Antonio, Alfred P. Sattelberger, and Kenneth R. Czerwinski pp 8462–8467 DOI: 10.1021/ic301011c

Synthesis and Investigation of [B20H17O(CH2)5]3–, a Novel Solvent Complex of the [B20H18]4– Ion Jacqueline P. Smits, Nicholas Mustachio, Brian Newell, and Debra A. Feakes pp 8468–8472 DOI: 10.1021/ic301044m

Al-Induced Crystallization of Amorphous Ge and Formation of Fractal Ge Micro-/Nanoclusters Quanbao Li, Chen Chen, Zhiwen Chen, Zheng Jiao, Minghong Wu, Chan-Hung Shek, C. M. Lawrence Wu, and Joseph K. L. Lai pp 8473–8478 DOI: 10.1021/ic301046z

Carboxylate-Free Manganese(II) Phosphonate Assemblies: Synthesis, Structure, and Magnetism Vadapalli Chandrasekhar, Joydeb Goura, and E. Carolina Sañudo pp 8479–8487 DOI: 10.1021/ic301060j

3d4f Heterobimetallic Dinuclear and Tetranuclear Complexes Involving Tetrathiafulvalene as Ligands: X-ray Structures and Magnetic and Photophysical Investigations Goulven Cosquer, Fabrice Pointillart, Boris Le Guennic, Yann Le Gal, Stéphane Golhen, Olivier Cador, and Lahcène Ouahab pp 8488–8501 DOI: 10.1021/ic3010689

Crystallographic and Magnetic Phase Transitions in the Layered Ruthenium Oxyarsenides TbRuAsO and DyRuAsO Michael A. McGuire, Andrew F. May, and Brian C. Sales pp 8502–8508 DOI: 10.1021/ic3010695

Physical Characterization and Reactivity of the Uranyl Peroxide [UO2(η2-O2)(H2O)2]·2H2O: Implications for Storage of Spent Nuclear Fuels Colm Mallon, Aurora Walshe, Robert J. Forster, Tia E. Keyes, and Robert J. Baker pp 8509–8515 DOI: 10.1021/ic3010823

Formation of Specific Configurations at Stereogenic Nitrogen Centers upon Their Coordination to Zinc and Mercury Prisca K. Eckert, Viktoria H. Gessner, Michael Knorr, and Carsten Strohmann pp 8516–8523 DOI: 10.1021/ic301089h

Anosovite-Type V3O5: A New Binary Oxide of Vanadium D. Weber, C. Wessel, C. Reimann, C. Schwickert, A. Müller, T. Ressler, R. Pöttgen, T. Bredow, R. Dronskowski, and M. Lerch pp 8524–8529 DOI: 10.1021/ic301096d

Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs) Dong Woo Lee, Saet Byeol Kim, and Kang Min Ok pp 8530–8537 DOI: 10.1021/ic301316r

A Six-Coordinate Ytterbium Complex Exhibiting Easy-Plane Anisotropy and Field-Induced Single-Ion Magnet Behavior Jun-Liang Liu, Kang Yuan, Ji-Dong Leng, Liviu Ungur, Wolfgang Wernsdorfer, Fu-Sheng Guo, Liviu F. Chibotaru, and Ming-Liang Tong pp 8538–8544 DOI: 10.1021/ic301115b

Tetrathiafulvalene-Triazine-Dipyridylamines as Multifunctional Ligands for Electroactive Complexes: Synthesis, Structures, and Theoretical Study Diana G. Branzea, Arnaud Fihey, Thomas Cauchy, Abdelkrim El-Ghayoury, and Narcis Avarvari pp 8545–8556 DOI: 10.1021/ic301117h

Bonding Trends Traversing the Tetravalent Actinide Series: Synthesis, Structural, and Computational Analysis of AnIV(Aracnac)4 Complexes (An = Th, U, Np, Pu; Aracnac = ArNC(Ph)CHC(Ph)O; Ar = 3,5-tBu2C6H3) David D. Schnaars, Andrew J. Gaunt, Trevor W. Hayton, Matthew B. Jones, Ian Kirker, Nikolas Kaltsoyannis, Iain May, Sean D. Reilly, Brian L. Scott, and Guang Wu pp 8557–8566 DOI: 10.1021/ic301109f

Protonation and Complexation Properties of Polyaromatic Terdentate Six-Membered Chelate Ligands Thi Nhu Y Hoang, Timothée Lathion, Laure Guénée, Emmanuel Terazzi, and Claude Piguet pp 8567–8575 DOI: 10.1021/ic301126y

Structural Analysis of Isomeric Europium(III) Chelates of NB-DOTMA Benjamin C. Webber and Mark Woods pp 8576–8582 DOI: 10.1021/ic3011597

{Sn9[Si(SiMe3)3]2}2-: A Metalloid Tin Cluster Compound With a Sn9 Core of Oxidation State Zero Claudio Schrenk, Florian Winter, Rainer Pöttgen, and Andreas Schnepf pp 8583–8588 DOI: 10.1021/ic3011647

Ligand-Localized Triplet-State Photophysics in a Platinum(II) Terpyridyl Perylenediimideacetylide Valentina Prusakova, Catherine E. McCusker, and Felix N. Castellano pp 8589–8598 DOI: 10.1021/ic301169t

Unexpected Disproportionation of Tetramethylethylenediamine-Supported Perchlorodisilane Cl3SiSiCl3 Jan Tillmann, Frank Meyer-Wegner, Andor Nadj, Johanna Becker-Baldus, Tanja Sinke, Michael Bolte, Max C. Holthausen, Matthias Wagner, and Hans-Wolfram Lerner pp 8599–8606 DOI: 10.1021/ic301283m

Testing the Concept of Hypervalency: Charge Density Analysis of K2SO4 Mette S. Schmøkel, Simone Cenedese, Jacob Overgaard, Mads R. V. Jørgensen, Yu-Sheng Chen, Carlo Gatti, Dietmar Stalke, and Bo B. Iversen pp 8607–8616 DOI: 10.1021/ic301372m

EPR/ENDOR, Mössbauer, and Quantum-Chemical Investigations of Diiron Complexes Mimicking the Active Oxidized State of [FeFe]Hydrogenase Alexey Silakov, Matthew T. Olsen, Stephen Sproules, Eduard J. Reijerse, Thomas B. Rauchfuss, and Wolfgang Lubitz pp 8617–8628 DOI: 10.1021/ic3013766

Synthesis, Structural Elucidation, and Application of a Pyrazolylpyridine–Molybdenum Oxide Composite as a Heterogeneous Catalyst for Olefin Epoxidation Sónia Figueiredo, Ana C. Gomes, Patrícia Neves, Tatiana R. Amarante, Filipe A. Almeida Paz, Rosário Soares, André D. Lopes, Anabela A. Valente, Martyn Pillinger, and Isabel S. Gonçalves pp 8629–8635 DOI: 10.1021/ic301405r

Correction to Homochiral 1D Helical Chain Based on an Achiral Cu(II) Complex Chihiro Kachi-Terajima, Megumi Ishii, Toshiaki Saito, Chikahide Kanadani, Takunori Harada, and Reiko Kuroda pp 8636–8636 DOI: 10.1021/ic301427a

Issue 16

Self-Assembled Bilayers on Indium–Tin Oxide (SAB-ITO) Electrodes: A Design for Chromophore–Catalyst Photoanodes Christopher R. K. Glasson, Wenjing Song, Dennis L. Ashford, Aaron Vannucci, Zuofeng Chen, Javier J. Concepcion, Patrick L. Holland, and Thomas J. Meyer pp 8637–8639 DOI: 10.1021/ic300636w

Silver(I) Ethynide Coordination Networks and Clusters Assembled with tert-Butylphosphonic Acid Yun-Peng Xie and Thomas C. W. Mak pp 8640–8642 DOI: 10.1021/ic300913u

New Chiral Zinc Complexes: Synthesis, Structure, and Induction of Axial Chirality Helmut Degenbeck, Anne-Sophie Felten, Eduardo C. Escudero-Adán, Jordi Benet-Buchholz, Lorenzo Di Bari, Gennaro Pescitelli, and Anton Vidal-Ferran pp 8643–8645 DOI: 10.1021/ic300915p

Tracing the Sources of the Different Magnetic Behavior in the Two Phases of the Bistable (BDTA)2[Co(mnt)2] Compound Sergi Vela, Mercè Deumal, Jordi Ribas-Arino, and Juan J. Novoa pp 8646–8648 DOI: 10.1021/ic301085t

Solvent-Induced Single-Crystal-to-Single-Crystal Transformation in Multifunctional Chiral Dysprosium(III) Compounds Jian Liu, Xiao-Peng Zhang, Tao Wu, Bin-Bin Ma, Tian-Wei Wang, Cheng-Hui Li, Yi-Zhi Li, and Xiao-Zeng You pp 8649–8651 DOI: 10.1021/ic3012475

Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes Bastian Feldscher, Hubert Theil, Anja Stammler, Hartmut Bögge, and Thorsten Glaser pp 8652–8654 DOI: 10.1021/ic301312v

A Cationic Antimonite Chain Templated by Sulfate: [Sb6O74+][(SO42–)2] Honghan Fei, Cari S. Han, and Scott R. J. Oliver pp 8655–8657 DOI: 10.1021/ic3013409

A Copper(II) Thiolate from Reductive Cleavage of an S-Nitrosothiol Marie M. Melzer, Susanne Mossin, Allan Jay P. Cardenas, Kamille D. Williams, Shiyu Zhang, Karsten Meyer, and Timothy H. Warren pp 8658–8660 DOI: 10.1021/ic301356h

Caging Peroxide: Anion-Templated Synthesis and Characterization of a Rare-Earth Cluster William J. Gee, Jonathan G. MacLellan, Craig M. Forsyth, Boujemaa Moubaraki, Keith S. Murray, Philip C. Andrews, and Peter C. Junk pp 8661–8663 DOI: 10.1021/ic301382r

Novel Chemosensor for the Visual Detection of Copper(II) in Aqueous Solution at the ppm Level Vadapalli Chandrasekhar, Sourav Das, Rajeev Yadav, Sakiat Hossain, Rashmi Parihar, Ganesh Subramaniam, and Pratik Sen pp 8664–8666 DOI: 10.1021/ic301399a

Enantioselective Synthesis of Tetranuclear Quadruple Helicates Claire Deville, Alexandra Spyratou, Paulina Aguirre-Etcheverry, Céline Besnard, and Alan F. Williams pp 8667–8669 DOI: 10.1021/ic3014943

Reactivity of Rhodium(I) Complexes Bearing Nitrogen-Containing Ligands toward CH3I: Synthesis and Full Characterization of Neutral cis-[RhX(CO)2(L)] and Acetyl [RhI(μ-I)(COMe)(CO)(L)]2 Complexes Romain J. Adcock, Duc Hanh Nguyen, Sonia Ladeira, Carole Le Berre, Philippe Serp, and Philippe Kalck pp 8670–8685 DOI: 10.1021/ic2019988

Synthesis and Structural Characterization of NaxSi136 (0 < x ≤ 24) Single Crystals and Low-Temperature Transport of Polycrystalline Specimens Stevce Stefanoski, Christos D. Malliakas, Mercouri G. Kanatzidis, and George S. Nolas pp 8686–8692 DOI: 10.1021/ic202199t

Emissive Osmium(II) Complexes Supported by N-Heterocyclic Carbene-based CCC-Pincer Ligands and Aromatic Diimines Lai-Hon Chung, Siu-Chung Chan, Wing-Chun Lee, and Chun-Yuen Wong pp 8693–8703 DOI: 10.1021/ic202726g

Organometallic Ni Pincer Complexes for the Electrocatalytic Production of Hydrogen Oana R. Luca, James D. Blakemore, Steven J. Konezny, Jeremy M. Praetorius, Timothy J. Schmeier, Glendon B. Hunsinger, Victor S. Batista, Gary W. Brudvig, Nilay Hazari, and Robert H. Crabtree pp 8704–8709 DOI: 10.1021/ic300009a

β-Diketiminate Germylene-Supported Pentafluorophenylcopper(I) and -silver(I) Complexes [LGe(Me)(CuC6F5)n]2 (n = 1, 2), LGe[C(SiMe3)N2]AgC6F5, and {LGe[C(SiMe3)N2](AgC6F5)2}2 (L = HC[C(Me)N-2,6-iPr2C6H3]2): Synthesis and Structural Characterization Na Zhao, Jinyuan Zhang, Ying Yang, Hongping Zhu, Yan Li, and Gang Fu pp 8710–8718 DOI: 10.1021/ic300216m

Phosph(on/in)ate-Bridged Vanadium(IV) Dimers: Synthesis and Characterization Alexander E. Anderson, Michael P. Weberski, Jr., and Craig C. McLauchlan pp 8719–8728 DOI: 10.1021/ic3002306

Synthesis and Characterization of the Crystal Structure and Magnetic Properties of the New Fluorophosphate LiNaCo[PO4]F Hamdi Ben Yahia, Masahiro Shikano, Shinji Koike, Kuniaki Tatsumi, Hironori Kobayashi, Hitoshi Kawaji, Maxim Avdeev, Wojciech Miiller, Chris D. Ling, Jia Liu, and Myung-Hwan Whangbo pp 8729–8738 DOI: 10.1021/ic300374w

Syntheses, Structures, and Steady State and Time Resolved Photophysical Properties of a Tetraiminodiphenol Macrocyclic Ligand and Its Dinuclear Zinc(II)/Cadmium(II) Complexes with Coordinating and Noncoordinating Anions Samit Majumder, Leena Mandal, and Sasankasekhar Mohanta pp 8739–8749 DOI: 10.1021/ic300412u

Radical Pathway in Catecholase Activity with Zinc-Based Model Complexes of Compartmental Ligands Averi Guha, Tanmay Chattopadhyay, Nanda Dulal Paul, Madhuparna Mukherjee, Somen Goswami, Tapan Kumar Mondal, Ennio Zangrando, and Debasis Das pp 8750–8759 DOI: 10.1021/ic300400v

Fluorescent Zinc Sensor with Minimized Proton-Induced Interferences: Photophysical Mechanism for Fluorescence Turn-On Response and Detection of Endogenous Free Zinc Ions Ji Eon Kwon, Sumin Lee, Youngmin You, Kyung-Hwa Baek, Kei Ohkubo, Jaeheung Cho, Shunichi Fukuzumi, Injae Shin, Soo Young Park, and Wonwoo Nam pp 8760–8774 DOI: 10.1021/ic300476e

Tetranuclear d-f Metallostars: Synthesis, Relaxometric, and Luminescent Properties Geert Dehaen, Svetlana V. Eliseeva, Peter Verwilst, Sophie Laurent, Luce Vander Elst, Robert N. Muller, Wim De Borggraeve, Koen Binnemans, and Tatjana N. Parac-Vogt pp 8775–8783 DOI: 10.1021/ic300537y

Experimental and Computational Study of a New Wheel-Shaped {[W5O21]3[(UVIO2)2(μ-O2)]3}30– Polyoxometalate Pere Miró, Jie Ling, Jie Qiu, Peter C. Burns, Laura Gagliardi, and Christopher J. Cramer pp 8784–8790 DOI: 10.1021/ic3005536

Synthesis of CuTCNQ/Au Microrods by Galvanic Replacement of Semiconducting Phase I CuTCNQ with KAuBr4 in Aqueous Medium Andrew Pearson, Anthony P. O’Mullane, Suresh K. Bhargava, and Vipul Bansal pp 8791–8801 DOI: 10.1021/ic300555j

Structure Refinement and Two-Center Luminescence of Ca3La3(BO3)5:Ce3+ under VUV–UV Excitation Chunmeng Liu, Hongbin Liang, Xiaojun Kuang, Jiuping Zhong, Shuaishuai Sun, and Ye Tao pp 8802–8809 DOI: 10.1021/ic3006053

Exploratory Investigation of New SHG Materials Based on Galloborates Ting Hu, Chun-Li Hu, Fang Kong, Jiang-Gao Mao, and Thomas C. W. Mak pp 8810–8817 DOI: 10.1021/ic3006376

Highly Luminescent and Thermally Stable Lanthanide Coordination Polymers Designed from 4-(Dipyridin-2-yl)aminobenzoate: Efficient Energy Transfer from Tb3+ to Eu3+ in a Mixed Lanthanide Coordination Compound A. R. Ramya, Debajit Sharma, Srinivasan Natarajan, and M. L. P. Reddy pp 8818–8826 DOI: 10.1021/ic300654e

X-ray Absorption Study of the Solvation Structure of Cu2+ in Methanol and Dimethyl Sulfoxide Andrea Zitolo, Giovanni Chillemi, and Paola D’Angelo pp 8827–8833 DOI: 10.1021/ic3006647

Marked Difference in the Electronic Structure of Cyanide-Ligated Ferric Protoglobins and Myoglobin Due to Heme Ruffling Sabine Van Doorslaer, Lesley Tilleman, Ben Verrept, Filip Desmet, Sara Maurelli, Florin Trandafir, Luc Moens, and Sylvia Dewilde pp 8834–8841 DOI: 10.1021/ic3007074

Syntheses and Magnetic Properties Study of Isostructural BiM2BP2O10 (M = Co, Ni) Containing a Quasi-1D Linear Chain Structure Wei-Long Zhang, Zhang-Zhen He, Tian-Long Xia, Zhong-Zhen Luo, Hao Zhang, Chen-Sheng Lin, and Wen-Dan Cheng pp 8842–8847 DOI: 10.1021/ic300758t

Hydrolytic Activity of Vanadate toward Serine-Containing Peptides Studied by Kinetic Experiments and DFT Theory Phuong Hien Ho, Tzvetan Mihaylov, Kristine Pierloot, and Tatjana N. Parac-Vogt pp 8848–8859 DOI: 10.1021/ic300761g

Pyrophosphate Complexation of Tin(II) in Aqueous Solutions as Applied in Electrolytes for the Deposition of Tin and Tin Alloys Such as White Bronze Magnus R. Buchner, Florian Kraus, and Hubert Schmidbaur pp 8860–8867 DOI: 10.1021/ic300782q

On the Suppression Mechanism of the Pseudo-Jahn–Teller Effect in Middle E6 (E = P, As, Sb) Rings of Triple-Decker Sandwich Complexes Alexander S. Ivanov, Konstantin V. Bozhenko, and Alexander I. Boldyrev pp 8868–8872 DOI: 10.1021/ic300786w

Syntheses and Characterization of Six Quaternary Uranium Chalcogenides A2M4U6Q17 (A = Rb or Cs; M = Pd or Pt; Q = S or Se) George N. Oh, Eun Sang Choi, Jun Lu, Lukasz A. Koscielski, Matthew D. Ward, Donald E. Ellis, and James A. Ibers pp 8873–8881 DOI: 10.1021/ic300865y

Conventional and Stuffed Bergman-Type Phases in the Na–Au–T (T = Ga, Ge, Sn) Systems: Syntheses, Structures, Coloring of Cluster Centers, and Fermi Sphere–Brillouin Zone Interactions Qisheng Lin, Volodymyr Smetana, Gordon J. Miller, and John D. Corbett pp 8882–8889 DOI: 10.1021/ic300866q

Molecular Oxygen Reduction Electrocatalyzed by meso-Substituted Cobalt Corroles Coated on Edge-Plane Pyrolytic Graphite Electrodes in Acidic Media Zhongping Ou, Aixiang Lü, Deying Meng, Shi Huang, Yuanyuan Fang, Guifen Lu, and Karl M. Kadish pp 8890–8896 DOI: 10.1021/ic300886s

Homoleptic Pnictogen–Chalcogen Coordination Complexes Jonathan W. Dube, Mikko M. Hänninen, Jason L. Dutton, Heikki M. Tuononen, and Paul J. Ragogna pp 8897–8903 DOI: 10.1021/ic300892p

Prospects for Three-Electron Donor Boronyl (BO) Ligands and Dioxodiborene (B2O2) Ligands as Bridging Groups in Binuclear Iron Carbonyl Derivatives Yu Chang, Qian-Shu Li, Yaoming Xie, and R. Bruce King pp 8904–8915 DOI: 10.1021/ic300893e

Heteroleptic Dipyrrinato Complexes Containing 5-Ferrocenyldipyrromethene and Dithiocarbamates as Coligands: Selective Chromogenic and Redox Probes Rakesh Kumar Gupta, Rampal Pandey, Roopshikha Singh, Nitin Srivastava, Biswajit Maiti, Satyen Saha, Peizhou Li, Qiang Xu, and Daya Shankar Pandey pp 8916–8930 DOI: 10.1021/ic300900m

Connecting [NiFe]- and [FeFe]-Hydrogenases: Mixed-Valence Nickel–Iron Dithiolates with Rotated Structures David Schilter, Thomas B. Rauchfuss, and Matthias Stein pp 8931–8941 DOI: 10.1021/ic300910r

Structural Periodicity in the Coordination Chemistry of Aqueous Pu(IV) Sulfates Richard E. Wilson pp 8942–8947 DOI: 10.1021/ic301025f

Synthesis, Crystal Structure, Transport, and Magnetic Properties of Novel Ternary Copper Phosphides, A2Cu6P5 (A = Sr, Eu) and EuCu4P3 Dmitri O. Charkin, Arthur V. Urmanov, Sergey M. Kazakov, Dmitri Batuk, Artem M. Abakumov, Stephan Knöner, Elena Gati, Bernd Wolf, Michael Lang, Andrey V. Shevelkov, Gustaaf Van Tendeloo, and Evgeni V. Antipov pp 8948–8955 DOI: 10.1021/ic301033h

Positive Surface Charge Enhances Selective Cellular Uptake and Anticancer Efficacy of Selenium Nanoparticles Bo Yu, Yibo Zhang, Wenjie Zheng, Cundong Fan, and Tianfeng Chen pp 8956–8963 DOI: 10.1021/ic301050v

Co-complexation of Lithium Gallates on the Titanium Molecular Oxide {[Ti(η5-C5Me5)(μ-O)}3(μ3-CH)] María Gómez-Pantoja, Pilar Gómez-Sal, Alberto Hernán-Gómez, Avelino Martín, Miguel Mena, and Cristina Santamaría pp 8964–8972 DOI: 10.1021/ic301057u

Thermochemistry of Sr2Ce1–xPrxO4 (x = 0, 0.2, 0.5, 0.8, and 1): Variable-Temperature and -Atmosphere in-situ and ex-situ Powder X-ray Diffraction Studies and Their Physical Properties Wang Hay Kan and Venkataraman Thangadurai pp 8973–8981 DOI: 10.1021/ic301071x

Titanium–oxo–Clusters with Dicarboxylates: Single-Crystal Structure and Photochromic Effect Yin-Yin Wu, Wen Luo, Yu-Hong Wang, Ya-Yang Pu, Xiang Zhang, Li-Sheng You, Qin-Yu Zhu, and Jie Dai pp 8982–8988 DOI: 10.1021/ic301092b

Effect of Nonmagnetic Substitution on the Magnetic Properties and Charge-Transfer Phase Transition of an Iron Mixed-Valence Complex, (n-C3H7)4N[FeIIFeIII(dto)3] (dto = C2O2S2) Hiromichi Ida, Atsushi Okazawa, Norimichi Kojima, Ryo Shimizu, Yasuhiro Yamada, and Masaya Enomoto pp 8989–8996 DOI: 10.1021/ic3010954

Redox Routes to Substitution of Aluminum(III): Synthesis and Characterization of (IP–)2AlX (IP = α-iminopyridine, X = Cl, Me, SMe, S2CNMe2, C≡CPh, N3, SPh, NHPh) Thomas W. Myers, Alexandra L. Holmes, and Louise A. Berben pp 8997–9004 DOI: 10.1021/ic301128m

Bifunctional Mixed-Lanthanide Cyano-Bridged Coordination Polymers Ln0.5Ln′0.5(H2O)5[W(CN)8] (Ln/Ln′ = Eu3+/Tb3+, Eu3+/Gd3+, Tb3+/Sm3+) Elena Chelebaeva, Jérôme Long, Joulia Larionova, Rute A. S. Ferreira, Luis D. Carlos, Filipe A. Almeida Paz, José B. R. Gomes, Alexander Trifonov, Christian Guérin, and Yannick Guari pp 9005–9016 DOI: 10.1021/ic301144j

99Tc and Re Incorporated into Metal Oxide Polyoxometalates: Oxidation State Stability Elucidated by Electrochemistry and Theory Donna McGregor, Benjamin P. Burton-Pye, Israel M. Mbomekalle, Pablo A. Aparicio, Susanna Romo, Xavier López, Josep M. Poblet, and Lynn C. Francesconi pp 9017–9028 DOI: 10.1021/ic3011713

Synthesis and X-ray Structures of Novel Macrocycles and Macrobicycles Containing N,N-Di(pyrrolylmethyl)-N-methylamine Moiety: Preliminary Anion Binding Study Rajnish Kumar, Tapas Guchhait, and Ganesan Mani pp 9029–9038 DOI: 10.1021/ic3011822

Tunability of Band Gaps in Metal–Organic Frameworks Chi-Kai Lin, Dan Zhao, Wen-Yang Gao, Zhenzhen Yang, Jingyun Ye, Tao Xu, Qingfeng Ge, Shengqian Ma, and Di-Jia Liu pp 9039–9044 DOI: 10.1021/ic301189m

Energetics and Structure of Uranium(VI)–Acetate Complexes in Dimethyl Sulfoxide Plinio Di Bernardo, Pier Luigi Zanonato, Franco Benetollo, Andrea Melchior, Marilena Tolazzi, and Linfeng Rao pp 9045–9055 DOI: 10.1021/ic301190d

Nine Diiron(II) Complexes of Three Bis-tetradentate Pyrimidine Based Ligands with NCE (E = S, Se, BH3) Coligands Worku A. Gobeze, Victoria A. Milway, Juan Olguín, Guy N. L. Jameson, and Sally Brooker pp 9056–9065 DOI: 10.1021/ic3012052

Making Sense of Boron-Rich Binary Be–B Phases Andreas Hermann, N. W. Ashcroft, and Roald Hoffmann pp 9066–9075 DOI: 10.1021/ic301215y

Naphthalene and Anthracene Cobaltates(1−): Useful Storable Sources of an Atomic Cobalt Anion William W. Brennessel and John E. Ellis pp 9076–9094 DOI: 10.1021/ic301240u

Copolymerization of Cyclohexene Oxide and CO2 with a Chromium Diamine-bis(phenolate) Catalyst Rebecca K. Dean, Louise N. Dawe, and Christopher M. Kozak pp 9095–9103 DOI: 10.1021/ic301402z

Synthesis, Structure, and Paramagnetism of Manganese(II) Iminophosphate Complexes Daniel N. Woodruff, Eric J. L. McInnes, Daniel O. Sells, Richard E. P. Winpenny, and Richard A. Layfield pp 9104–9109 DOI: 10.1021/ic3014046

Heterometallic CoIII4FeIII2 Schiff Base Complex: Structure, Electron Paramagnetic Resonance, and Alkane Oxidation Catalytic Activity Dmytro S. Nesterov, Eduard N. Chygorin, Volodymyr N. Kokozay, Volodymyr V. Bon, Roman Boča, Yuriy N. Kozlov, Lidia S. Shul’pina, Julia Jezierska, Andrew Ozarowski, Armando J. L. Pombeiro, and Georgiy B. Shul’pin pp 9110–9122 DOI: 10.1021/ic301460q

MnIII(tetra-biphenyl-porphyrin)–TCNE Single-Chain Magnet via Suppression of the Interchain Interactions Ryuta Ishikawa, Keiichi Katoh, Brian K. Breedlove, and Masahiro Yamashita pp 9123–9131 DOI: 10.1021/ic3015223

Ring-Opening Polymerization of Epoxides Catalyzed by Uranyl Complexes: An Experimental and Theoretical Study of the Reaction Mechanism Jian Fang, Aurora Walshe, Laurent Maron, and Robert J. Baker pp 9132–9140 DOI: 10.1021/ic3015942

Issue 17

Topological Difference in 2D Layers Steers the Formation of Rigid and Flexible 3D Supramolecular Isomers: Impact on the Adsorption Properties Prakash Kanoo, Ryotaro Matsuda, Ryo Kitaura, Susumu Kitagawa, and Tapas Kumar Maji pp 9141–9143 DOI: 10.1021/ic300695v

Solid-to-Solid Oxidation of a Vanadium(IV) to a Vanadium(V) Compound: Chemisty of a Sulfur-Containing Siderophore Pabitra B. Chatterjee and Debbie C. Crans pp 9144–9146 DOI: 10.1021/ic301026b

Miscibility Gap in the U–Nd–O Phase Diagram: a New Approach of Nuclear Oxides in the Environment? L. Desgranges, Y. Pontillon, P. Matheron, M. Marcet, P. Simon, G. Guimbretière, and F. Porcher pp 9147–9149 DOI: 10.1021/ic301100c

(C8H22N4Zn)2Ge7O14(OH)F3: A One-Dimensional Zinc Germanate Containing Hollow Columns with an 18-Membered Window Quang Bac Nguyen and Kwang-Hwa Lii pp 9150–9152 DOI: 10.1021/ic301216q

A Magnetic Resonance Imaging Contrast Agent Capable of Detecting Hydrogen Peroxide Meng Yu, Ronald J. Beyers, John D. Gorden, Justin N. Cross, and Christian R. Goldsmith pp 9153–9155 DOI: 10.1021/ic3012603

Size-Selective Biocatalysis of Myoglobin Immobilized into a Mesoporous Metal–Organic Framework with Hierarchical Pore Sizes Yao Chen, Vasiliki Lykourinou, Tran Hoang, Li-June Ming, and Shengqian Ma pp 9156–9158 DOI: 10.1021/ic301280n

Nitrate-Bridged “Pseudo-Double-Propeller”-Type Lanthanide(III)–Copper(II) Heterometallic Clusters: Syntheses, Structures, and Magnetic Properties Abhijeet K. Chaudhari, Biplab Joarder, Eric Rivière, Guillaume Rogez, and Sujit K. Ghosh pp 9159–9161 DOI: 10.1021/ic3012876

Nanoscale Hemispheres in Novel Mixed-Valent Uranyl Chromate(V,VI), (C3NH10)10[(UO2)13(Cr125+O42)(Cr6+O4)6(H2O)6](H2O)6 Oleg I. Siidra, Evgeny V. Nazarchuk, Anatoly A. Petrunin, Roman A. Kayukov, and Sergey V. Krivovichev pp 9162–9164 DOI: 10.1021/ic301288r

[N(n-Bu)4]2[Pu(NO3)6] and [N(n-Bu)4]2[PuCl6]: Starting Materials To Facilitate Nonaqueous Plutonium(IV) Chemistry Sean D. Reilly, Brian L. Scott, and Andrew J. Gaunt pp 9165–9167 DOI: 10.1021/ic301518g

Ligand-Based Reduction of CO2 and Release of CO on Iron(II) Zachary Thammavongsy, Takele Seda, Lev N. Zakharov, Werner Kaminsky, and John D. Gilbertson pp 9168–9170 DOI: 10.1021/ic3015404

Synthesis, Reactivity, Electrochemical Behavior, and Crystal Structure of a Family of Multivalent Metal Carbido–Carbonyl Clusters Based on the Rh10(C)2Au4–6 Framework Laura Cherchi, Alessandro Fumagalli, Serena Fedi, Piero Zanello, Fabrizia Fabrizi De Biani, Franco Laschi, Luigi Garlaschelli, Piero Macchi, and Angelo Sironi pp 9171–9180 DOI: 10.1021/ic201613j

Tuning of Water and Hydroxide Content of Intercalated Ruddlesden–Popper-type Oxides in the PrSr3Co1.5Fe1.5O10−δ System Laurent Jantsky, Hiroshi Okamoto, Antoine Demont, and Helmer Fjellvåg pp 9181–9191 DOI: 10.1021/ic300001s

[V16O38(CN)]9–: A Soluble Mixed-Valence Redox-Active Building Block with Strong Antiferromagnetic Coupling Tony D. Keene, Deanna M. D’Alessandro, Karl W. Krämer, Jason R. Price, David J. Price, Silvio Decurtins, and Cameron J. Kepert pp 9192–9199 DOI: 10.1021/ic3001834

Enhanced Hydrostability in Ni-Doped MOF-5 Huanhuan Li, Wei Shi, Kaina Zhao, Han Li, Yanmin Bing, and Peng Cheng pp 9200–9207 DOI: 10.1021/ic3002898

Direct Synthesis of High-Quality Water-Soluble CdTe:Zn2+ Quantum Dots Qisui Wang, Tingting Fang, Peng Liu, Bohua Deng, Xinmin Min, and Xi Li pp 9208–9213 DOI: 10.1021/ic300473u

Structure, Bonding, and Catecholase Mechanism of Copper Bispidine Complexes Peter Comba, Bodo Martin, Amsaveni Muruganantham, and Johannes Straub pp 9214–9225 DOI: 10.1021/ic3004917

A Highly Selective Fluorescent Sensor for Distinguishing Cadmium from Zinc Ions Based on a Quinoline Platform Xiaoyan Zhou, Pengxuan Li, Zhaohua Shi, Xiaoliang Tang, Chunyang Chen, and Weisheng Liu pp 9226–9231 DOI: 10.1021/ic300661c

pH- and Dopant-Dependent CdMoO4:Mn Nanocrystals: Luminescence and Magnetic Properties Qilin Dai, Gongguo Zhang, Pan Liu, Jing Wang, and Jinke Tang pp 9232–9239 DOI: 10.1021/ic3006663

Aminotroponiminatogermaacid Halides with a Ge(E)X Moiety (E = S, Se; X = F, Cl) Soumen Sinhababu, Rahul Kumar Siwatch, Goutam Mukherjee, Gopalan Rajaraman, and Selvarajan Nagendran pp 9240–9248 DOI: 10.1021/ic300715y

Mixed Bis(μ-silylene) and (μ-Silylene)/(μ-Germylene) Complexes Involving the Rh/Ir Metal Combination: Nature of the Si···Si Interactions in the Bis(μ-silylene) Species Md Hosnay Mobarok, Robert McDonald, Michael J. Ferguson, and Martin Cowie pp 9249–9258 DOI: 10.1021/ic300720y

LaCo1–xNixO3 with Improved Electrical Conductivity Hisashi Kozuka, Kazushige Ohbayashi, and Kunihito Koumoto pp 9259–9264 DOI: 10.1021/ic301386s

Constructing Sandwich-Type Rare Earth Double-Decker Complexes with N-Confused Porphyrinato and Phthalocyaninato Ligands Wei Cao, Hailong Wang, Xin Wang, Hung Kay Lee, Dennis K. P. Ng, and Jianzhuang Jiang pp 9265–9272 DOI: 10.1021/ic300789j

Charged, but Found “Not Guilty”: Innocence of the Suspect Bridging Ligands [RO(O)CNNC(O)OR]2– = L2– in [(acac)2Ru(μ-L)Ru(acac)2]n, n = +,0,–,2– Sayak Roy, Biprajit Sarkar, Hans-Georg Imrich, Jan Fiedler, Stanislav Záliš, Reyes Jimenez-Aparicio, Francisco A. Urbanos, Shaikh M. Mobin, Goutam Kumar Lahiri, and Wolfgang Kaim pp 9273–9281 DOI: 10.1021/ic300809w

pH-Specific Hydrothermal Assembly of Binary and Ternary Pb(II)-(O,N-Carboxylic Acid) Metal Organic Framework Compounds: Correlation of Aqueous Solution Speciation with Variable Dimensionality Solid-State Lattice Architecture and Spectroscopic Signatures C. Gabriel, M. Perikli, C. P. Raptopoulou, A. Terzis, V. Psycharis, C. Mateescu, T. Jakusch, T. Kiss, M. Bertmer, and A. Salifoglou pp 9282–9296 DOI: 10.1021/ic300850g

Copper(I) Nitro Complex with an Anionic [HB(3,5-Me2Pz)3]− Ligand: A Synthetic Model for the Copper Nitrite Reductase Active Site Sodio C. N. Hsu, Yu-Lun Chang, Wan-Jung Chuang, Hsing-Yin Chen, I-Jung Lin, Michael Y. Chiang, Chai-Lin Kao, and Hsuan-Ying Chen pp 9297–9308 DOI: 10.1021/ic300932a

l- and d-Proline Thiosemicarbazone Conjugates: Coordination Behavior in Solution and the Effect of Copper(II) Coordination on Their Antiproliferative Activity Miljan N. M. Milunovic, Éva A. Enyedy, Nóra V. Nagy, Tamás Kiss, Robert Trondl, Michael A. Jakupec, Bernhard K. Keppler, Regina Krachler, Ghenadie Novitchi, and Vladimir B. Arion pp 9309–9321 DOI: 10.1021/ic300967j

Synthesis, Characterization, and Activity of Yttrium(III) Nitrate Complexes Bearing Tripodal Phosphine Oxide and Mixed Phosphine–Phosphine Oxide Ligands Peter E. Sues, Alan J. Lough, and Robert H. Morris pp 9322–9332 DOI: 10.1021/ic3010147

Compressed Cesium Polyhydrides: Cs+ Sublattices and H3– Three-Connected Nets Andrew Shamp, James Hooper, and Eva Zurek pp 9333–9342 DOI: 10.1021/ic301045v

Dependence of the Photophysical Properties on the Number of 2,2′-Bipyridine Units in a Series of Luminescent Europium and Terbium Cryptates Nicola Alzakhem, Caroline Bischof, and Michael Seitz pp 9343–9349 DOI: 10.1021/ic3010568

Characterization of Cobalt(III) Hydroxamic Acid Complexes Based on a Tris(2-pyridylmethyl)amine Scaffold: Reactivity toward Cysteine Methyl Ester Mickael Alimi, Anas Allam, Mohamed Selkti, Alain Tomas, Pascal Roussel, Erwan Galardon, and Isabelle Artaud pp 9350–9356 DOI: 10.1021/ic301090t

Cyanide-Bridged FeIII–CuII Complexes: Jahn–Teller Isomerism and Its Influence on the Magnetic Properties Mihail Atanasov, Peter Comba, and Stefan Helmle pp 9357–9368 DOI: 10.1021/ic301122h

In Situ Study of the Solid-State Formation of U1–xAmxO2±δ Solid Solution Florent Lebreton, Renaud C. Belin, Damien Prieur, Thibaud Delahaye, and Philippe Blanchart pp 9369–9375 DOI: 10.1021/ic301124d

Hydrolysis Studies on Bismuth Nitrate: Synthesis and Crystallization of Four Novel Polynuclear Basic Bismuth Nitrates L. Miersch, T. Rüffer, M. Schlesinger, H. Lang, and M. Mehring pp 9376–9384 DOI: 10.1021/ic301148p

Crucial Role of Paramagnetic Ligands for Magnetostructural Anomalies in “Breathing Crystals” Evgeny V. Tretyakov, Svyatoslav E. Tolstikov, Anastasiya O. Suvorova, Aleksey V. Polushkin, Galina V. Romanenko, Artem S. Bogomyakov, Sergey L. Veber, Matvey V. Fedin, Dmitry V. Stass, Edward Reijerse, Wolfgang Lubitz, Ekaterina M. Zueva, and Victor I. Ovcharenko pp 9385–9394 DOI: 10.1021/ic301149e

Two Homologous Intermetallic Phases in the Na–Au–Zn System with Sodium Bound in Unusual Paired Sites within 1D Tunnels Saroj L. Samal, Qisheng Lin, and John D. Corbett pp 9395–9402 DOI: 10.1021/ic301196z

Group 14 Metal Terminal Phosphides: Correlating Structure with |JMP| Eric C. Y. Tam, Nicola A. Maynard, David C. Apperley, J. David Smith, Martyn P. Coles, and J. Robin Fulton pp 9403–9415 DOI: 10.1021/ic301208d

Variable Nitric Oxide Reactivity of Tropocoronand Cobalt(III) Nitrite Complexes as a Function of the Polymethylene Linker Chain Length Julia Kozhukh and Stephen J. Lippard pp 9416–9422 DOI: 10.1021/ic3012266

Chemical/Physical Pressure Tunable Spin-Transition Temperature and Hysteresis in a Two-Step Spin Crossover Porous Coordination Framework Jian-Bin Lin, Wei Xue, Bao-Ying Wang, Jun Tao, Wei-Xiong Zhang, Jie-Peng Zhang, and Xiao-Ming Chen pp 9423–9430 DOI: 10.1021/ic301237p

MnII Coordination Polymers Based on Bi-, Tri-, and Tetranuclear and Polymeric Chain Building Units: Crystal Structures and Magnetic Properties Lu-Fang Ma, Min-Le Han, Jian-Hua Qin, Li-Ya Wang, and Miao Du pp 9431–9442 DOI: 10.1021/ic3012537

Synthesis and Physicochemical Properties of Metallobacteriochlorins Chih-Yuan Chen, Erjun Sun, Dazhong Fan, Masahiko Taniguchi, Brian E. McDowell, Eunkyung Yang, James R. Diers, David F. Bocian, Dewey Holten, and Jonathan S. Lindsey pp 9443–9464 DOI: 10.1021/ic301262k

Active Site Models for the CuA Site of Peptidylglycine α-Hydroxylating Monooxygenase and Dopamine β-Monooxygenase Atsushi Kunishita, Mehmed Z. Ertem, Yuri Okubo, Tetsuro Tano, Hideki Sugimoto, Kei Ohkubo, Nobutaka Fujieda, Shunichi Fukuzumi, Christopher J. Cramer, and Shinobu Itoh pp 9465–9480 DOI: 10.1021/ic301272h

Uranium(IV) Sulfates: Investigating Structural Periodicity in the Tetravalent Actinides David D. Schnaars and Richard E. Wilson pp 9481–9490 DOI: 10.1021/ic301291w

Synthesis and Structural Characterization of Heterometallic Thorium Aluminum Polynuclear Molecular Clusters Melissa Fairley, Daniel K. Unruh, Samangi Abeysinghe, and Tori Z. Forbes pp 9491–9498 DOI: 10.1021/ic3013014

O2 Insertion into Group 9 Metal–Hydride Bonds: Evidence for Oxygen Activation through the Hydrogen-Atom-Abstraction Mechanism Jason M. Keith, Thomas S. Teets, and Daniel G. Nocera pp 9499–9507 DOI: 10.1021/ic301303n

Zn2+ Responsive Bimodal Magnetic Resonance Imaging and Fluorescent Imaging Probe Based on a Gadolinium(III) Complex Jian Luo, Wei-Sheng Li, Peng Xu, Li-Yi Zhang, and Zhong-Ning Chen pp 9508–9516 DOI: 10.1021/ic301308z

Ternary Arsenides A2Zn5As4 (A = K, Rb): Zintl Phases Built from Stellae Quadrangulae Stanislav S. Stoyko, Mansura Khatun, and Arthur Mar pp 9517–9521 DOI: 10.1021/ic301311m

Reactions of an Osmium-Hexahydride Complex with Cytosine, Deoxycytidine, and Cytidine: The Importance of the Minor Tautomers Miguel A. Esteruelas, Jorge García-Raboso, and Montserrat Oliván pp 9522–9528 DOI: 10.1021/ic3013238

Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+) Sau Doan Nguyen and P. Shiv Halasyamani pp 9529–9538 DOI: 10.1021/ic301334c

Anion-Exchange-Driven Disassembly of a SiO2/CTAB Composite Mesophase: the Formation of Hollow Mesoporous Silica Spheres Qiyu Yu, Junfeng Hui, Pengpeng Wang, and Xun Wang pp 9539–9543 DOI: 10.1021/ic301371q

Enhanced Anode Performances of Polyaniline–TiO2–Reduced Graphene Oxide Nanocomposites for Lithium Ion Batteries Fan Zhang, Huaqiang Cao, Dongmei Yue, Jingxian Zhang, and Meizhen Qu pp 9544–9551 DOI: 10.1021/ic301378j

Influence of Postgrowth Li-Poor Vapor-Transport Equilibration on the Surface Li2O Content of a Congruent LiNbO3 Crystal De-Long Zhang, Bei Chen, Ping-Rang Hua, and Edwin Yue-Bun Pun pp 9552–9556 DOI: 10.1021/ic301414s

Inorganic Polar Blocks into Controlled Acentric Assemblies D. Endara, M. Colmont, M. Huvé, F. Capet, J. Lejay, P. Aschehoug, and O. Mentré pp 9557–9562 DOI: 10.1021/ic3014305

Probing the Presence of Multiple Metal–Metal Bonds in Technetium Chlorides by X-ray Absorption Spectroscopy: Implications for Synthetic Chemistry Frederic Poineau, Erik V. Johnstone, Paul M. Forster, Longzou Ma, Alfred P. Sattelberger, and Kenneth R. Czerwinski pp 9563–9570 DOI: 10.1021/ic3014859

Issue 18

Fe20 Cluster Units Based Coordination Polymer from in Situ Ligand Conversion and Trapping of an Intermediate Yong-Fei Zeng, Xin Hu, Li Xue, Sui-Jun Liu, Tong-Liang Hu, and Xian-He Bu pp 9571–9573 DOI: 10.1021/ic300963z

An Inclusion Complex of Hexamolybdate inside a Supramolecular Cage and Its Structural Conversion Muxin Han, Jakob Hey, Wataru Kawamura, Dietmar Stalke, Mitsuhiko Shionoya, and Guido H. Clever pp 9574–9576 DOI: 10.1021/ic301359n

Spontaneous Resolution of a Mixed-Ligand Nickel(II) Coordination Polymer with Achiral Precursors Kamal Kumar Bisht and Eringathodi Suresh pp 9577–9579 DOI: 10.1021/ic301636z

Construction of Heterometallic Clusters in a Small Peptide Scaffold as [NiFe]-Hydrogenase Models: Development of a Synthetic Methodology Arnab Dutta, G. Alexander Hamilton, Hilairy Ellen Hartnett, and Anne Katherine Jones pp 9580–9588 DOI: 10.1021/ic2026818

From a Dy(III) Single Molecule Magnet (SMM) to a Ferromagnetic [Mn(II)Dy(III)Mn(II)] Trinuclear Complex Asamanjoy Bhunia, Michael T. Gamer, Liviu Ungur, Liviu F. Chibotaru, Annie K. Powell, Yanhua Lan, Peter W. Roesky, Fabian Menges, Christoph Riehn, and Gereon Niedner-Schatteburg pp 9589–9597 DOI: 10.1021/ic300065x

A Coordination Chemistry Study of Hydrated and Solvated Cationic Vanadium Ions in Oxidation States +III, +IV, and +V in Solution and Solid State Joanna Krakowiak, Daniel Lundberg, and Ingmar Persson pp 9598–9609 DOI: 10.1021/ic300202f

Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers Ionut Mihalcea, Christophe Volkringer, Natacha Henry, and Thierry Loiseau pp 9610–9618 DOI: 10.1021/ic3005757

Unraveling the Mechanisms of Carboxyl Ester Bond Hydrolysis Catalyzed by a Vanadate Anion Tzvetan Mihaylov, Tatjana Parac-Vogt, and Kristine Pierloot pp 9619–9628 DOI: 10.1021/ic300620b

Encapsulation and Sensitization of UV–vis and Near Infrared Lanthanide Hydrate Emitters for Dual- and Bimodal-Emissions in Both Air and Aqueous Media Based on a Porous Heteroatom-Rich Cd(II)-Framework Yan-An Li, Shu-Kui Ren, Qi-Kui Liu, Jian-Ping Ma, Xueyuan Chen, Haomiao Zhu, and Yu-Bin Dong pp 9629–9635 DOI: 10.1021/ic300665a

A Study on the Luminescence and Energy Transfer of Single-Phase and Color-Tunable KCaY(PO4)2:Eu2+,Mn2+ Phosphor for Application in White-Light LEDs Wei-Ren Liu, Chien-Hao Huang, Chiao-Wen Yeh, Jen-Ching Tsai, Yi-Chen Chiu, Yao-Tsung Yeh, and Ru-Shi Liu pp 9636–9641 DOI: 10.1021/ic3007102

Ratiometric and Selective Fluorescent Sensor for Zn2+ as an “Off–On–Off” Switch and Logic Gate Ya-Ping Li, Hua-Rong Yang, Qiang Zhao, Wei-Chao Song, Jie Han, and Xian-He Bu pp 9642–9648 DOI: 10.1021/ic300738e

Tuning MOF Stability and Porosity via Adding Rigid Pillars Yan-Xi Tan, Yan-Ping He, and Jian Zhang pp 9649–9654 DOI: 10.1021/ic300778m

Extended Network Thiocyanate- and Tetracyanoethanide-Based First-Row Transition Metal Complexes Endrit Shurdha, Saul H. Lapidus, Peter W. Stephens, Curtis E. Moore, Arnold L. Rheingold, and Joel S. Miller pp 9655–9665 DOI: 10.1021/ic300804y

Building-up Remarkably Stable Magnesium Porphyrin Polymers Self-Assembled via Bidentate Axial Ligands: Synthesis, Structure, Surface Morphology, and Effect of Bridging Ligands Sk Asif Ikbal, Sanfaori Brahma, and Sankar Prasad Rath pp 9666–9676 DOI: 10.1021/ic300826p

Tuning Structural Topologies of Three Photoluminescent Metal–Organic Frameworks via Isomeric Biphenyldicarboxylates Feng Guo, Fei Wang, Hui Yang, Xiuling Zhang, and Jian Zhang pp 9677–9682 DOI: 10.1021/ic3008969

Mild, Reversible Reaction of Iridium(III) Amido Complexes with Carbon Dioxide Graham E. Dobereiner, Jianguo Wu, Michael G. Manas, Nathan D. Schley, Michael K. Takase, Robert H. Crabtree, Nilay Hazari, Feliu Maseras, and Ainara Nova pp 9683–9693 DOI: 10.1021/ic300923c

Dependence of the Reduction Products of Platinum(IV) Prodrugs upon the Configuration of the Substrate, Bulk of the Carrier Ligands, and Nature of the Reducing Agent MarilĂą Sinisi, Francesco P. Intini, and Giovanni Natile pp 9694–9704 DOI: 10.1021/ic300957v

Metal-Mediated Controllable Creation of Secondary, Tertiary, and Quaternary Carbon Centers: A Powerful Strategy for the Synthesis of Iron, Cobalt, and Copper Complexes with in Situ Generated Substituted 1-Pyridineimidazo[1,5-a]pyridine Ligands Yanmei Chen, Lei Li, Zhou Chen, Yonglu Liu, Hailiang Hu, Wenqian Chen, Wei Liu, Yahong Li, Tao Lei, Yanyuan Cao, Zhenghui Kang, Miaoshui Lin, and Wu Li pp 9705–9713 DOI: 10.1021/ic300949y

Thermal and Light-Induced Spin Switching Dynamics in the 2D Coordination Network of {[Zn1-xFex(bbtr)3](ClO4)2}∞: The Role of Cooperative Effects Pradip Chakraborty, Cristian Enachescu, Christophe Walder, Robert Bronisz, and Andreas Hauser pp 9714–9722 DOI: 10.1021/ic301006c

Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units J. Palmer West, Dino Sulejmanovic, Shiou-Jyh Hwu, Jian He, Don VanDerveer, and B. Keith Johnson pp 9723–9729 DOI: 10.1021/ic3010129

Bimetallic Ruthenium PNP Pincer Complex As a Platform to Model Proposed Intermediates in Dinitrogen Reduction to Ammonia Sergio S. Rozenel and John Arnold pp 9730–9739 DOI: 10.1021/ic3010322

Reductive Deprotonation and Dehydrogenation of Phenylhydrazine at a Nickel Center To Give a Nickel Diazenido Complex Claudia Köthe, Ramona Metzinger, Christian Herwig, and Christian Limberg pp 9740–9747 DOI: 10.1021/ic301066x

Assignment of Metal–Ligand Modes in Pt(II) Diimine Complexes Relevant to Solar Energy Conversion Stewart F. Parker, Keith Refson, Robert D. Bennett, Jonathan Best, Mikhail Ya. Mel’nikov, and Julia A. Weinstein pp 9748–9756 DOI: 10.1021/ic3011184

Lithium Dihydroborate: First-Principles Structure Prediction of LiBH2 Riccarda Caputo and Adem Tekin pp 9757–9765 DOI: 10.1021/ic301127q

Tuning the Functionality of a Carbon Nanofiber–Pt–RuO2 System from Charge Storage to Electrocatalysis Beena K. Balan and Sreekumar Kurungot pp 9766–9774 DOI: 10.1021/ic301147s

Antibacterial Action of 4,4′-Bipyrazolyl-Based Silver(I) Coordination Polymers Embedded in PE Disks Aurel Tăbăcaru, Claudio Pettinari, Fabio Marchetti, Corrado di Nicola, Konstantin V. Domasevitch, Simona Galli, Norberto Masciocchi, Stefania Scuri, Iolanda Grappasonni, and Mario Cocchioni pp 9775–9788 DOI: 10.1021/ic3011635

Structural Modulation and Phase Transitions in La2CoO4.14 Investigated by Synchrotron X-ray and Neutron Single-Crystal Diffraction LoĂŻc Le DrĂ©au, Carmelo Prestipino, Olivier Hernandez, JĂĽrg Schefer, Gavin Vaughan, Serge Paofai, Juan Manuel Perez-Mato, Shoichi Hosoya, and Werner Paulus pp 9789–9798 DOI: 10.1021/ic301165a

Platinum(II) Complexes of Cyclic Triphosphenium Ions: a 31P NMR Spectroscopic and Computational Study Philippa K. Coffer (nĂ©e Monks), Robert M. K. Deng, Keith B. Dillon, Mark A. Fox, and Richard J. Olivey pp 9799–9808 DOI: 10.1021/ic3011663

A Unique Discrete Tetranuclear Cu′–Cu(N-N)2Cu–Cu′ Copper(II) Complex, Built from a ÎĽ3-1,2,4-Triazolato-ÎĽ-carboxylato Ligand, as an Effective DNA Cleavage Agent Javier Hernández-Gil, Sacramento Ferrer, Alfonso Castiñeiras, and Francesc Lloret pp 9809–9819 DOI: 10.1021/ic301168k

Synthesis of Functionalized Materials Using Aryloxo-Organometallic Compounds toward Spinel-like MM′2O4 (M = Ba2+, Sr2+; M′ = In3+, Al3+) Double Oxides Łukasz John, Magdalena KosiĹ„ska-Klähn, Lucjan B. Jerzykiewicz, Leszek KÄ™piĹ„ski, and Piotr Sobota pp 9820–9832 DOI: 10.1021/ic301218v

Reactivity of Compound II: Electronic Structure Analysis of Methane Hydroxylation by Oxoiron(IV) Porphyrin Complexes Angela Rosa and Giampaolo Ricciardi pp 9833–9845 DOI: 10.1021/ic301232r

Carbonyl Diazide, OC(N3)2: Synthesis, Purification, and IR Spectrum Alex M. Nolan, Brent K. Amberger, Brian J. Esselman, Venkatesan S. Thimmakondu, John F. Stanton, R. Claude Woods, and Robert J. McMahon pp 9846–9851 DOI: 10.1021/ic301270b

Acetate-Bridged Platinum(III) Complexes Derived from Cisplatin Justin J. Wilson and Stephen J. Lippard pp 9852–9864 DOI: 10.1021/ic301289j

Increase in the Coordination Number of a Cobalt Porphyrin after Photo-Induced Interfacial Electron Transfer into Nanocrystalline TiO2 Darren Achey, Shane Ardo, and Gerald J. Meyer pp 9865–9872 DOI: 10.1021/ic301300h

Synthesis and Biological Activity of Ester- and Amide-Functionalized Imidazolium Salts and Related Water-Soluble Coinage Metal N-Heterocyclic Carbene Complexes Maura Pellei, Valentina Gandin, Marika Marinelli, Cristina Marzano, Muhammed Yousufuddin, H. V. Rasika Dias, and Carlo Santini pp 9873–9882 DOI: 10.1021/ic3013188

Formation, Spectroscopic Characterization, and Solution Stability of an [Fe4S4]2+ Cluster Derived from β-Cyclodextrin Dithiolate Wayne Lo, Ping Zhang, Chang-Chun Ling, Shaw Huang, and R. H. Holm pp 9883–9892 DOI: 10.1021/ic301324u

Structural Impact of Platinum on the Incommensurably Modulated Îł-Brass Related Composite Structure Pd15Zn54 Partha P. Jana and Sven Lidin pp 9893–9901 DOI: 10.1021/ic301326p

Peptide Bond Hydrolysis Catalyzed by the Wells–Dawson Zr(α2-P2W17O61)2 Polyoxometalate Gregory Absillis and Tatjana N. Parac-Vogt pp 9902–9910 DOI: 10.1021/ic301364n

Undecaphenylcorroles Steffen Berg, Kolle E. Thomas, Christine M. Beavers, and Abhik Ghosh pp 9911–9916 DOI: 10.1021/ic301388e

Construction of (CuX)2n Cluster-Containing (X = Br, I; n = 1, 2) Coordination Polymers Assembled by Dithioethers ArS(CH2)mSAr (Ar = Ph, p-Tol; m = 3, 5): Effect of the Spacer Length, Aryl Group, and Metal-to-Ligand Ratio on the Dimensionality, Cluster Nuclearity, and the Luminescence Properties of the Metal–Organic Frameworks Michael Knorr, Fabrice Guyon, Abderrahim Khatyr, Carsten Strohmann, Magali Allain, Shawkat M. Aly, Antony Lapprand, Daniel Fortin, and Pierre D. Harvey pp 9917–9934 DOI: 10.1021/ic301385u

Acid-Induced Opening of [closo-B10H10]2– as a New Route to 6-Substituted nido-B10H13 Decaboranes and Related Carboranes Oleg Bondarev, Yulia V. Sevryugina, Satish S. Jalisatgi, and M. Frederick Hawthorne pp 9935–9942 DOI: 10.1021/ic3014267

Crystal Structure and Computational Investigation of an Analogue of Grubbs’ Second Generation Catalyst with a Fluorous Phosphine Robert Tuba, Edward N. Brothers, Joseph H. Reibenspies, Hassan S. Bazzi, and John A. Gladysz pp 9943–9949 DOI: 10.1021/ic301434g

A Zeolite-Like Zinc Triazolate Framework with High Gas Adsorption and Separation Performance Rui-Biao Lin, Da Chen, Yan-Yong Lin, Jie-Peng Zhang, and Xiao-Ming Chen pp 9950–9955 DOI: 10.1021/ic301463z

Molybdenum(VI) Dioxo Complexes Employing Schiff Base Ligands with an Intramolecular Donor for Highly Selective Olefin Epoxidation Martina E. Judmaier, Christof Holzer, Manuel Volpe, and Nadia C. Mösch-Zanetti pp 9956–9966 DOI: 10.1021/ic301464w

Controlling the Electronic States and Physical Properties of MMX-Type Diplatinum-Iodide Chain Complexes via Binary Countercations Hiroaki Iguchi, Shinya Takaishi, Brian K. Breedlove, Masahiro Yamashita, Hiroyuki Matsuzaki, and Hiroshi Okamoto pp 9967–9977 DOI: 10.1021/ic301469u

Pressure-Induced Transition from an Antiferromagnet to a Ferrimagnet for MnII(TCNE)[C4(CN)8]1/2 (TCNE = Tetracyanoethylene) Amber C. McConnell, Joshua D. Bell, and Joel S. Miller pp 9978–9982 DOI: 10.1021/ic3014865

Slow Magnetic Relaxations in Manganese(III) Tetra(meta-fluorophenyl)porphyrin-tetracyanoethenide. Comparison with the Relative Single Chain Magnet ortho Compound Z. Tomkowicz, M. Rams, M. BaĹ‚anda, S. Foro, H. Nojiri, Y. Krupskaya, V. Kataev, B. BĂĽchner, S. K. Nayak, J. V. Yakhmi, and W. Haase pp 9983–9994 DOI: 10.1021/ic3014927

Cd2+ Complexation with P(CH2OH)3, OP(CH2OH)3, and (HOCH2)2PO2–: Coordination in Solution and Coordination Polymers Alexander V. Anyushin, Dmitry A. Mainichev, Nikolay K. Moroz, Pavel A. Abramov, Dmitry Yu. Naumov, Maxim N. Sokolov, and Vladimir P. Fedin pp 9995–10003 DOI: 10.1021/ic3014283

Proline as Chiral Auxiliary for the Economical Asymmetric Synthesis of Ruthenium(II) Polypyridyl Complexes Chen Fu, Marianne Wenzel, Elisabeth Treutlein, Klaus Harms, and Eric Meggers pp 10004–10011 DOI: 10.1021/ic3015157

Allosteric Effects in Binuclear Homo- and Heterometallic Triple-Stranded Lanthanide Podates Patrick E. Ryan, Gabriel Canard, Sylvain Koeller, Bernard Bocquet, and Claude Piguet pp 10012–10024 DOI: 10.1021/ic301631n

Mechanistic Borderline of One-Step Hydrogen Atom Transfer versus Stepwise Sc3+-Coupled Electron Transfer from Benzyl Alcohol Derivatives to a Non-Heme Iron(IV)-Oxo Complex Yuma Morimoto, Jiyun Park, Tomoyoshi Suenobu, Yong-Min Lee, Wonwoo Nam, and Shunichi Fukuzumi pp 10025–10036 DOI: 10.1021/ic3016723

Well-Defined Vanadium Organoazide Complexes and Their Conversion to Terminal Vanadium Imides: Structural Snapshots and Evidence for a Nitrene Capture Mechanism W. Hill Harman, Michael F. Lichterman, Nicholas A. Piro, and Christopher J. Chang pp 10037–10042 DOI: 10.1021/ic301673g

Mononuclear Five- and Six-Coordinate Iron Hydrazido and Hydrazine Species Caroline T. Saouma, Connie C. Lu, and Jonas C. Peters pp 10043–10054 DOI: 10.1021/ic301704f

Controlling the Chiral Inversion Reaction of the Metallopeptide Ni-Asparagine-Cysteine-Cysteine with Dioxygen Amanda M. Glass, Mary E. Krause, Jennifer S. Laurence, and Timothy A. Jackson pp 10055–10063 DOI: 10.1021/ic301717q

Issue 19

Kinetic Inertness of the Mn2+ Complexes Formed with AAZTA and Some Open-Chain EDTA Derivatives Ferenc K. Kálmán and Gyula Tircsó pp 10065–10067 DOI: 10.1021/ic300832e

Synthesis of a FeIISH Complex Stabilized by an Intramolecular N–H···S Hydrogen Bond, Which Acts as a H2S Donor Erwan Galardon, Thomas Roger, Patrick Deschamps, Pascal Roussel, Alain Tomas, and Isabelle Artaud pp 10068–10070 DOI: 10.1021/ic300952d

Homochiral Helical Metal–Organic Frameworks of Potassium Daniel L. Reger, Andrew P. Leitner, and Mark D. Smith pp 10071–10073 DOI: 10.1021/ic301228j

Peripheral Stepwise Degradation of a Porphyrin J-Aggregate Ilaria Occhiuto, Giovanna De Luca, Mariachiara Trapani, Luigi Monsù Scolaro, and Robert F. Pasternack pp 10074–10076 DOI: 10.1021/ic301570p

Pyro without Fire: Synthesis, Structure, and Reactivity of a Dimeric Vanadyl Pyrophosphate Coordination Complex Nadia Marino, Susan K. Hanson, Peter Müller, and Robert P. Doyle pp 10077–10079 DOI: 10.1021/ic3015767

1H-ENDOR Evidence for a Hydrogen-Bonding Interaction That Modulates the Reactivity of a Nonheme FeIV═O Unit Muralidharan Shanmugam, Genqiang Xue, Lawrence Que, Jr., and Brian M. Hoffman pp 10080–10082 DOI: 10.1021/ic3015783

Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks Jian Lin, Juan Diwu, Justin N. Cross, Eric M. Villa, and Thomas E. Albrecht-Schmitt pp 10083–10085 DOI: 10.1021/ic301628q

Acid-Dependent Degradation of a [2Fe–2S] Cluster by Nitric Oxide Camly T. Tran and Eunsuk Kim pp 10086–10088 DOI: 10.1021/ic301676f

Luminescent Microporous Metal–Organic Framework with Functional Lewis Basic Sites on the Pore Surface: Specific Sensing and Removal of Metal Ions Kolleboyina Jayaramulu, Raghu Pradeep Narayanan, Subi J. George, and Tapas Kumar Maji pp 10089–10091 DOI: 10.1021/ic3017547

A Dinitrosyliron Complex within the Homoleptic Fe(NO)4 Anion: NO as Nitroxyl and Nitrosyl Ligands within a Single Structure Zong-Sian Lin, Tzung-Wen Chiou, Kuan-Yu Liu, Chang-Chih Hsieh, Jen-Shiang K. Yu, and Wen-Feng Liaw pp 10092–10094 DOI: 10.1021/ic3018437

Synthesis, Structure, and Magnetic Studies of Manganese–Oxygen Clusters of Reduced Coordination Number, Featuring an Unchelated, 5-Coordinate Octanuclear Manganese Cluster with Water-Derived Oxo Ligands Sandeep K. Kondaveeti, Shivaiah Vaddypally, Carol Lam, Daigorou Hirai, Ni Ni, Robert J. Cava, and Michael J. Zdilla pp 10095–10104 DOI: 10.1021/ic202448c

Application of the Hubbard Model to Cp*2Yb(bipy), a Model System for Strong Exchange Coupling in Lanthanide Systems Wayne W. Lukens, Nicola Magnani, and Corwin H. Booth pp 10105–10110 DOI: 10.1021/ic300037q

Insertion of a Hydroxido Bridge into a Diphenoxido Dinuclear Copper(II) Complex: Drastic Change of the Magnetic Property from Strong Antiferromagnetic to Ferromagnetic and Enhancement in the Catecholase Activity Apurba Biswas, Lakshmi Kanta Das, Michael G. B. Drew, Carmen Diaz, and Ashutosh Ghosh pp 10111–10121 DOI: 10.1021/ic300319s

Complexes of 2,5-Bis(α-pyridyl)pyrrolate with Pd(II) and Pt(II): A Monoanionic Iso-π-Electron Ligand Analog of Terpyridine Gregory H. Imler, Zhi Lu, Kurt A. Kistler, Patrick J. Carroll, Bradford B. Wayland, and Michael J. Zdilla pp 10122–10128 DOI: 10.1021/ic300435t

Histidine Based Fluorescence Sensor Detects Hg2+ in Solution, Paper Strips, and in Cells Joydev Hatai, Suman Pal, Gregor P. Jose, and Subhajit Bandyopadhyay pp 10129–10135 DOI: 10.1021/ic300530f

Topotactic Reduction Yielding Black Titanium Oxide Nanostructures as Metallic Electronic Conductors Satoshi Tominaka pp 10136–10140 DOI: 10.1021/ic300557u

Stereodynamics in Eight-Coordination; A 2D NMR Spectroscopic and Computational Study of the Exchange Process in ThCl4(Me2NCH2CH2NMe2)2 Graham E. Ball and Richard A. Andersen pp 10141–10147 DOI: 10.1021/ic300586f

Framework Solids Based on Copper(II) Halides (Cl/Br) and Methylene-Bridged Bis(1-hydroxybenzotriazole): Synthesis, Crystal Structures, Magneto-Structural Correlation, and Density Functional Theory (DFT) Studies Ashok Sasmal, Shyamapada Shit, Corrado Rizzoli, Hongfeng Wang, Cédric Desplanches, and Samiran Mitra pp 10148–10157 DOI: 10.1021/ic300629v

New Trick for an Old Ligand! The Sensing of Zn(II) Using a Lanthanide Based Ternary Yb(III)-cyclen-8-hydroxyquinoline System As a Dual Emissive Probe for Displacement Assay Steve Comby, Sarah A. Tuck, Laura K. Truman, Oxana Kotova, and Thorfinnur Gunnlaugsson pp 10158–10168 DOI: 10.1021/ic300697w

Gd4Ge3–xPnx (Pn = P, Sb, Bi, x = 0.5–3): Stabilizing the Nonexisting Gd4Ge3 Binary through Valence Electron Concentration. Electronic and Magnetic Properties of Gd4Ge3–xPnx Yan Yin Janice Cheung, Volodymyr Svitlyk, and Yurij Mozharivskyj pp 10169–10175 DOI: 10.1021/ic300817j

Synthesis and Characterization of Hypoelectronic Tantalaboranes: Comparison of the Geometric and Electronic Structures of [(Cp*TaX)2B5H11] (X = Cl, Br, and I) K. Geetharani, Bellie Sundaram Krishnamoorthy, Samia Kahlal, Shaikh M. Mobin, Jean-François Halet, and Sundargopal Ghosh pp 10176–10184 DOI: 10.1021/ic300848f

Sr2Mn3Sb2O2 Type Oxyselenides: Structures, Magnetism, and Electronic Properties of Sr2AO2M2Se2 (A=Co, Mn; M=Cu, Ag) Shifeng Jin, Xiaolong Chen, Jiangang Guo, Ming Lei, Jingjing Lin, Jianguo Xi, Wenjun Wang, and Wanyan Wang pp 10185–10192 DOI: 10.1021/ic301022g

Synthesis, Structure, and Physical Properties of Ln(Cu,Al,Ga)13–x (Ln = La–Pr, and Eu) and Eu(Cu,Al)13–x W. Adam Phelan, Michael J. Kangas, Gregory T. McCandless, Brenton L. Drake, Neel Haldolaarachchige, Liang L. Zhao, Jiakui K. Wang, Xiaoping P. Wang, David P. Young, Emilia Morosan, Christina Hoffmann, and Julia Y. Chan pp 10193–10202 DOI: 10.1021/ic301024t

Protein-Mediated Synthesis of Nanosized Mn-Doped ZnS: A Multifunctional, UV-Durable Bio-Nanocomposite Abhinandan Makhal, Soumik Sarkar, and Samir Kumar Pal pp 10203–10210 DOI: 10.1021/ic301083g

Syntheses, Structures, and Magnetic Properties of a Family of Tetranuclear Hydroxido-Bridged NiII2LnIII2 (Ln = La, Gd, Tb, and Dy) Complexes: Display of Slow Magnetic Relaxation by the Zinc(II)–Dysprosium(III) Analogue Sk Md Towsif Abtab, Manoranjan Maity, Kisholoy Bhattacharya, E. Carolina Sañudo, and Muktimoy Chaudhury pp 10211–10221 DOI: 10.1021/ic301138r

Thermal Decomposition and Recovery Behaviors of Layered Gadolinium Hydroxychloride Seoung-Soo Lee, Byung-Il Lee, Seung-joo Kim, Song-Ho Byeon, and Jun-Kun Kang pp 10222–10232 DOI: 10.1021/ic301143r

Experimental and Time-Dependent Density Functional Theory Characterization of the UV–Visible Spectra of Monomeric and μ-Oxo Dimeric Ferriprotoporphyrin IX David Kuter, Gerhard A. Venter, Kevin J. Naidoo, and Timothy J. Egan pp 10233–10250 DOI: 10.1021/ic301154e

Structural Study of Hydrated/Dehydrated Manganese Thiophene-2,5-diphosphonate Metal Organic Frameworks, Mn2(O3P–C4H2S–PO3)·2H2O Jean-Michel Rueff, Olivier Perez, Alain Pautrat, Nicolas Barrier, Gary B. Hix, Sylvie Hernot, Hélène Couthon-Gourvès, and Paul-Alain Jaffrès pp 10251–10261 DOI: 10.1021/ic301187y

Reactions of the Cationic Zinc Thiolate Model Complex [Zn(Tab)4](PF6)2 with N-Donor Ligands and Cobalt Dichloride Ai-Xia Zheng, Jing Si, Xiao-Yan Tang, Li-Li Miao, Miao Yu, Kai-Peng Hou, Fan Wang, Hong-Xi Li, and Jian-Ping Lang pp 10262–10273 DOI: 10.1021/ic301191n

Site-Isolated Redox Reactivity in a Trinuclear Iron Complex Emily V. Eames and Theodore A. Betley pp 10274–10278 DOI: 10.1021/ic301241s

Fe(II) Complexes That Mimic the Active Site Structure of Acetylacetone Dioxygenase: O2 and NO Reactivity Heaweon Park, Michael M. Bittner, Jacob S. Baus, Sergey V. Lindeman, and Adam T. Fiedler pp 10279–10289 DOI: 10.1021/ic3012712

Trigonal Mn3 and Co3 Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic, and Computational Investigation into the Correlation of Molecular and Electronic Structure Alison R. Fout, Dianne J. Xiao, Qinliang Zhao, T. David Harris, Evan R. King, Emily V. Eames, Shao-Liang Zheng, and Theodore A. Betley pp 10290–10299 DOI: 10.1021/ic301278m

High Pressure Synthesis and Superconductivity of the Ternary Compounds Mg(Mg1–xAlx)Si with the Anticotunnite Structure Shidong Ji, Masashi Tanaka, Shuai Zhang, and Shoji Yamanaka pp 10300–10305 DOI: 10.1021/ic301296u

Simple Route to Lattice Energies in the Presence of Complex Ions Leslie Glasser pp 10306–10310 DOI: 10.1021/ic301329c

Precise Electrochemical Control of Ferromagnetism in a Cyanide-Bridged Bimetallic Coordination Polymer Yoshifumi Mizuno, Masashi Okubo, Koichi Kagesawa, Daisuke Asakura, Tetsuichi Kudo, Haoshen Zhou, Katsuyoshi Oh-ishi, Atsushi Okazawa, and Norimichi Kojima pp 10311–10316 DOI: 10.1021/ic301361h

Antitumor Platinum(II) Complexes Containing Platinum-Based Moieties of Present Platinum Drugs and Furoxan Groups as Nitric Oxide Donors: Synthesis, DNA Interaction, and Cytotoxicity Jian Zhao, Shaohua Gou, Yanyan Sun, Lei Fang, and Zhimei Wang pp 10317–10324 DOI: 10.1021/ic301374z

Trifunctional Metal Ion-Catalyzed Solvolysis: Cu(II)-Promoted Methanolysis of N,N-bis(2-picolyl) Benzamides Involves Unusual Lewis Acid Activation of Substrate, Delivery of Coordinated Nucleophile, Powerful Assistance of the Leaving Group Departure Mark A. R. Raycroft, Christopher I. Maxwell, Robyn A. A. Oldham, Areen Saffouri Andrea, Alexei A. Neverov, and R. Stan Brown pp 10325–10333 DOI: 10.1021/ic301454y

Understanding the Forces That Govern Packing: A Density Functional Theory and Structural Investigation of Anion−π–Anion and Nonclassical C–H···Anion Interactions Sally Brooker, Nicholas G. White, Antonio Bauzá, Pere M. Deyà, and Antonio Frontera pp 10334–10340 DOI: 10.1021/ic3014688

Fragmentation of the Fluorite Type in Fe8Al17.4Si7.6: Structural Complexity in Intermetallics Dictated by the 18 Electron Rule Rie T. Fredrickson and Daniel C. Fredrickson pp 10341–10349 DOI: 10.1021/ic3015089

Comparison of the Effect of Functional Groups on Gas-Uptake Capacities by Fixing the Volumes of Cages A and B and Modifying the Inner Wall of Cage C in rht-Type MOFs XiaoLiang Zhao, Di Sun, Shuai Yuan, Shengyu Feng, Rong Cao, Daqiang Yuan, Suna Wang, Jianmin Dou, and Daofeng Sun pp 10350–10355 DOI: 10.1021/ic3015207

High-Resolution Spectroscopy and Structure of Osmium Tetroxide. A Benchmark Study on 192OsO4 Maud Louviot, Vincent Boudon, Laurent Manceron, Pascale Roy, Dionisio Bermejo, and Raúl Z. Martínez pp 10356–10365 DOI: 10.1021/ic3015282

Synthesis of Chlorin-Sensitized Near Infrared-Emitting Lanthanide Complexes Johanna Laakso, Geraldine A. Rosser, Csongor Szíjjártó, Andrew Beeby, and K. Eszter Borbas pp 10366–10374 DOI: 10.1021/ic3015354

Theoretical and Experimental Investigations on Hypoelectronic Heterodimetallaboranes of Group 6 Transition Metals Bellie Sundaram Krishnamoorthy, Arunabha Thakur, Kiran Kumar Varma Chakrahari, Shubhankar Kumar Bose, Paul Hamon, Thierry Roisnel, Samia Kahlal, Sundargopal Ghosh, and Jean-François Halet pp 10375–10383 DOI: 10.1021/ic301571e

On the Interaction of Acetone with Electrophilic Metallocavitands Having Extended Cavities Christian N. Garon, Maxime Daigle, Isabelle Levesque, Philippe Dufour, Hassan Iden, Christian Tessier, Thierry Maris, Jean-François Morin, and Frédéric-Georges Fontaine pp 10384–10393 DOI: 10.1021/ic3015755

Structure, Optical Properties, and Magnetism of the Full Zn1–xCuxWO4 (0 ≤ x ≤ 1) Composition Range Joseph E. Yourey, Joshua B. Kurtz, and Bart M. Bartlett pp 10394–10401 DOI: 10.1021/ic301607g

Structure–Property Relationships in Solid Solutions of Noncentrosymmetric Aurivillius Phases, Bi4–xLaxTi3O12 (x = 0–0.75) Seung-Jin Oh, Yiseul Shin, T. Thao Tran, Dong Woo Lee, Anne Yoon, P. Shiv Halasyamani, and Kang Min Ok pp 10402–10407 DOI: 10.1021/ic301615f

Synthesis of Backbone P-Functionalized Imidazol-2-ylidene Complexes: En Route to Novel Functional Ionic Liquids Paresh Kumar Majhi, Susanne Sauerbrey, Gregor Schnakenburg, Anthony J. Arduengo, III, and Rainer Streubel pp 10408–10416 DOI: 10.1021/ic301641z

Protonation of a Peroxodiiron(III) Complex and Conversion to a Diiron(III/IV) Intermediate: Implications for Proton-Assisted O–O Bond Cleavage in Nonheme Diiron Enzymes Matthew A. Cranswick, Katlyn K. Meier, Xiaopeng Shan, Audria Stubna, Jószef Kaizer, Mark P. Mehn, Eckard Münck, and Lawrence Que, Jr. pp 10417–10426 DOI: 10.1021/ic301642w

Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N) Fernanda Cimadevilla, M. Esther García, Daniel García-Vivó, Miguel A. Ruiz, Claudia Graiff, and Antonio Tiripicchio pp 10427–10436 DOI: 10.1021/ic301674k

Multiple Metal Binding to the 9-Methyladenine Model Nucleobase Involving N1, N6, and N7: Discrete Di- and Trinuclear Species with Different Combinations of Monofunctional PdII and PtII Entities Tímea Mihály, Marta Garijo Añorbe, Francisca M. Albertí, Pablo J. Sanz Miguel, and Bernhard Lippert pp 10437–10446 DOI: 10.1021/ic301681f

Biologically Relevant Heterodinuclear Iron–Manganese Complexes Michaël Carboni, Martin Clémancey, Florian Molton, Jacques Pécaut, Colette Lebrun, Lionel Dubois, Geneviève Blondin, and J.-M. Latour pp 10447–10460 DOI: 10.1021/ic301725z

Employment of a New Tripodal Ligand for the Synthesis of Cobalt(II/III), Nickel(II), and Copper(II) Clusters: Magnetic, Optical, and Thermal Properties Angelos B. Canaj, Demetrios I. Tzimopoulos, Aggelos Philippidis, George E. Kostakis, and Constantinos J. Milios pp 10461–10470 DOI: 10.1021/ic301744e

Issue 20

Novel Lithium-Containing Honeycomb Structures Vinod Kumar, Neha Bhardwaj, Nobel Tomar, Vaishali Thakral, and S. Uma pp 10471–10473 DOI: 10.1021/ic301125n

Arylated versus Cyclometalated Platinum(II) Polypyridines: Photoluminescence from Pt(4′-R-trpy)Ph+ Systems (R = NMe2, N-Pyrrolidinyl, or 1-Pyrenyl) Daniel P. Lazzaro, Phillip E. Fanwick, and David R. McMillin pp 10474–10476 DOI: 10.1021/ic301593b

Trifluoropropynyl as a Surrogate for the Cyano Ligand and Intense, Room-Temperature, Metal-Centered Emission from Its Rh(III) Complex Chivin Sun, Parth U. Thakker, Levan Khulordava, Daniel J. Tobben, Seth M. Greenstein, David L. Grisenti, Andrew G. Kantor, and Paul S. Wagenknecht pp 10477–10479 DOI: 10.1021/ic3016113

Incorporation of Neptunium(VI) into a Uranyl Selenite Nathan A. Meredith, Matthew J. Polinski, Jian Lin, Antonio Simonetti, and Thomas E. Albrecht-Schmitt pp 10480–10482 DOI: 10.1021/ic301682b

Ruthenium(II) Thiacrown Complexes Incorporating Noninnocent Redox Active Ligands: Synthesis, Electrochemical Properties, and Theoretical Studies James D. Ingram, Paulo J. Costa, Harry Adams, Michael D. Ward, Vítor Félix, and Jim A. Thomas pp 10483–10494 DOI: 10.1021/ic200814k

Syntheses and Spectroscopic, Structural, Electrochemical, Spectroelectrochemical, and Theoretical Studies of Osmium(II) Mono- and Bis-Alkynyl Complexes Patrick J. West, Marie P. Cifuentes, Torsten Schwich, Michael D. Randles, Joseph P. Morrall, Erandi Kulasekera, Simon Petrie, Robert Stranger, and Mark G. Humphrey pp 10495–10502 DOI: 10.1021/ic202542c

New Family of Cerium Halide Based Materials: CeX3·ROH Compounds Containing Planes, Chains, and Tetradecanuclear Rings Shae Anne Vaughn, Bryan C. Chakoumakos, Radu Custelcean, Joanne O. Ramey, Mark D. Smith, Lynn A. Boatner, and Hans-Conrad zur Loye pp 10503–10511 DOI: 10.1021/ic3003349

Cubane-Type Mo3FeS44+,5+ Complexes Containing Outer Diphosphane Ligands: Ligand Substitution Reactions, Spectroscopic Studies, and Electronic Structure Ivan Sorribes, Francesc Lloret, Joao C. Waerenborgh, Victor Polo, Rosa Llusar, and Cristian Vicent pp 10512–10521 DOI: 10.1021/ic300368z

Two New Dy3 Triangles with Trinuclear Circular Helicates and Their Single-Molecule Magnet Behavior Shuang-Yan Lin, Lang Zhao, Yun-Nan Guo, Peng Zhang, Yang Guo, and Jinkui Tang pp 10522–10528 DOI: 10.1021/ic300371m

Dinuclear Ruthenium Nitrido Complexes Supported by an Oxygen Tripodal Ligand Xiao-Yi Yi, Ho-Yuen Ng, Wai-Man Cheung, Herman H. Y. Sung, Ian D. Williams, and Wa-Hung Leung pp 10529–10535 DOI: 10.1021/ic300638r

Cyclometalated Iridium(III) Complexes Containing Hydroxide/Chloride Ligands: Isolation of Heterobridged Dinuclear Iridium(III) Compounds Containing μ-OH and μ-Pyrazole Ligands Vadapalli Chandrasekhar, Bani Mahanti, Priyanka Bandipalli, and Kotamarthi Bhanuprakash pp 10536–10547 DOI: 10.1021/ic300694m

Meso-substituted Porphyrin Derivatives via Palladium-Catalyzed Amination Showing Wide Range Visible Absorption: Synthesis and Photophysical Studies Kalliopi Ladomenou, Theodore Lazarides, Manas K. Panda, Georgios Charalambidis, Dimitra Daphnomili, and Athanassios G. Coutsolelos pp 10548–10556 DOI: 10.1021/ic300714n

Ligand Contributions to the Electronic Structures of the Oxidized Cobalt(II) salen Complexes Amélie Kochem, Hussein Kanso, Benoit Baptiste, Himanshu Arora, Christian Philouze, Olivier Jarjayes, Hervé Vezin, Dominique Luneau, Maylis Orio, and Fabrice Thomas pp 10557–10571 DOI: 10.1021/ic300763t

Syntheses and Electronic Properties of Rhodium(III) Complexes Bearing a Redox-Active Ligand Sarath Wanniarachchi, Brendan J. Liddle, Brandon Kizer, Jeewantha S. Hewage, Sergey V. Lindeman, and James R. Gardinier pp 10572–10580 DOI: 10.1021/ic300772h

New Dicyano Cyclometalated Compounds Containing Pd(II)–Tl(I) Bonds as Building Blocks in 2D Extended Structures: Synthesis, Structure, and Luminescence Studies Violeta Sicilia, Juan Forniés, Sara Fuertes, and Antonio Martín pp 10581–10589 DOI: 10.1021/ic300808z

Highly Flexible Molecule “Chameleon”: Reversible Thermochromism and Phase Transitions in Solid Copper(II) Diiminate Cu[CF3—C(NH)—CF═C(NH)—CF3]2 Victor N. Khrustalev, Svetlana O. Kostenko, Mikhail I. Buzin, Alexander A. Korlyukov, Yan V. Zubavichus, Michael A. Kurykin, and Mikhail Yu. Antipin pp 10590–10602 DOI: 10.1021/ic300814w

Synthesis and Magnetic Properties of a New Family of Macrocyclic MII3LnIII Complexes: Insights into the Effect of Subtle Chemical Modification on Single-Molecule Magnet Behavior Humphrey L. C. Feltham, Rodolphe Clérac, Liviu Ungur, Veacheslav Vieru, Liviu F. Chibotaru, Annie K. Powell, and Sally Brooker pp 10603–10612 DOI: 10.1021/ic300819u

Preservation of Chirality and Polarity between Chiral and Polar Building Units in the Solid State Romain Gautier and Kenneth R. Poeppelmeier pp 10613–10618 DOI: 10.1021/ic300847t

Cadmium(II) Complex Formation with Selenourea and Thiourea in Solution: An XAS and 113Cd NMR Study Farideh Jalilehvand, Zahra Amini, and Karnjit Parmar pp 10619–10630 DOI: 10.1021/ic300852t

Me–Si Bond Cleavage of Anionic Bis(trimethylsilyl)amide in Scorpionate-Anchored Rare Earth Metal Complexes Weiyin Yi, Jie Zhang, Zhenxia Chen, and Xigeng Zhou pp 10631–10638 DOI: 10.1021/ic3008552

Reactivity Control in Iron(III) Amino Triphenolate Complexes: Comparison of Monomeric and Dimeric Complexes Christopher J. Whiteoak, Blerina Gjoka, Eddy Martin, Marta Martínez Belmonte, Eduardo C. Escudero-Adán, Cristiano Zonta, Giulia Licini, and Arjan. W. Kleij pp 10639–10649 DOI: 10.1021/ic3008624

Effects of Lanthanoid Cations on the First Electronic Transition of Liquid Water Studied Using Attenuated Total Reflection Far-Ultraviolet Spectroscopy: Ligand Field Splitting of Lanthanoid Hydrates in Aqueous Solutions Takeyoshi Goto, Akifumi Ikehata, Yusuke Morisawa, Noboru Higashi, and Yukihiro Ozaki pp 10650–10656 DOI: 10.1021/ic3009255

Coordination Polymers Utilizing N-Oxide Functionalized Host Ligands James J. Henkelis, Sarah A. Barnett, Lindsay P. Harding, and Michaele J. Hardie pp 10657–10674 DOI: 10.1021/ic300940k

Cluster Coordination and Photoluminescence Properties of α-Ag2WO4 Microcrystals L. S. Cavalcante, M. A. P. Almeida, W. Avansi, Jr., R. L. Tranquilin, E. Longo, N. C. Batista, V. R. Mastelaro, and M. Siu Li pp 10675–10687 DOI: 10.1021/ic300948n

Novel Blue-Emitting NaxCa1-xAl2-xSi2+xO8:Eu2+ (x = 0.34) Phosphor with High Luminescent Efficiency for UV-Pumped Light-Emitting Diodes Ga-yeon Lee, Ji Yeon Han, Won Bin Im, Sang Hoon Cheong, and Duk Young Jeon pp 10688–10694 DOI: 10.1021/ic300956m

Synthesis and Electrochemistry of Organometallic Cobaltadithiaazulenes Mitsushiro Nomura, Fumiaki Imamura, Nguyen Ba Tuyet Nga, Chikako Fujita-Takayama, Toru Sugiyama, and Masatsugu Kajitani pp 10695–10703 DOI: 10.1021/ic300993a

EPR, Resonance Raman, and DFT Calculations on Thiolate- and Imidazole-Bound Iron(III) Porphyrin Complexes: Role of the Axial Ligand in Tuning the Electronic Structure Pradip Kumar Das, Sudipta Chatterjee, Subhra Samanta, and Abhishek Dey pp 10704–10714 DOI: 10.1021/ic3016035

Synthesis and Structure of Dirhodium Analogue of Octaborane-12 and Decaborane-14 Dipak Kumar Roy, Shubhankar Kumar Bose, R. S. Anju, V. Ramkumar, and Sundargopal Ghosh pp 10715–10722 DOI: 10.1021/ic301070e

Halide Ordering in Reduced Mixed Halides, Chlorides/Iodides, of Zirconium: Syntheses and Structures of Cs2[(Zr6B)(Cl,I)15] Cluster Compounds Arne Pigorsch and Martin Köckerling pp 10723–10727 DOI: 10.1021/ic3010807

Interplay of Metallophilic Interactions, π–π Stacking, and Ligand Substituent Effects in the Structures and Luminescence Properties of Neutral PtII and PdII Aryl Isocyanide Complexes Ilya M. Sluch, Anthea J. Miranda, Oussama Elbjeirami, Mohammad A. Omary, and LeGrande M. Slaughter pp 10728–10746 DOI: 10.1021/ic301104a

Soluble Diamagnetic Model for Malaria Pigment: Coordination Chemistry of Gallium(III)protoporphyrin-IX D. Scott Bohle, Erin L. Dodd, Tyler B. J. Pinter, and Martin J. Stillman pp 10747–10761 DOI: 10.1021/ic301106g

Syntheses and Structures of Closely Related Copper(I) Complexes of Tridentate (2-Pyridylmethyl)imine and (2-Pyridylmethyl)amine Ligands and Their Use in Mediating Atom Transfer Radical Polymerizations Sara A. Turner, Zachary D. Remillard, Desire T. Gijima, Emily Gao, Robert D. Pike, and Christopher Goh pp 10762–10773 DOI: 10.1021/ic3011585

PtII-Mediated Imine–Nitrile Coupling Leading to Symmetrical (1,3,5,7,9-Pentaazanona-1,3,6,8-tetraenato)Pt(II) Complexes Containing the Incorporated 1,3-Diiminoisoindoline Moiety Jamal Lasri, Maxim L. Kuznetsov, M. Fátima C. Guedes da Silva, and Armando J. L. Pombeiro pp 10774–10786 DOI: 10.1021/ic301176b

Synthesis, Structural Characterization, and Ab Initio Study of Cu5+δIn2+xSb2–x: A New B8-Related Structure Type Carola J. Müller, Sven Lidin, Susana Ramos de Debiaggi, Crispulo E. Deluque Toro, and Armando Fernández Guillermet pp 10787–10792 DOI: 10.1021/ic3011794

Metallic Yb2AuGe3: An Ordered Superstructure in the AlB2-Type Family with Mixed-Valent Yb and a High-Temperature Phase Transition Sebastian C. Peter and Sumanta Sarkar , Mercouri G. Kanatzidis pp 10793–10799 DOI: 10.1021/ic301197w

Stable Cu(I) Complexes with Thioamidoguanidine Possessing Halide-Bridge Structure Santosh K. Sahoo, Nilufa Khatun, Himanshu Sekhar Jena, and Bhisma K. Patel pp 10800–10807 DOI: 10.1021/ic301429g

Symmetry Aspects of H2 Splitting by Five-Coordinate d6 Ruthenium Amides, and Calculations on Acetophenone Hydrogenation, Ruthenium Alkoxide Formation, and Subsequent Hydrogenolysis in a Model trans-Ru(H)2(diamine)(diphosphine) System Faraj Hasanayn and Robert H. Morris pp 10808–10818 DOI: 10.1021/ic301233j

The 16 CB11(CH3)n(CD3)12–n• Radicals with 5-Fold Substitution Symmetry: Spin Density Distribution in CB11Me12• Jiří Kaleta, Ján Tarábek, Akin Akdag, Radek Pohl, and Josef Michl pp 10819–10824 DOI: 10.1021/ic301236s

Electrochemiluminescence of the [Ru(bpy)3]2+ Complex: The Coreactant Effect of PAMAM Dendrimers in an Aqueous Medium P. Perez-Tejeda, R. Prado-Gotor, and E. M. Grueso pp 10825–10831 DOI: 10.1021/ic301239x

Implications of Stoichiometry-Controlled Structural Changeover Between Heteroleptic Trigonal [Cu(phenAr2)(py)]+ and Tetragonal [Cu(phenAr2)(py)2]+ Motifs for Solution and Solid-State Supramolecular Self-Assembly Subhadip Neogi, Gregor Schnakenburg, Yvonne Lorenz, Marianne Engeser, and Michael Schmittel pp 10832–10841 DOI: 10.1021/ic301286w

Rational Design of a Ratiometric and Targetable Fluorescent Probe for Imaging Lysosomal Zinc Ions Lin Xue, Guoping Li, Dongjian Zhu, Qing Liu, and Hua Jiang pp 10842–10849 DOI: 10.1021/ic301307v

Density Functional Investigation of the Water Oxidation by Iron Complexes Based on Tetradentate Nitrogen Ligands Esra E. Kasapbasi and Myung-Hwan Whangbo pp 10850–10855 DOI: 10.1021/ic3013359

Ion Association in AlCl3 Aqueous Solutions from Constrained First-Principles Molecular Dynamics Emilie Cauët, Stuart A. Bogatko, Eric J. Bylaska, and John H. Weare pp 10856–10869 DOI: 10.1021/ic301346k

Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units Yunjing Shi, Shilie Pan, Xiaoyu Dong, Ying Wang, Min Zhang, Fangfang Zhang, and Zhongxiang Zhou pp 10870–10875 DOI: 10.1021/ic301351k

Stereoselective Synthesis of Biphenolate/Binaphtolate Titanate and Zirconate Alkoxide Species: Structural Characterization and Use in the Controlled ROP of Lactide Laurine Azor, Corinne Bailly, Lydia Brelot, Marc Henry, Pierre Mobian, and Samuel Dagorne pp 10876–10883 DOI: 10.1021/ic301352t

Zinc, Cadmium, and Mercury Complexes of a Pyridyloxy-Substituted Cyclotriphosphazene: Syntheses, Structures, and Fluxional Behavior Eric W. Ainscough, Andrew M. Brodie, Patrick J. B. Edwards, Geoffrey B. Jameson, Carl A. Otter, and Stephen Kirk pp 10884–10892 DOI: 10.1021/ic3013574

Lanthanide Complexes Based on a Diazapyridinophane Platform Containing Picolinate Pendants Adrián Roca-Sabio, Célia S. Bonnet, Marta Mato-Iglesias, David Esteban-Gómez, Éva Tóth, Andrés de Blas, Teresa Rodríguez-Blas, and Carlos Platas-Iglesias pp 10893–10903 DOI: 10.1021/ic301369z

Mechanism of “Turn-on” Fluorescent Sensors for Mercury(II) in Solution and Its Implications for Ligand Design Hyunjung Lee, Hee-Seung Lee, Joseph H. Reibenspies, and Robert D. Hancock pp 10904–10915 DOI: 10.1021/ic301380w

Synthesis, Protonation, and Reduction of Ruthenium–Peroxo Complexes with Pendent Nitrogen Bases Tristan A. Tronic, Werner Kaminsky, Michael K. Coggins, and James M. Mayer pp 10916–10928 DOI: 10.1021/ic3013987

Environmental Influence on the Single-Molecule Magnet Behavior of [MnIII6CrIII]3+: Molecular Symmetry versus Solid-State Effects Veronika Hoeke, Maik Heidemeier, Erich Krickemeyer, Anja Stammler, Hartmut Bögge, Jürgen Schnack, Andrei Postnikov, and Thorsten Glaser pp 10929–10954 DOI: 10.1021/ic301406j

A Model of Magnetic and Relaxation Properties of the Mononuclear [Pc2Tb]−TBA+ Complex O. S. Reu, A. V. Palii, S. M. Ostrovsky, P. L. W. Tregenna-Piggott, and S. I. Klokishner pp 10955–10965 DOI: 10.1021/ic3014078

Structural and Energetic Properties of Closed Shell XFn (X = Cl, Br, and I; n = 1–7) and XOnFm (X = Cl, Br, and I; n = 1–3; m = 0–6) Molecules and Ions Leading to Stability Predictions for Yet Unknown Compounds K. Sahan Thanthiriwatte, Monica Vasiliu, and David A. Dixon , Karl O. Christe pp 10966–10982 DOI: 10.1021/ic301438b

Synthesis, Structures, And Magnetic Behavior of New Anionic Copper(II) Sulfate Aggregates and Chains Andrew D. Burrows, Mary F. Mahon, Viorica M. Sebestyen, Yanhua Lan, and Annie K. Powell pp 10983–10989 DOI: 10.1021/ic301478x

Controlled Growth and Applications of Complex Metal Oxide ZnSn(OH)6 Polyhedra Jingzhou Yin, Feng Gao, Chengzhen Wei, and Qingyi Lu pp 10990–10995 DOI: 10.1021/ic301496k

Synthesis and Characterization of Antiapicophilic Arsoranes and Related Compounds Xin-Dong Jiang, Shiro Matsukawa, Satoshi Kojima, and Yohsuke Yamamoto pp 10996–11006 DOI: 10.1021/ic3014893

O′3–NaxVO2 System: A Superstructure for Na1/2VO2 Christophe Didier, Marie Guignard, Jacques Darriet, and Claude Delmas pp 11007–11016 DOI: 10.1021/ic301505e

Synthesis of Binucleating Macrocycles and Their Nickel(II) Hydroxo- and Cyano-Bridged Complexes with Divalent Ions: Anatomical Variation of Ligand Features Xiaofeng Zhang, Deguang Huang, Yu-Sheng Chen, and R. H. Holm pp 11017–11029 DOI: 10.1021/ic301506x

Titanium(IV) and Vitamin C: Aqueous Complexes of a Bioactive Form of Ti(IV) Katherine M. Buettner, Joseph M. Collins, and Ann M. Valentine pp 11030–11039 DOI: 10.1021/ic301545m

Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks Jacob H. Olshansky, Thanh Thao Tran, Kristen J. Hernandez, Matthias Zeller, P. Shiv Halasyamani, Joshua Schrier, and Alexander J. Norquist pp 11040–11048 DOI: 10.1021/ic3015496

Stable Silaimines with Three- and Four-Coordinate Silicon Atoms Prinson P. Samuel, Ramachandran Azhakar, Rajendra S. Ghadwal, Sakya S. Sen, Herbert W. Roesky, Markus Granitzka, Julia Matussek, Regine Herbst-Irmer, and Dietmar Stalke pp 11049–11054 DOI: 10.1021/ic301543y

Methane to Methanol Conversion Induced by Thorium Oxide through the CH3Th(O)H Intermediate in Solid Argon Yu Gong, Lester Andrews, Virgil E. Jackson, and David A. Dixon pp 11055–11060 DOI: 10.1021/ic301595h

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P2 Ligand M. Angeles Alvarez, M. Esther García, Daniel García-Vivó, Alberto Ramos, and Miguel A. Ruiz pp 11061–11075 DOI: 10.1021/ic301612g

Effects of Linker Torsional Constraints on the Rate of Ground-State Hole Transfer in Porphyrin Dyads Christopher J. Hondros, Kunche Aravindu, James R. Diers, Dewey Holten, Jonathan S. Lindsey, and David F. Bocian pp 11076–11086 DOI: 10.1021/ic301613k

Noncovalent Interactions in Peri-Substituted Chalconium Acenaphthene and Naphthalene Salts: A Combined Experimental, Crystallographic, Computational, and Solid-State NMR Study Fergus R. Knight, Rebecca A. M. Randall, Kasun S. Athukorala Arachchige, Lucy Wakefield, John M. Griffin, Sharon E. Ashbrook, Michael Bühl, Alexandra M. Z. Slawin, and J. Derek Woollins pp 11087–11097 DOI: 10.1021/ic301627y

Revisiting Zinc Coordination in Human Carbonic Anhydrase II He Song, David L. Wilson, Erik R. Farquhar, Edwin A. Lewis, and Joseph P. Emerson pp 11098–11105 DOI: 10.1021/ic301645j

Hydrothermal Derived LaOF:Ln3+ (Ln = Eu, Tb, Sm, Dy, Tm, and/or Ho) Nanocrystals with Multicolor-Tunable Emission Properties Mengmeng Shang, Dongling Geng, Xiaojiao Kang, Dongmei Yang, Yang Zhang, and Jun Lin pp 11106–11116 DOI: 10.1021/ic301662c

Electrochemiluminescence Properties of [Pt2Ag4(C≡CC6H4R)8]n (R = CH3, n = 1; R = H, n = 1 and 2) with Amine (TPrA and DBAE) as the Coreactant and Determination of Sudan I Qiao-Hua Wei, Li-Jing Han, Yi Jiang, Xiao-Xia Lin, Ya-Nan Duan, and Guo-Nan Chen pp 11117–11125 DOI: 10.1021/ic3016657

Heterobimetallic MOFs Containing Tetrathiocyanometallate Building Blocks: Pressure-Induced Spin Crossover in the Porous {FeII(pz)[PdII(SCN)4]} 3D Coordination Polymer Francisco J. Muñoz-Lara, Zulema Arcís-Castillo, M. Carmen Muñoz, J. Alberto Rodríguez-Velamazán, Ana B. Gaspar, and José A. Real pp 11126–11132 DOI: 10.1021/ic3016673

Synthesis and Characterization of Amine-Bridged Bis(phenolate)lanthanide Alkoxides and Their Application in the Controlled Polymerization of rac-Lactide and rac-β-Butyrolactone Kun Nie, Lei Fang, Yingming Yao, Yong Zhang, Qi Shen, and Yaorong Wang pp 11133–11143 DOI: 10.1021/ic301746c

Ba3LnInS6 (Ln = Pr, Sm, Gd, Yb) and Ba2LnGaS5 (Ln = Pr, Nd): Syntheses, Structures, and Magnetic and Optical Properties Kai Feng, Youguo Shi, Wenlong Yin, Wendong Wang, Jiyong Yao, and Yicheng Wu pp 11144–11149 DOI: 10.1021/ic301750x

The First Uranyl Arsonates Featuring Heterometallic Cation–Cation Interactions with UVI═O–ZnII Bonding Tao Tian, Weiting Yang, Qing-Jiang Pan, and Zhong-Ming Sun pp 11150–11154 DOI: 10.1021/ic3017479

[1.1]Ferrocenophanes and Bis(ferrocenyl) Species with Aluminum and Gallium as Bridging Elements: Synthesis, Characterization, and Electrochemical Studies Bidraha Bagh, Nora C. Breit, Klaus Harms, Gabriele Schatte, Ian J. Burgess, Holger Braunschweig, and Jens Müller pp 11155–11167 DOI: 10.1021/ic301777y

Expanding Yttrium Bis(trimethylsilylamide) Chemistry Through the Reaction Chemistry of (N2)2–, (N2)3–, and (NO)2– Complexes Joy H. Farnaby, Ming Fang, Joseph W. Ziller, and William J. Evans pp 11168–11176 DOI: 10.1021/ic301778q

One-Dimensional Uranyl-2,2′-bipyridine Coordination Polymer with Cation–Cation Interactions: (UO2)2(2,2′-bpy)(CH3CO2)(O)(OH) Pius O. Adelani and Peter C. Burns pp 11177–11183 DOI: 10.1021/ic301783q

Crystal Structure and Superconducting Properties of Hexagonal Lithium–Niobium Oxynitride Teruki Motohashi, Masahiko Ito, Yuji Masubuchi, Makoto Wakeshima, and Shinichi Kikkawa pp 11184–11189 DOI: 10.1021/ic301870n

Cobalt in a Bis-β-diketiminate Environment Michael P. Marshak, Matthew B. Chambers, and Daniel G. Nocera pp 11190–11197 DOI: 10.1021/ic301970w

Isomer-Directed Structural Diversity and Its Effect on the Nanosheet Exfoliation and Magnetic Properties of 2,3-Dimethylsuccinate Hybrid Frameworks Paul J. Saines, Mark Steinmann, Jin-Chong Tan, Hamish H.-M. Yeung, Wei Li, Phillip T. Barton, and Anthony K. Cheetham pp 11198–11209 DOI: 10.1021/ic302011x

Issue 21

Elucidation of Tetraboric Acid with a New Borate Fundamental Building Block in a Chiral Uranyl Fluoroborate Shuao Wang, T. Gannon Parker, Daniel J. Grant, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Laura Gagliardi, and Thomas E. Albrecht-Schmitt pp 11211–11213 DOI: 10.1021/ic300741s

New High-Nuclearity Carbonyl and Carbonyl-Substituted Rhodium Clusters and Their Relationships with Polyicosahedral Carbonyl-Substituted Palladium- and Gold-Thiolates Dmitriy S. Dolzhnikov, Maria C. Iapalucci, Giuliano Longoni, Cristina Tiozzo, Stefano Zacchini, and Cristina Femoni pp 11214–11216 DOI: 10.1021/ic3011508

A Nitrogenase Cluster Model [Fe8S6O] with an Oxygen Unsymmetrically Bridging Two Proto-Fe4S3 Cubes: Relevancy to the Substrate Binding Mode of the FeMo Cofactor Shun Ohta, Yasuhiro Ohki, Takayoshi Hashimoto, Roger E. Cramer, and Kazuyuki Tatsumi pp 11217–11219 DOI: 10.1021/ic301348f

A FRET Enzyme-Based Probe for Monitoring Hydrogen Sulfide Maria Strianese, Gottfried J. Palm, Stefano Milione, Olaf Kühl, Winfried Hinrichs, and Claudio Pellecchia pp 11220–11222 DOI: 10.1021/ic301363d

Is the Isolated Pentagon Rule Always Satisfied for Metallic Carbide Endohedral Fullerenes? Tao Yang, Xiang Zhao, Sheng-Tao Li, and Shigeru Nagase pp 11223–11225 DOI: 10.1021/ic3014514

Skeletal Transformation of Isolated Pentagon Rule (IPR) Fullerene C82 into Non-IPR C82Cl28 with Notably Low Activation Barriers Ilya N. Ioffe, Olga N. Mazaleva, Lev N. Sidorov, Shangfeng Yang, Tao Wei, Erhard Kemnitz, and Sergey I. Troyanov pp 11226–11228 DOI: 10.1021/ic301650j

A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst Manas Sutradhar, Marina V. Kirillova, M. Fátima C. Guedes da Silva, Luísa M. D. R. S. Martins, and Armando J. L. Pombeiro pp 11229–11231 DOI: 10.1021/ic3017062

Comparative Study of Activation Methods on Tuning Gas Sorption Properties of a Metal–Organic Framework with Nanosized Ligands Yan-Ping He, Yan-Xi Tan, and Jian Zhang pp 11232–11234 DOI: 10.1021/ic3017529

Synthesis, Lattice Dynamics, and Mechanical Properties of a High-Pressure Scheelite Phase of RVO4 Zuocai Huang, Lei Zhang, and Wei Pan pp 11235–11237 DOI: 10.1021/ic3017672

Synthesis and Characterization of a Chromium(V) cis-1,2-Cyclohexanediolato Complex: A Model of Reactive Intermediates in Chromium-Induced Cancers Ruben Bartholomäus, Klaus Harms, Aviva Levina, and Peter A. Lay pp 11238–11240 DOI: 10.1021/ic301900q

μ-O Bridged Mn10 Assemblies with Open O6 Sites for Binding Extra Guests: Structural, Magnetic, and Surface Studies Muhammad U. Anwar, Louise N. Dawe, Mohammad S. Alam, and Laurence K. Thompson pp 11241–11250 DOI: 10.1021/ic3003355

Two New Types of Xenon–Carbon Species: The Zwitterion, 1-(Xe+)C6F4-4-(BF3–), and the Dication, [1,4-(Xe)2C6F4]2+ Hermann-Josef Frohn, Vural Bilir, and Ulrich Westphal pp 11251–11258 DOI: 10.1021/ic3017112

Spacer Separated Donor–Acceptor Complexes [D→C6F4→BF3] (D = Xe, CO, N2) and the Dication [Xe→C6F4←Xe]2+. A Theoretical Study Catharina Goedecke, René Sitt, and Gernot Frenking pp 11259–11265 DOI: 10.1021/ic301722q

Series of Inorganic–Organic Hybrid Materials Constructed From Octamolybdates and Metal–Organic Frameworks: Syntheses, Structures, and Physical Properties Wei-Qiu Kan, Jin Yang, Ying-Ying Liu, and Jian-Fang Ma pp 11266–11278 DOI: 10.1021/ic300134z

Chiral Crystallization of a Heterodinuclear Ni-Ln Series: Comprehensive Analysis of the Magnetic Properties. Fanica Cimpoesu, Françoise Dahan, Sonia Ladeira, Marilena Ferbinteanu, and Jean-Pierre Costes pp 11279–11293 DOI: 10.1021/ic3001784

Switching Orientation of Two Axial Imidazole Ligands between Parallel and Perpendicular in Low-Spin Fe(III) and Fe(II) Nonplanar Porphyrinates Ranjan Patra, Dipankar Sahoo, Soumyajit Dey, Debangsu Sil, and Sankar Prasad Rath pp 11294–11305 DOI: 10.1021/ic300229u

Quantum Mechanical Design of Efficient Second-Order Nonlinear Optical Materials Based on Heteroaromatic Imido-Substituted Hexamolybdates: First Theoretical Framework of POM-Based Heterocyclic Aromatic Rings Muhammad Ramzan Saeed Ashraf Janjua pp 11306–11314 DOI: 10.1021/ic3002652

Cooperative Assembly of Zn Cross-Linked Artificial Tripeptides with Pendant Hydroxyquinoline Ligands Meng Zhang, Joy A. Gallagher, Matthew B. Coppock, Lisa M. Pantzar, and Mary Elizabeth Williams pp 11315–11323 DOI: 10.1021/ic3004504

Tunable Energy Transfer Rates via Control of Primary, Secondary, and Tertiary Structure of a Coiled Coil Peptide Scaffold Dale J. Wilger, Stephanie E. Bettis, Christopher K. Materese, Maria Minakova, Garegin A. Papoian, John M. Papanikolas, and Marcey L. Waters pp 11324–11338 DOI: 10.1021/ic300669t

Design of a Peptidic Turn with High Affinity for HgII Sara Pires, Jelena Habjanič, Murat Sezer, Cláudio M. Soares, Lars Hemmingsen, and Olga Iranzo pp 11339–11348 DOI: 10.1021/ic3008014

Lanthanide Metal–Organic Frameworks: Searching for Efficient Solvent-Free Catalysts Richard F. D’Vries, Marta Iglesias, Natalia Snejko, Enrique Gutiérrez-Puebla, and M. Angeles Monge pp 11349–11355 DOI: 10.1021/ic300816r

Identifying a Structural Preference in Reduced Rare-Earth Metal Halides by Combining Experimental and Computational Techniques Simon Steinberg, Jakoah Brgoch, Gordon J. Miller, and Gerd Meyer pp 11356–11364 DOI: 10.1021/ic300838a

DFT Study of the Stereoselective Formation of cis-W(CO)4(η2-C2H4)2 in the Gas-Phase Consecutive Coordination of C2H4 onto Doubly Coordinatively Unsaturated W(CO)4 Yo-ichi Ishikawa, Kei Umemoto, and Arifumi Okada pp 11365–11370 DOI: 10.1021/ic300858d

Oxyhydrides of (Ca,Sr,Ba)TiO3 Perovskite Solid Solutions Tatsunori Sakaguchi, Yoji Kobayashi, Takeshi Yajima, Masatoshi Ohkura, Cédric Tassel, Fumitaka Takeiri, Shingo Mitsuoka, Hiroshi Ohkubo, Takafumi Yamamoto, Jung eun Kim, Naruki Tsuji, Akihiko Fujihara, Yoshitaka Matsushita, James Hester, Maxim Avdeev, Kenji Ohoyama, and Hiroshi Kageyama pp 11371–11376 DOI: 10.1021/ic300859n

Anion-Induced Self-Assembly of Luminescent and Magnetic Homoleptic Cyclic Tetranuclear Ln4(Salen)4 and Ln4(Salen)2 Complexes (Ln = Nd, Yb, Er, or Gd) Weixu Feng, Yao Zhang, Zhao Zhang, Xingqiang Lü, Han Liu, Guoxiang Shi, Dan Zou, Jirong Song, Daidi Fan, Wai-Kwok Wong, and Richard A. Jones pp 11377–11386 DOI: 10.1021/ic300918c

A Bis(terpyridine)ruthenium Complex with Three Redox-Active Amine Sites: Electrochemical, Optical, and Computational Studies You-Ming Zhang, Si-Hai Wu, Chang-Jiang Yao, Hai-Jing Nie, and Yu-Wu Zhong pp 11387–11395 DOI: 10.1021/ic301004e

Homo- and Heterovalent Substitutions in the New Clathrates I Si30P16Te8–xSex and Si30+xP16–xTe8–xBrx: Synthesis, Crystal Structure, and Thermoelectric Properties Nikolay S. Abramchuk, Wilder Carrillo-Cabrera, Igor Veremchuk, Niels Oeschler, Andrei V. Olenev, Yurii Prots, Ulrich Burkhardt, Evgeny V. Dikarev, Juri Grin, and Andrei V. Shevelkov pp 11396–11405 DOI: 10.1021/ic3010097

Ferritin Ion Channel Disorder Inhibits Fe(II)/O2 Reactivity at Distant Sites Takehiko Tosha, Rabindra K. Behera, and Elizabeth C. Theil pp 11406–11411 DOI: 10.1021/ic3010135

Discovery of Spin Glass Behavior in Ln2Fe4Sb5 (Ln = La–Nd and Sm) W. Adam Phelan, Giang V. Nguyen, Jiakui K. Wang, Gregory T. McCandless, Emilia Morosan, John F. DiTusa, and Julia Y. Chan pp 11412–11421 DOI: 10.1021/ic301030f

Staple Motifs, Initial Steps in the Formation of Thiolate-Protected Gold Nanoparticles: How Do They Form? Víctor Rojas-Cervellera, Ernest Giralt, and Carme Rovira pp 11422–11429 DOI: 10.1021/ic301079k

Amino Alcohol-Derived Reduced Schiff Base VIVO and VV Compounds as Catalysts for Asymmetric Sulfoxidation of Thioanisole with Hydrogen Peroxide Pedro Adão, Maxim L. Kuznetsov, Sónia Barroso, Ana M. Martins, F. Avecilla, and João Costa Pessoa pp 11430–11449 DOI: 10.1021/ic301153p

Electrochemical and Spectroscopic Study of Ce(III) Coordination in the 1-Butyl-3-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide Ionic Liquid Containing Chloride Ion Li-Hsien Chou, Walter E. Cleland, Jr., and Charles L. Hussey pp 11450–11457 DOI: 10.1021/ic301172g

From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange Weiting Yang, Hong-Yue Wu, Run-Xue Wang, Qing-Jiang Pan, Zhong-Ming Sun, and Hongjie Zhang pp 11458–11465 DOI: 10.1021/ic301183h

Linking 31P Magnetic Shielding Tensors to Crystal Structures: Experimental and Theoretical Studies on Metal(II) Aminotris(methylenephosphonates) Johannes Weber, Gisbert Grossmann, Konstantinos D. Demadis, Nikos Daskalakis, Erica Brendler, Martin Mangstl, and Jörn Schmedt auf der Günne pp 11466–11477 DOI: 10.1021/ic301192y

Oligometallic Template Strategy for Synthesis of a Macrocyclic Dimer-Type Octaoxime Ligand for Its Cooperative Complexation Shigehisa Akine, Toshio Tadokoro, and Tatsuya Nabeshima pp 11478–11486 DOI: 10.1021/ic3012525

Expanding the Ruddlesden–Popper Manganite Family: The n = 3 La3.2Ba0.8Mn3O10 Member Joke Hadermann, Artem M. Abakumov, Alexander A. Tsirlin, Marina G. Rozova, Eleni Sarakinou, and Evgeny V. Antipov pp 11487–11492 DOI: 10.1021/ic301332e

Synthesis, Crystal Structure, and Magnetic Properties of Li3Mg2OsO6, a Geometrically Frustrated Osmium(V) Oxide with an Ordered Rock Salt Structure: Comparison with Isostructural Li3Mg2RuO6 Phuong-Hieu T. Nguyen, Farshid Ramezanipour, John E. Greedan, Lachlan M. D. Cranswick, and Shahab Derakhshan pp 11493–11499 DOI: 10.1021/ic3013377

Long-Range Electron Transfer in Zinc-Phthalocyanine-Oligo(Phenylene-ethynylene)-Based Donor-Bridge-Acceptor Dyads Erik Göransson, Julien Boixel, Jérôme Fortage, Denis Jacquemin, Hans-Christian Becker, Errol Blart, Leif Hammarström, and Fabrice Odobel pp 11500–11512 DOI: 10.1021/ic3013552

Preparation of Hollow Co3O4 Microspheres and Their Ethanol Sensing Properties Qingze Jiao, Min Fu, Chao You, Yun Zhao, and Hansheng Li pp 11513–11520 DOI: 10.1021/ic3013602

Detailed Electrochemical Studies of the Tetraruthenium Polyoxometalate Water Oxidation Catalyst in Acidic Media: Identification of an Extended Oxidation Series using Fourier Transformed Alternating Current Voltammetry Chong-Yong Lee, Si-Xuan Guo, Aidan F. Murphy, Timothy McCormac, Jie Zhang, Alan M. Bond, Guibo Zhu, Craig L. Hill, and Yurii V. Geletii pp 11521–11532 DOI: 10.1021/ic301370y

Clarifying the Mechanism of Cation Exchange in Ca(II)[15-MCCu(II)Ligand-5] Complexes Choong-Sun Lim, Matteo Tegoni, Tamás Jakusch, Jeff W. Kampf, and Vincent L. Pecoraro pp 11533–11540 DOI: 10.1021/ic3013798

Effect of pH and Reaction Time on the Structures of Early Lanthanide(III) Borate Perchlorates Matthew J. Polinski, Shuao Wang, Evgeny V. Alekseev, Justin N. Cross, Wulf Depmeier, and Thomas E. Albrecht-Schmitt pp 11541–11548 DOI: 10.1021/ic301421e

Pt–Mo and Pt–W Mixed-Metal Clusters with Chelating or Bridging Diphosphine Short-Bite Ligands (Ph2P)2NH and (Ph2P)2N(CH2)9CH3: A Combined Synthetic and Theoretical Study Stefano Todisco, Vito Gallo, Piero Mastrorilli, Mario Latronico, Nazzareno Re, Francesco Creati, and Pierre Braunstein pp 11549–11561 DOI: 10.1021/ic301445h

New Layered Tin(II) Thiophosphates ASnPS4 (A = K, Rb, Cs): Synthesis, Structure, Glass Formation, and the Modulated CsSnPS4 Santanu Banerjee, Christos D. Malliakas, and Mercouri G. Kanatzidis pp 11562–11573 DOI: 10.1021/ic301456m

Synthesis and Reversible Transformation of Cun-Bridged (n = 1, 2, or 4) Silicodecatungstate Dimers Kosuke Suzuki, Masahiro Shinoe, and Noritaka Mizuno pp 11574–11581 DOI: 10.1021/ic301488a

Topological Versatility of Oxalate-Based Bimetallic One-Dimensional (1D) Compounds Associated with Ammonium Cations Emilio Pardo, Cyrille Train, Kamal Boubekeur, Geoffrey Gontard, Joan Cano, Francesc Lloret, Keitaro Nakatani, and Michel Verdaguer pp 11582–11593 DOI: 10.1021/ic3014915

Preparations of Metal Trichalcogenophosphonates from Organophosphonate Esters Robert P. Davies, Laura Patel, and Andrew J. P. White pp 11594–11601 DOI: 10.1021/ic301504p

Do Solid-State Structures Reflect Lewis Acidity Trends of Heavier Group 13 Trihalides? Experimental and Theoretical Case Study Alexey Y. Timoshkin, Michael Bodensteiner, Tatiana N. Sevastianova, Anna S. Lisovenko, Elena I. Davydova, Manfred Scheer, Christian Graßl, and Alina V. Butlak pp 11602–11611 DOI: 10.1021/ic301507c

Syntheses and Characterization of Salts with the [Al(D)4F2]+  Cation (D = Pyridine or Water) Anton Dimitrov, Detlef Heidemann, Khalaf I. Khallow, and Erhard Kemnitz pp 11612–11622 DOI: 10.1021/ic301502u

Synthesis, Crystal Structures, and Luminescence Properties of Carboxylate Based Rare-Earth Coordination Polymers Roel Decadt, Kristof Van Hecke, Diederik Depla, Karen Leus, David Weinberger, Isabel Van Driessche, Pascal Van Der Voort, and Rik Van Deun pp 11623–11634 DOI: 10.1021/ic301544q

A Tripyrrolylmethane-Based Macrobicyclic Triazacryptand: X-ray Structure, Size-Selective Anion Binding, and Fluoride-Ion-Mediated Proton–Deuterium Exchange Studies Tapas Guchhait, Ganesan Mani, Carola Schulzke, and Anakuthil Anoop pp 11635–11644 DOI: 10.1021/ic301546v

Bilayer Mott System Based on Ni(dmit)2 (dmit = 1,3-dithiole-2-thione-4,5-dithiolate) Anion Radicals: Two Isostructural Salts Exhibit Contrasting Magnetic Behavior Tetsuro Kusamoto, Hiroshi M. Yamamoto, Naoya Tajima, Yugo Oshima, Satoshi Yamashita, and Reizo Kato pp 11645–11654 DOI: 10.1021/ic301552z

Color-Tunable Emission and Energy Transfer in Ca3Gd7(PO4)(SiO4)5O2: Ce3+/Tb3+/Mn2+ Phosphors Yang Zhang, Guogang Li, Dongling Geng, Mengmeng Shang, Chong Peng, and Jun Lin pp 11655–11664 DOI: 10.1021/ic3015578

Facile Metalation of Hbzq by [cis-Pt(C6F5)2(thf)2]: A Route to a Pentafluorophenyl Benzoquinolate Solvate Complex That Easily Coordinates Terminal Alkynes. Spectroscopic and Optical Properties Jesús R. Berenguer, Elena Lalinde, M. Teresa Moreno, Sergio Sánchez, and Javier Torroba pp 11665–11679 DOI: 10.1021/ic301563u

Effect of Nitrogen-Containing Impurities on the Activity of Perovskitic Catalysts for the Catalytic Combustion of Methane Olga Buchneva, Alessandro Gallo, and Ilenia Rossetti pp 11680–11687 DOI: 10.1021/ic3015892

Selective and Effective Stabilization of MoVI═O Bonds by NH···S Hydrogen Bonds via Trans Influence Taka-aki Okamura, Miki Tatsumi, Yui Omi, Hitoshi Yamamoto, and Kiyotaka Onitsuka pp 11688–11697 DOI: 10.1021/ic301597d

A Binuclear MnIII Complex of a Scorpiand-Like Ligand Displaying a Single Unsupported MnIII–O–MnIII Bridge Salvador Blasco, Joan Cano, M. Paz Clares, Santiago García-Granda, Antonio Doménech, Hermas R. Jiménez, Begoña Verdejo, Francesc Lloret, and Enrique García-España pp 11698–11706 DOI: 10.1021/ic3016063

Identification of a Nonanuclear {CoII9} Polyoxometalate Cluster as a Homogeneous Catalyst for Water Oxidation Sara Goberna-Ferrón, Laura Vigara, Joaquín Soriano-López, and José Ramón Galán-Mascarós pp 11707–11715 DOI: 10.1021/ic301618h

Bis(amidinato)germylenerhodium Complexes: Synthesis, Structure, and Density Functional Theory Calculations Dimitri Matioszek, Nathalie Saffon, Jean-Marc Sotiropoulos, Karinne Miqueu, Annie Castel, and Jean Escudié pp 11716–11721 DOI: 10.1021/ic3016194

X-ray Absorption Spectroscopy Study of Novel Inorganic–organic Hybrid Ferromagnetic Cu–pyz–[M(CN)8]3– Assemblies Olaf Stefańczyk, Robert Podgajny, Tomasz Korzeniak, Michał Rams, Marcin Kozieł, Wiesław Łasocha, Dariusz A. Zając, and Barbara Sieklucka pp 11722–11729 DOI: 10.1021/ic301634m

Synthesis, Structure, Magnetism, and Optical Properties of Cs2Cu3DyTe4 Jean-Marie Babo, Eun Sang Choi, and Thomas E. Albrecht-Schmitt pp 11730–11735 DOI: 10.1021/ic301649p

Syntheses, Structures, Physical Properties, and Electronic Structures of Ba2MLnTe5 (M = Ga and Ln = Sm, Gd, Dy, Er, Y; M = In and Ln = Ce, Nd, Sm, Gd, Dy, Er, Y) Wenlong Yin, Wendong Wang, Lei Bai, Kai Feng, Youguo Shi, Wenyu Hao, Jiyong Yao, and Yicheng Wu pp 11736–11744 DOI: 10.1021/ic301655e

A Crystal Structure Analysis and Magnetic Investigation on Highly Ordered Mesoporous Cr2O3 Harun Tüysüz, Claudia Weidenthaler, Tobias Grewe, Elena Lorena Salabaş, Maria. J. Benitez Romero, and Ferdi Schüth pp 11745–11752 DOI: 10.1021/ic301671a

Synthesis, Structure, and Electrochemistry of the Ni–Au Carbonyl Cluster [Ni12Au(CO)24]3– and Its Relation to [Ni32Au6(CO)44]6– Iacopo Ciabatti, Cristina Femoni, Maria Carmela Iapalucci, Giuliano Longoni, Stefano Zacchini, Serena Fedi, and Fabrizia Fabrizi de Biani pp 11753–11761 DOI: 10.1021/ic301679h

Charge Distribution and Local Structure of Americium-Bearing Thorium Oxide Solid Solutions U. Carvajal-Nunez, D. Prieur, T. Vitova, and J. Somers pp 11762–11768 DOI: 10.1021/ic301709d

Vibrational Probes and Determinants of the S = 0 S = 2 Spin Crossover in Five-Coordinate [Fe(TPP)(CN)]− Jianfeng Li, Qian Peng, Alexander Barabanschikov, Jeffrey W. Pavlik, E. Ercan Alp, Wolfgang Sturhahn, Jiyong Zhao, J. Timothy Sage, and W. Robert Scheidt pp 11769–11778 DOI: 10.1021/ic301719v

Na1.515EuGeS4, A Three-Dimensional Crystalline Assembly of Empty Nanotubules Constructed with Europium(II/III) Mixed Valence Ions Amitava Choudhury, Fernande Grandjean, Gary J. Long, and Peter K. Dorhout pp 11779–11786 DOI: 10.1021/ic301724v

Key Hydride Vibrational Modes in [NiFe] Hydrogenase Model Compounds Studied by Resonance Raman Spectroscopy and Density Functional Calculations Hannah S. Shafaat, Katharina Weber, Taras Petrenko, Frank Neese, and Wolfgang Lubitz pp 11787–11797 DOI: 10.1021/ic3017276

Tetraalkylammonium Uranyl Isothiocyanates Clare E. Rowland, Mercouri G. Kanatzidis, and L. Soderholm pp 11798–11804 DOI: 10.1021/ic301741u

Structural Parameters of Pr3MgNi14 during Hydrogen Absorption–Desorption Process Kenji Iwase, Naoyoshi Terashita, Kazuhiro Mori, and Toru Ishigaki pp 11805–11810 DOI: 10.1021/ic301743p

Study of Ga3+-Induced Hydrothermal Crystallization of an α-Quartz Type Ga1-xFexPO4 Single Crystal by in Situ X-ray Absorption Spectroscopy (XAS) Manhal Souleiman, Olivier Cambon, Abel Haidoux, Julien Haines, Claire Levelut, Vincent Ranieri, and Jean-Louis Hazemann pp 11811–11819 DOI: 10.1021/ic3017485

Dinuclear Complexes Containing Linear M–F–M [M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)] Bridges: Trends in Structures, Antiferromagnetic Superexchange Interactions, and Spectroscopic Properties Daniel L. Reger, Andrea E. Pascui, Mark D. Smith, Julia Jezierska, and Andrew Ozarowski pp 11820–11836 DOI: 10.1021/ic301757g

Preparation of a Diphosphine with Persistent Phosphinyl Radical Character in Solution: Characterization, Reactivity with O2, S8, Se, Te, and P4, and Electronic Structure Calculations Nick A. Giffin, Arthur D. Hendsbee, Tracey L. Roemmele, Michael D. Lumsden, Cory C. Pye, and Jason D. Masuda pp 11837–11850 DOI: 10.1021/ic301758k

Structure and Spectroscopic Properties of Gold(I) Diselenophosph(in)ate Complexes: A Joint Experimental and Theoretical Study Camille Latouche, Yu-Chen Lee, Jian-Hong Liao, Eric Furet, Jean-Yves Saillard, C. W. Liu, and Abdou Boucekkine pp 11851–11859 DOI: 10.1021/ic301763k

Reactivity Studies on [Cp′FeI]2: Monomeric Amido, Phenoxo, and Alkyl Complexes Marc D. Walter and Peter S. White pp 11860–11872 DOI: 10.1021/ic301770f

Heterometallic Tetranuclear [LnIII2CoIII2] Complexes Including Suppression of Quantum Tunneling of Magnetization in the [DyIII2CoIII2] Single Molecule Magnet Stuart K. Langley, Nicholas F. Chilton, Liviu Ungur, Boujemaa Moubaraki, Liviu F. Chibotaru, and Keith S. Murray pp 11873–11881 DOI: 10.1021/ic301784m

Photoinduced Ligand Exchange and Covalent DNA Binding by Two New Dirhodium Bis-Amidato Complexes Scott J. Burya, Alycia M. Palmer, Judith C. Gallucci, and Claudia Turro pp 11882–11890 DOI: 10.1021/ic3017886

(IP)2GaIII Complexes Facilitate Net Two-Electron Redox Transformations (IP = α-Iminopyridine) Chelsea D. Cates, Thomas W. Myers, and Louise A. Berben pp 11891–11897 DOI: 10.1021/ic301792w

Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)2(TFA)2 Tianning Diao, Paul White, Ilia Guzei, and Shannon S. Stahl pp 11898–11909 DOI: 10.1021/ic301799p

Substituent Exchange Reactions of Linear Oligomeric Aryloxyphosphazenes with Sodium 2,2,2-Trifluoroethoxide Xiao Liu, Jonathan P. Breon, Chen Chen, and Harry R. Allcock pp 11910–11916 DOI: 10.1021/ic301808v

Kinetic and Mechanistic Aspects of Atom Transfer Radical Addition (ATRA) Catalyzed by Copper Complexes with Tris(2-pyridylmethyl)amine William T. Eckenhoff, Ashley B. Biernesser, and Tomislav Pintauer pp 11917–11929 DOI: 10.1021/ic3018198

Syntheses, Structures, and Properties of New Manganese Carbonyls as Photoactive CO-Releasing Molecules: Design Strategies That Lead to CO Photolability in the Visible Region Margarita A. Gonzalez, Samantha J. Carrington, Nicole L. Fry, Jose L. Martinez, and Pradip K. Mascharak pp 11930–11940 DOI: 10.1021/ic3018216

Rare-Earth Metal Tris(trimethylsilylmethyl) Anionic Complexes Bearing One 1-Phenyl-2,3,4,5-tetrapropylcyclopentadienyl Ligand: Synthesis, Structural Characterization, and Application Ling Xu, Zitao Wang, Wen-Xiong Zhang, and Zhenfeng Xi pp 11941–11948 DOI: 10.1021/ic3018369

Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br) Jian Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric M. Villa, and Thomas E. Albrecht-Schmitt pp 11949–11954 DOI: 10.1021/ic301846g

Relationship between Oxygen Affinity and Autoxidation of Myoglobin Tomokazu Shibata, Daichi Matsumoto, Ryu Nishimura, Hulin Tai, Ariki Matsuoka, Satoshi Nagao, Takashi Matsuo, Shun Hirota, Kiyohiro Imai, Saburo Neya, Akihiro Suzuki, and Yasuhiko Yamamoto pp 11955–11960 DOI: 10.1021/ic301848t

Guanine Nucleobase Adducts Formed by [Pt(di-(2-picolyl)amine)Cl]Cl: Evidence That a Tridentate Ligand with Only in-Plane Bulk Can Slow Guanine Base Rotation Chase Andrepont, Patricia A. Marzilli, and Luigi G. Marzilli pp 11961–11970 DOI: 10.1021/ic3018634

A Palladium(II) Center Activates Nitrile Ligands toward 1,3-Dipolar Cycloaddition of Nitrones Substantially More than the Corresponding Platinum(II) Center Andreii S. Kritchenkov, Nadezhda A. Bokach, Galina L. Starova, and Vadim Yu. Kukushkin pp 11971–11979 DOI: 10.1021/ic301866y

Ca10Pt7Tt3 (Tt = Si, Ge): New Platinide Phases Featuring Electron-Rich 4c–6e Bonded [Pt7Tt3]20– Intermetalloid Clusters Isa Doverbratt, Siméon Ponou, Sven Lidin, and Daniel C. Fredrickson pp 11980–11985 DOI: 10.1021/ic301867q

Elucidating the Mechanism of the Halide-Induced Ligand Rearrangement Reaction Hyojong Yoo, Mari S. Rosen, Aaron M. Brown, Michael J. Wiester, Charlotte L. Stern, and Chad A. Mirkin pp 11986–11995 DOI: 10.1021/ic3018776

Coordinated Aqua vs Methanol Substitution Kinetics in fac-Re(I) Tricarbonyl Tropolonato Complexes Marietjie Schutte, Andreas Roodt, and Hendrik G. Visser pp 11996–12006 DOI: 10.1021/ic301891u

The Structure of MLn(hfbc)4 and a Key to High Circularly Polarized Luminescence Sebastiano Di Pietro and Lorenzo Di Bari pp 12007–12014 DOI: 10.1021/ic3018979

Synthesis and Biological Activity of Organoantimony(III)-Containing Heteropolytungstates Maria Barsukova-Stuckart, Luis F. Piedra-Garza, Bimersha Gautam, Gabriela Alfaro-Espinoza, Natalya V. Izarova, Abhishek Banerjee, Bassem S. Bassil, Matthias S. Ullrich, Hans J. Breunig, Cristian Silvestru, and Ulrich Kortz pp 12015–12022 DOI: 10.1021/ic301892s

Coordination Chemistry of N,N,N′,N′-Tetrakis(3,5-substituted benzyl-2-oxide)-2,2′-(ethylenedioxy)diethanamine Modified Group 4 Metal Alkoxides Timothy J. Boyle, Daniel T. Yonemoto, and Leigh Anna Steele , Joshua Farrell, Peter Renehan, and Taylor Huhta pp 12023–12031 DOI: 10.1021/ic3019327

Correlations and Differences between Uranium(VI) Arsonates and Phosphonates Pius O. Adelani, Laurent J. Jouffret, Jennifer E. S. Szymanowski, and Peter C. Burns pp 12032–12040 DOI: 10.1021/ic301942t

Influence of the Metal (Al, Cr, and Co) and the Substituents of the Porphyrin in Controlling the Reactions Involved in the Copolymerization of Propylene Oxide and Carbon Dioxide by Porphyrin Metal(III) Complexes. 2. Chromium Chemistry Chandrani Chatterjee and Malcolm H. Chisholm pp 12041–12052 DOI: 10.1021/ic302137w

Correction to Biologically Relevant Heterodinuclear Iron–Manganese Complexes Michaël Carboni, Martin Clémancey, Florian Molton, Jacques Pécaut, Colette Lebrun, Lionel Dubois, Geneviève Blondin, and J.-M. Latour pp 12053–12053 DOI: 10.1021/ic302144r

Correction to Crystallographic and Magnetic Phase Transitions in the Layered Ruthenium Oxyarsenides TbRuAsO and DyRuAsO Michael A. McGuire, Andrew F. May, and Brian C. Sales pp 12054–12054 DOI: 10.1021/ic302207h

Issue 22

Editorial for the Virtual Issue on Quantum Molecular Magnets Kim R. Dunbar pp 12055–12058 DOI: 10.1021/ic302312m

General One-Step Self-Assembly of Isostructural Intermetallic CoII3LnIII Cubane Aggregates Pei Wang, Santiranjan Shannigrahi, Nikolai L. Yakovlev, and T. S. Andy Hor pp 12059–12061 DOI: 10.1021/ic301527b

Bisulfite-Driven Autocatalysis in the Bromate–Thiosulfate Reaction in a Slightly Acidic Medium Zhen Wang, Qingyu Gao, Changwei Pan, Yuemin Zhao, and Attila K. Horváth pp 12062–12064 DOI: 10.1021/ic302019k

Photoluminescence Switching with Changes in the Coordination Number and Coordinating Volatile Organic Compounds in Tetracyanidonitridorhenium(V) and -technetium(V) Complexes Hayato Ikeda, Takashi Yoshimura, Akitaka Ito, Eri Sakuda, Noboru Kitamura, Tsutomu Takayama, Tsutomu Sekine, and Atsushi Shinohara pp 12065–12074 DOI: 10.1021/ic202243d

Synthesis and Structural Characterization of a Family of Modified Hafnium tert-Butoxide for Use as Precursors to Hafnia Nanoparticles Timothy J. Boyle, Leigh Anna M. Steele, Patrick D. Burton, Sarah M. Hoppe, Chelsea Lockhart, and Mark A. Rodriguez pp 12075–12092 DOI: 10.1021/ic300622h

New Dinuclear Cobalt(II) and Zinc(II) Complexes of a Carboxylate-Rich Dinucleating Ligand: Synthesis, Structure, Spectroscopic Characterization, and Their Interactions with Sugars Manindranath Bera, Ashley B. S. Curtiss, Ghezai T. Musie, and Douglas R. Powell pp 12093–12101 DOI: 10.1021/ic3004432

Ferrocene–Dithiolene Hybrids: Control of Strong Donor–Acceptor Electronic Communication to Reverse the Charge Transfer Direction Tetsuro Kusamoto, Kenji Takada, Ryota Sakamoto, Shoko Kume, and Hiroshi Nishihara pp 12102–12113 DOI: 10.1021/ic300581a

Cationic Iridium Complexes with Intramolecular π–π Interaction and Enhanced Steric Hindrance for Solid-State Light-Emitting Electrochemical Cells Hsiao-Fan Chen, Wen-Yi Hung, Shou-Wei Chen, Ting-Chih Wang, Shih-Wei Lin, Shu-Hua Chou, Chih-Teng Liao, Hai-Ching Su, Hsiao-An Pan, Pi-Tai Chou, Yi-Hung Liu, and Ken-Tsung Wong pp 12114–12121 DOI: 10.1021/ic300673k

Ligand Effects on the Oxidative Addition of Halogens to (dpp-nacnacR)Rh(phdi) David W. Shaffer, Scott A. Ryken, Ryan A. Zarkesh, and Alan F. Heyduk pp 12122–12131 DOI: 10.1021/ic300733j

Azadipyrromethene Dye Derivatives in Coordination Chemistry: the Structure–Property Relationship in Homoleptic Metal(II) Complexes André Bessette, Janaina G. Ferreira, Martin Giguère, Francis Bélanger, Denis Désilets, and Garry S. Hanan pp 12132–12141 DOI: 10.1021/ic300872m

Oxinobactin and Sulfoxinobactin, Abiotic Siderophore Analogues to Enterobactin Involving 8-Hydroxyquinoline Subunits: Thermodynamic and Structural Studies Amaury du Moulinet d’Hardemare, Gisèle Gellon, Christian Philouze, and Guy Serratrice pp 12142–12151 DOI: 10.1021/ic301081a

Dicyanogermylenes: A Tale of Isomers and Interconversions Ashwini Bundhun, Hassan H. Abdallah, Ponnadurai Ramasami, Peter P. Gaspar, and Henry F. Schaefer, III pp 12152–12164 DOI: 10.1021/ic301225w

Computational Differentiation of Brønsted Acidity Induced by Alkaline Earth or Rare Earth Cations in Zeolites Andrey A. Rybakov, Alexander V. Larin, and Georgy M. Zhidomirov pp 12165–12175 DOI: 10.1021/ic301279v

Series of Dicyanamide-Interlaced Assembly of Zinc-Schiff-Base Complexes: Crystal Structure and Photophysical and Thermal Studies Monami Maiti, Dipali Sadhukhan, Santarupa Thakurta, Syamantak Roy, Guillaume Pilet, Ray J. Butcher, Aline Nonat, Loïc J. Charbonnière, and Samiran Mitra pp 12176–12187 DOI: 10.1021/ic3012958

First Example of a Reversible Single-Crystal-to-Single-Crystal Polymerization–Depolymerization Accompanied by a Magnetic Anomaly for a Transition-Metal Complex with an Organic Radical Victor I. Ovcharenko, Sergey V. Fokin, Elvina T. Kostina, Galina V. Romanenko, Artem S. Bogomyakov, and Eugene V. Tretyakov pp 12188–12194 DOI: 10.1021/ic301328x

Spectroscopic Characterization of the Active FeIIIFeIII and FeIIIFeII Forms of a Purple Acid Phosphatase Model System Peter Comba, Lawrence R. Gahan, Valeriu Mereacre, Graeme R. Hanson, Annie K. Powell, Gerhard Schenk, and Marta Zajaczkowski-Fischer pp 12195–12209 DOI: 10.1021/ic301347t

Chiral Tripodal Ligand Containing Three N-Heterocyclic Donor Functions and Its Copper Complexes: Crystallization of [LCuI]22+/[L2CuII]2+ Stereoisomers and Tyrosinase Activity Aline Arnold, Christian Limberg, and Ramona Metzinger pp 12210–12217 DOI: 10.1021/ic301391s

Crystal Packing Effects on the Magnetic Slow Relaxation of Tb(III)-Nitronyl Nitroxide Radical Cyclic Dinuclear Clusters Fabrice Pointillart, Kevin Bernot, Giordano Poneti, and Roberta Sessoli pp 12218–12229 DOI: 10.1021/ic301394x

Synthesis, Crystal Structures, and Dual Donor Luminescence Sensitization in Novel Terbium Tetracyanoplatinates Philip A. Smith, Carlos Crawford, Nuquie Beedoe, Zerihun Assefa, and Richard E. Sykora pp 12230–12241 DOI: 10.1021/ic3013975

Organic Vapor Sorption in a High Surface Area Dysprosium(III)–Phosphine Oxide Coordination Material Ilich A. Ibarra, Ji Woong Yoon, Jong-San Chang, Su Kyoung Lee, Vincent M. Lynch, and Simon M. Humphrey pp 12242–12247 DOI: 10.1021/ic301415p

Synthesis and Structural Characterization of New Cu(I) Complexes with the Antithyroid Drug 6-n-Propyl-thiouracil. Study of the Cu(I)-Catalyzed Intermolecular Cycloaddition of Iodonium Ylides toward Benzo[b]furans with Pharmaceutical Implementations K. Paizanos, D. Charalampou, N. Kourkoumelis, D. Kalpogiannaki, L. Hadjiarapoglou, A. Spanopoulou, K. Lazarou, M. J. Manos, A. J. Tasiopoulos, M. Kubicki, and S. K. Hadjikakou pp 12248–12259 DOI: 10.1021/ic3014255

Complex Open-Framework Germanate Built by 8-Coordinated Ge10 Clusters Huijuan Yue, Maxim V. Peskov, Junliang Sun, and Xiaodong Zou pp 12260–12265 DOI: 10.1021/ic301449y

Synthesis and Reactivity of Nitrogen Nucleophiles-Induced Cage-Rearrangement Silsesquioxanes Thapakorn Jaroentomeechai, Pa-kwan Yingsukkamol, Chuttree Phurat, Ekasith Somsook, Tanakorn Osotchan, and Vuthichai Ervithayasuporn pp 12266–12272 DOI: 10.1021/ic3015145

Magnetic and Structural Studies of the Multifunctional Material SrFe0.75Mo0.25O3−δ M. Retuerto, M.-R. Li, Y. B. Go, A. Ignatov, M. Croft, K. V. Ramanujachary, J. Hadermann, J. P. Hodges, R. H. Herber, I. Nowik, and M. Greenblatt pp 12273–12280 DOI: 10.1021/ic301550m

Complex Cation Order in Anion-Deficient BanYFen-1O2.5n Perovskite Phases Kun Luo and Michael A. Hayward pp 12281–12287 DOI: 10.1021/ic3015628

Aqueous Uranium(VI) Complexes with Acetic and Succinic Acid: Speciation and Structure Revisited Christian Lucks, André Rossberg, Satoru Tsushima, Harald Foerstendorf, Andreas C. Scheinost, and Gert Bernhard pp 12288–12300 DOI: 10.1021/ic301565p

A Homologous Series of First-Row Transition-Metal Complexes of 2,2′-Bipyridine and their Ligand Radical Derivatives: Trends in Structure, Magnetism, and Bonding Mark Irwin, Laurence R. Doyle, Tobias Krämer, Radovan Herchel, John E. McGrady, and Jose M. Goicoechea pp 12301–12312 DOI: 10.1021/ic301587f

Symmetrical Hydrogen Bonds in Iridium(III) Alkoxides with Relevance to Outer Sphere Hydrogen Transfer Nathan D. Schley, Stéphanie Halbert, Christophe Raynaud, Odile Eisenstein, and Robert H. Crabtree pp 12313–12323 DOI: 10.1021/ic301601c

Zero-Field Splitting in a Series of Structurally Related Mononuclear NiII–Bispidine Complexes Mihail Atanasov, Peter Comba, Stefan Helmle, Dennis Müller, and Frank Neese pp 12324–12335 DOI: 10.1021/ic3016047

CsCoO2 Featuring a Novel Polyoxocobaltate(III) Anion Based on a Two-Dimensional Architecture of Interconnected Tetrahedra Naveed Zafar Ali, Jürgen Nuss, Reinhard K. Kremer, and Martin Jansen pp 12336–12342 DOI: 10.1021/ic301637w

Synthesis and Reactions of the First Room Temperature Stable Li/Cl Phosphinidenoid Complex Vitaly Nesterov, Gregor Schnakenburg, Arturo Espinosa, and Rainer Streubel pp 12343–12349 DOI: 10.1021/ic301652u

Syntheses, Structures, and Magnetic Properties of a Novel mer-[(bbp)FeIII(CN)3]2– Building Block (bbp: bis(2-benzimidazolyl)pyridine dianion) and Its Related Heterobimetallic Fe(III)–Ni(II) Complexes Anangamohan Panja, Philippe Guionneau, Ie-Rang Jeon, Stephen M. Holmes, Rodolphe Clérac, and Corine Mathonière pp 12350–12359 DOI: 10.1021/ic301661x

Infinite Copper(II) Coordination Architectures from a Resonative Aminotriazine-Derived Tripodal Ligand: Synthesis, Structures, and Magnetic Properties Meng-Jung Tsai, Jing-Yun Wu, Ming-Hsi Chiang, Cheng-Hao Huang, Ming-Yu Kuo, and Long-Li Lai pp 12360–12371 DOI: 10.1021/ic3016854

Reversible Rearrangements of Cu(II) Cage Complexes: Solvent and Anion Influences Paul V. Bernhardt, Helena Font, Carlos Gallego, Manuel Martínez, and Carlos Rodríguez pp 12372–12379 DOI: 10.1021/ic301696v

Stabilization of Hypophosphite in the Binding Pocket of a Dinuclear Macrocyclic Complex: Synthesis, Structure, and Properties of [Ni2L(μ-O2PH2)]BPh4 (L = N6S2 Donor Ligand) Jochen Lach, Alexander Jeremies, Vasile Lozan, Claudia Loose, Torsten Hahn, Jens Kortus, and Berthold Kersting pp 12380–12388 DOI: 10.1021/ic301710b

Luminescent Properties of Metal–Organic Framework MOF-5: Relativistic Time-Dependent Density Functional Theory Investigations Min Ji, Xin Lan, Zhenping Han, Ce Hao, and Jieshan Qiu pp 12389–12394 DOI: 10.1021/ic301771b

Mesityltellurenyl Cations Stabilized by Triphenylpnictogens [MesTe(EPh3)]+ (E = P, As, Sb) Jens Beckmann, Jens Bolsinger, Andrew Duthie, Pamela Finke, Enno Lork, Carsten Lüdtke, Ole Mallow, and Stefan Mebs pp 12395–12406 DOI: 10.1021/ic3017722

Differences in Nuclearity, Molecular Shapes, and Coordination Modes of Azide in the Complexes of Cd(II) and Hg(II) with a “Metalloligand” [CuL] (H2L = N,N′-Bis(salicylidene)-1,3-propanediamine): Characterization in Solid and in Solutions, and Theoretical Calculations Lakshmi Kanta Das, Ramakant M. Kadam, Antonio Bauzá, Antonio Frontera, and Ashutosh Ghosh pp 12407–12418 DOI: 10.1021/ic301773h

Probing the Role of Met221 in the Unusual Metallo-β-lactamase GOB-18 María-Natalia Lisa, Jorgelina Morán-Barrio, María-Fernanda Guindón, and Alejandro J. Vila pp 12419–12425 DOI: 10.1021/ic301801h

Development of a Gd(III)-Based Receptor-Induced Magnetization Enhancement (RIME) Contrast Agent for β-Glucuronidase Activity Profiling Shih-Hsien Chen, Yu-Ting Kuo, Gyan Singh, Tian-Lu Cheng, Yu-Zheng Su, Tzu-Pin Wang, Yen-Yu Chiu, Jui-Jen Lai, Chih-Ching Chang, Twei-Shiun Jaw, Shey-Cherng Tzou, Gin-Chung Liu, and Yun-Ming Wang pp 12426–12435 DOI: 10.1021/ic301827p

Lanthanide Complexes of the Kläui Metalloligand, CpCo(P═O(OR)2)3: An Examination of Ligand Exchange Kinetics between Isotopomers by Electrospray Mass Spectrometry Kevin J. H. Allen, Emma C. Nicholls-Allison, Kevin R. D. Johnson, Rajinder S. Nirwan, David J. Berg, Dennis Wester, and Brendan Twamley pp 12436–12443 DOI: 10.1021/ic301830u

1,8-Naphthyridine-Derived Ni2+/Cu2+-Selective Fluorescent Chemosensor with Different Charge Transfer Processses Zhanxian Li, Wanying Zhao, Xiaoya Li, Yanyan Zhu, Chunmei Liu, Lina Wang, Mingming Yu, Liuhe Wei, Mingsheng Tang, and Hongyan Zhang pp 12444–12449 DOI: 10.1021/ic3018453

New Insights into the Electronic Structure and Reactivity of One-Electron Oxidized Copper(II)-(Disalicylidene)diamine Complexes Kazutaka Asami, Kazuaki Tsukidate, Satoshi Iwatsuki, Fumito Tani, Satoru Karasawa, Linus Chiang, Tim Storr, Fabrice Thomas, and Yuichi Shimazaki pp 12450–12461 DOI: 10.1021/ic3018503

Cationic Zirconium Hydrides Supported by an NNNN-Type Macrocyclic Ligand: Synthesis, Structure, and Reactivity Heiko Kulinna, Thomas P. Spaniol, Laurent Maron, and Jun Okuda pp 12462–12472 DOI: 10.1021/ic301880z

Molecular Redox: Revisiting the Electronic Structures of the Group 9 Metallocorroles Joshua H. Palmer and Kyle M. Lancaster pp 12473–12482 DOI: 10.1021/ic3018826

Rational Design of Selective Organoruthenium Inhibitors of Protein Tyrosine Phosphatase 1B Jun Xiang Ong, Chun Wei Yap, and Wee Han Ang pp 12483–12492 DOI: 10.1021/ic301884j

Structural and Electronic Comparison of 1st Row Transition Metal Complexes of a Tripodal Iminopyridine Ligand Ashley M. McDaniel, Anthony K. Rappé, and Matthew P. Shores pp 12493–12502 DOI: 10.1021/ic301909u

Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by Unsymmetrical Aminoalcohol Ligands Takayuki Nakajima, Keiko Seto, Fumihiro Horikawa, Isao Shimizu, Andreas Scheurer, Bunsho Kure, Takashi Kajiwara, Tomoaki Tanase, and Masahiro Mikuriya pp 12503–12510 DOI: 10.1021/ic3019106

Luminescent Properties of Ruthenium(II) Complexes with Sterically Expansive Ligands Bound to DNA Defects Anna J. McConnell, Mi Hee Lim, Eric D. Olmon, Hang Song, Elizabeth E. Dervan, and Jacqueline K. Barton pp 12511–12520 DOI: 10.1021/ic3019524

A Nine-Coordinated Bismuth(III) Complex Derived from Pentadentate 2,6-Diacetylpyridine Bis(4N-methylthiosemicarbazone): Crystal Structure and Both in Vitro and in Vivo Biological Evaluation Ming-Xue Li, Min Yang, Jing-Yang Niu, Li-Zhi Zhang, and Song-Qiang Xie pp 12521–12526 DOI: 10.1021/ic301959z

Pyrrole-Based New Diphosphines: Pd and Ni Complexes Bearing the PNP Pincer Ligand Shanish Kumar, Ganesan Mani, Sukanta Mondal, and Pratim Kumar Chattaraj pp 12527–12539 DOI: 10.1021/ic301967r

Copper Phosphonatoethanesulfonates: Temperature Dependent in Situ Energy Dispersive X-ray Diffraction Study and Influence of the pH on the Crystal Structures Mark Feyand, Annika Hübner, André Rothkirch, David S. Wragg, and Norbert Stock pp 12540–12547 DOI: 10.1021/ic301976s

Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. 12. New Heteropentanuclear Complexes Carrying Four Exocyclic Cis-platin-like Functionalities as Potential Bimodal (PDT/Cis-platin) Anticancer Agents Maria Pia Donzello, Elisa Viola, Claudio Ercolani, Zhen Fu, David Futur, and Karl M. Kadish pp 12548–12559 DOI: 10.1021/ic301989a

Panchromic Cationic Iridium(III) Complexes Kamrul Hasan and Eli Zysman-Colman pp 12560–12564 DOI: 10.1021/ic301998t

Rational Design of Single-Ion Magnets and Spin Qubits Based on Mononuclear Lanthanoid Complexes José J. Baldoví, Salvador Cardona-Serra, Juan M. Clemente-Juan, Eugenio Coronado, Alejandro Gaita-Ariño, and Andrew Palii pp 12565–12574 DOI: 10.1021/ic302068c

H2azapa: a Versatile Acyclic Multifunctional Chelator for 67Ga, 64Cu, 111In, and 177Lu Gwendolyn A. Bailey, Eric W. Price, Brian M. Zeglis, Cara L. Ferreira, Eszter Boros, Michael J. Lacasse, Brian O. Patrick, Jason S. Lewis, Michael J. Adam, and Chris Orvig pp 12575–12589 DOI: 10.1021/ic302225z

Issue 23

A Naked-Eye On–Off–On Molecular “Light Switch” Based on a Reversible “Conformational Switch” of G-Quadruplex DNA Jun-Liang Yao, Xing Gao, Wenliang Sun, Xue-Zhong Fan, Shuo Shi, and Tian-Ming Yao pp 12591–12593 DOI: 10.1021/ic301305q

Photoinduced Reactions between Pb3O4 and Organic Dyes in Aqueous Solution under Visible Light Yangen Zhou, Jinlin Long, Quan Gu, Huaxiang Lin, Huan Lin, and Xuxu Wang pp 12594–12596 DOI: 10.1021/ic301723m

Binding of EuIII to 1,2-Hydroxypyridinone-Modified Peptide Nucleic Acids Arnie R. de Leon, Abiola O. Olatunde, Janet R. Morrow, and Catalina Achim pp 12597–12599 DOI: 10.1021/ic301790v

Biomimetic Catalysis of a Porous Iron-Based Metal–Metalloporphyrin Framework Yao Chen, Tran Hoang, and Shengqian Ma pp 12600–12602 DOI: 10.1021/ic301923x

Coordination Chemistry and Reactivity of a Cupric Hydroperoxide Species Featuring a Proximal H-Bonding Substituent Sunghee Kim, Claudio Saracini, Maxime A. Siegler, Natalia Drichko, and Kenneth D. Karlin pp 12603–12605 DOI: 10.1021/ic302071e

Coordination Effects on Electron Distributions for Rhodium Complexes of the Redox-Active Bis(3,5-di-tert-butyl-2-phenolate)amide Ligand Géza Szigethy, David W. Shaffer, and Alan F. Heyduk pp 12606–12618 DOI: 10.1021/ic2026076

Probing High-Pressure Phase Transitions in Ti-Based Perovskite-Type Ferroelectrics Using Visible Resonance Raman Spectroscopy Guillaume Fraysse, Jérôme Rouquette, Julien Haines, Véronique Bornand, Philippe Papet, and Altaïr Soria Pereira pp 12619–12625 DOI: 10.1021/ic300381r

Synthesis and Crystal Structure of Cubic Ca16Si17N34 Sandra M. Hick, Mattheu I. Miller, Richard B. Kaner, and Richard G. Blair pp 12626–12629 DOI: 10.1021/ic300627q

Role of Fe–N–C Geometry Flip-Flop in Bistability in Fe(tetrazol-2-yl)4(C2H5CN)2-Type Core Based Coordination Network Agata Białońska and Robert Bronisz pp 12630–12637 DOI: 10.1021/ic300880w

New Insights into Formation of Trivalent Actinides Complexes with DTPA Sébastien Leguay, Thomas Vercouter, Sylvain Topin, Jean Aupiais, Dominique Guillaumont, Manuel Miguirditchian, Philippe Moisy, and Claire Le Naour pp 12638–12649 DOI: 10.1021/ic3011019

Rotational Rehybridization and the High Temperature Phase of UC2 Xiao-Dong Wen, Sven P. Rudin, Enrique R. Batista, David L. Clark, Gustavo E. Scuseria, and Richard L. Martin pp 12650–12659 DOI: 10.1021/ic301133m

Tris(carbene)borate Ligands Featuring Imidazole-2-ylidene, Benzimidazol-2-ylidene, and 1,3,4-Triazol-2-ylidene Donors. Evaluation of Donor Properties in Four-Coordinate {NiNO}10 Complexes Salvador B. Muñoz, III, Wallace K. Foster, Hsiu-Jung Lin, Charles G. Margarit, Diane A. Dickie, and Jeremy M. Smith pp 12660–12668 DOI: 10.1021/ic301204b

Pteridine Cleavage Facilitates DNA Photocleavage by Ru(II) Polypyridyl Compounds Benjamin R. Williams, Shannon R. Dalton, Meredith Skiba, Sung Eun Kim, Allison Shatz, Patrick J. Carroll, and Sharon J. Nieter Burgmayer pp 12669–12681 DOI: 10.1021/ic301219z

Formation of P–C Bond through Reductive Coupling between Bridging Phosphido and Benzoquinolinate Groups. Isolation of Complexes of the Pt(II)/Pt(IV)/Pt(II) Sequence Andersson Arias, Juan Forniés, Consuelo Fortuño, and Antonio Martín , Mario Latronico, Piero Mastrorilli, Stefano Todisco, and Vito Gallo pp 12682–12696 DOI: 10.1021/ic301298p

Design and Synthesis of a Luminescent Cyclometalated Iridium(III) Complex Having N,N-Diethylamino Group that Stains Acidic Intracellular Organelles and Induces Cell Death by Photoirradiation Shinsuke Moromizato, Yosuke Hisamatsu, Toshihiro Suzuki, Yasuki Matsuo, Ryo Abe, and Shin Aoki pp 12697–12706 DOI: 10.1021/ic301310q

Structural and Spectroscopic Trends in a Series of Half-Sandwich Scorpionate Complexes Shengwen Liang, Haoshuang Wang, Tapash Deb, Jeffrey L. Petersen, Gordon T. Yee, and Michael P. Jensen pp 12707–12719 DOI: 10.1021/ic301409s

Electronic Communication Across Diamagnetic Metal Bridges: A Homoleptic Gallium(III) Complex of a Redox-Active Diarylamido-Based Ligand and Its Oxidized Derivatives Brendan J. Liddle, Sarath Wanniarachchi, Jeewantha S. Hewage, Sergey V. Lindeman, Brian Bennett, and James R. Gardinier pp 12720–12728 DOI: 10.1021/ic301437f

Spectroscopic and Computational Studies of a Small-Molecule Functional Mimic of Iron Superoxide Dismutase, Iron 2,6-Diacetylpyridinebis(semioxamazide) Craig T. Gutman and Thomas C. Brunold pp 12729–12737 DOI: 10.1021/ic301547z

Diimine Triscarbonyl Re(I) of Isomeric Pyridyl-fulvene Ligands: an Electrochemical, Spectroscopic, and Computational Investigation Daniel Chartrand, Carlos A. Castro Ruiz, and Garry S. Hanan pp 12738–12747 DOI: 10.1021/ic301559s

Hexagonally Ordered KLaF4 Host: Phase-Controlled Synthesis and Luminescence Studies Shahzad Ahmad, G. Vijaya Prakash, and R. Nagarajan pp 12748–12754 DOI: 10.1021/ic301566e

Mixed-Valence Heptanuclear Iron Complexes with Ferromagnetic Interaction Ivan Šalitroš, Roman Boča, Radovan Herchel, Ján Moncol, Ivan Nemec, Mario Ruben, and Franz Renz pp 12755–12767 DOI: 10.1021/ic3015833

Roles of Acetone and Diacetone Alcohol in Coordination and Dissociation Reactions of Uranyl Complexes Daniel Rios, George Schoendorff, Michael J. Van Stipdonk, Mark S. Gordon, Theresa L. Windus, John K. Gibson, and Wibe A. de Jong pp 12768–12775 DOI: 10.1021/ic3015964

Luminescent Rhenium and Ruthenium Complexes of an Amphoteric Poly(amidoamine) Functionalized with 1,10-Phenanthroline Daniela Maggioni, Fabio Fenili, Laura D’Alfonso, Daniela Donghi, Monica Panigati, Ivan Zanoni, Roberta Marzi, Amedea Manfredi, Paolo Ferruti, Giuseppe D’Alfonso, and Elisabetta Ranucci pp 12776–12788 DOI: 10.1021/ic301616b

Nickel(II) Complexes Containing a Pyrrole–Diphosphine Pincer Ligand Gopaladasu T. Venkanna, Teresa Virginia M. Ramos, Hadi D. Arman, and Zachary J. Tonzetich pp 12789–12795 DOI: 10.1021/ic301633q

Reversible Double Oxidation and Protonation of the Non-Innocent Bridge in a Nickel(II) Salophen Complex David de Bellefeuille, Mohammad S. Askari, Benedikt Lassalle-Kaiser, Yves Journaux, Ally Aukauloo, Maylis Orio, Fabrice Thomas, and Xavier Ottenwaelder pp 12796–12804 DOI: 10.1021/ic301684h

Outer-Sphere Coordination Chemistry: Amido-Ammonium Ligands as Highly Selective Tetrachloridozinc(II)ate Extractants Jennifer R. Turkington, Violina Cocalia, Katrina Kendall, Carole A. Morrison, Patricia Richardson, Thomas Sassi, Peter A. Tasker, Philip J. Bailey, and Kathryn C. Sole pp 12805–12819 DOI: 10.1021/ic301691d

Synthesis, Characterization, MCD Spectroscopy, and TD-DFT Calculations of Copper-Metalated Nonperipherally Substituted Octaoctyl Derivatives of Tetrabenzotriazaporphyrin, cis- and trans-Tetrabenzodiazaporphyrin, Tetrabenzomonoazaporphyrin, and Tetrabenzoporphyrin John Mack, Lydia Sosa-Vargas, Simon J. Coles, Graham J. Tizzard, Isabelle Chambrier, Andrew N. Cammidge, Michael J. Cook, and Nagao Kobayashi pp 12820–12833 DOI: 10.1021/ic301712h

Calix[4]arenes of Aluminum and Gallium with Benzimidazolyl Ligands: Steric Control of the Conformation via Substitution on the Ligand Ernesto Rufino-Felipe, Miguel-Ángel Muñoz-Hernández, Hugo F. Saucedo-Azpeitia, and Sara A. Cortes-Llamas pp 12834–12840 DOI: 10.1021/ic301718m

Phosphorus–Nitrogen Compounds. Part 24. Syntheses, Crystal Structures, Spectroscopic and Stereogenic Properties, Biological Activities, and DNA Interactions of Novel Spiro-ansa-spiro- and Ansa-spiro-ansa-cyclotetraphosphazenes Gamze Elmas (nee Egemen), Aytuğ Okumuş, Zeynel Kılıç, Tuncer Hökelek, Leyla Açık, Hakan Dal, Nagehan Ramazanoğlu, and L.Yasemin Koç pp 12841–12856 DOI: 10.1021/ic3017134

Structure and Redox Behavior of Iron Oxophlorin and Role of Electron Transfer in the Heme Degradation Process Mahin Gheidi, Nasser Safari, and Mansour Zahedi pp 12857–12866 DOI: 10.1021/ic3017497

Synthesis and Characterization of the Europium(III) Pentakis(picrate) Complexes with Imidazolium Countercations: Structural and Photoluminescence Study Alex S. Borges, José Diogo L. Dutra, Ricardo O. Freire, Renaldo T. Moura, Jr., Jeferson G. Da Silva, Oscar L. Malta, Maria Helena Araujo, and Hermi F. Brito pp 12867–12878 DOI: 10.1021/ic301776n

Free Base and Metal Complexes of 5,15-Diaza-10,20-dimesitylporphyrins: Synthesis, Structures, Optical and Electrochemical Properties, and Aromaticities Yoshihiro Matano, Tarou Shibano, Haruyuki Nakano, Yoshifumi Kimura, and Hiroshi Imahori pp 12879–12890 DOI: 10.1021/ic301835c

Iron–Amide–Sulfide and Iron–Imide–Sulfide Clusters: Heteroligated Core Environments Relevant to the Nitrogenase FeMo Cofactor Xu-Dong Chen, Wei Zhang, Jeremiah S. Duncan, and Sonny C. Lee pp 12891–12904 DOI: 10.1021/ic301868m

Donor–Acceptor Complexation and Dehydrogenation Chemistry of Aminoboranes Adam C. Malcolm, Kyle J. Sabourin, Robert McDonald, Michael J. Ferguson, and Eric Rivard pp 12905–12916 DOI: 10.1021/ic3018997

Hetero-multinuclear Ruthenium(III)/Platinum(II) Complexes That Potentially Exhibit Both Antimetastatic and Antineoplastic Properties Craig M. Anderson, Isabelle R. Taylor, Michael F. Tibbetts, Jessica Philpott, Yongfeng Hu, and Joseph M. Tanski pp 12917–12924 DOI: 10.1021/ic301981s

LaSr3F5(CN2)2: A Prototype Structure for Mixed-Valent Eu4F5(CN2)2 Leonid Unverfehrt, Markus Ströbele, and H.-Jürgen Meyer pp 12925–12928 DOI: 10.1021/ic302039q

Spontaneous Redox Synthesis of the Charge Transfer Material TTF4[SVMo11O40] Qi Li, Jinzhen Lu, John F. Boas, Daouda A. K. Traore, Matthew C. J. Wilce, Fuzhi Huang, Lisandra L. Martin, Tadaharu Ueda, and Alan M. Bond pp 12929–12937 DOI: 10.1021/ic302045m

Dynamic Magnetic Materials Based on the Cationic Coordination Polymer [Cu(btix)2]n2n+ [btix = 1,4-Bis(triazol-1-ylmethyl)benzene]: Tuning the Structural and Magnetic Properties through Anion Exchange Eugenio Coronado, Mónica Giménez-Marqués, Carlos J. Gómez-García, and Guillermo Mínguez Espallargas pp 12938–12947 DOI: 10.1021/ic302066e

Cobalt Alkyl Complexes of a New Family of Chiral 1,3-Bis(2-pyridylimino)isoindolates and Their Application in Asymmetric Hydrosilylation Désirée C. Sauer, Hubert Wadepohl, and Lutz H. Gade pp 12948–12958 DOI: 10.1021/ic3020749

Reactivity of Diphenylpropynone Derivatives Toward Metal-Associated Amyloid-β Species Amit S. Pithadia, Akiko Kochi, Molly T. Soper, Michael W. Beck, Yuzhong Liu, Sanghyun Lee, Alaina S. DeToma, Brandon T. Ruotolo, and Mi Hee Lim pp 12959–12967 DOI: 10.1021/ic302084g

Supramolecular Rotators of (Aniliniums)([18]crown-6) in Electrically Conducting [Ni(dmit)2] Crystals Norihisa Hoshino, Yuuya Yoshii, Masaki Aonuma, Kazuya Kubo, Takayoshi Nakamura, and Tomoyuki Akutagawa pp 12968–12975 DOI: 10.1021/ic302093b

Reaction of 13-Vertex Carborane μ-1,2-(CH2)3-1,2-C2B11H11 with Nucleophiles: Scope and Mechanism Jian Zhang and Zuowei Xie pp 12976–12987 DOI: 10.1021/ic3020964

Copper Coordination to Native N-Terminally Modified versus Full-Length Amyloid-β: Second-Sphere Effects Determine the Species Present at Physiological pH Bruno Alies, Christian Bijani, Stéphanie Sayen, Emmanuel Guillon, Peter Faller, and Christelle Hureau pp 12988–13000 DOI: 10.1021/ic302097d

Efficient [WO4]2–-Catalyzed Chemical Fixation of Carbon Dioxide with 2-Aminobenzonitriles to Quinazoline-2,4(1H,3H)-diones Toshihiro Kimura, Hanako Sunaba, Keigo Kamata, and Noritaka Mizuno pp 13001–13008 DOI: 10.1021/ic302110a

A Family of Binuclear Dysprosium(III) Radical Compounds with Magnetic Relaxation in ON and OFF States Tian Han, Wei Shi, Xiao-Ping Zhang, Lei-Lei Li, and Peng Cheng pp 13009–13016 DOI: 10.1021/ic3021244

Interaction of In(I) and Tl(I) Cations with 2,6-Diaryl Pyridine Ligands: Cation Encapsulation within a Very Weakly Interacting N/Arene Host Environment Hassanatu B. Mansaray, Christina Y. Tang, Dragoslav Vidovic, Amber L. Thompson, and Simon Aldridge pp 13017–13022 DOI: 10.1021/ic3021386

Metal and Alloy Nanoparticles by Amine-Borane Reduction of Metal Salts by Solid-Phase Synthesis: Atom Economy and Green Process Udishnu Sanyal and Balaji R. Jagirdar pp 13023–13033 DOI: 10.1021/ic3021436

Diverse Reactions of PhI(OTf)2 with Common 2-Electron Ligands: Complex Formation, Oxidation, and Oxidative Coupling Thomas P. Pell, Shannon A. Couchman, Sara Ibrahim, David J. D. Wilson, Brian J. Smith, Peter J. Barnard, and Jason L. Dutton pp 13034–13040 DOI: 10.1021/ic302176f

Mechanism of CO Displacement from an Unusually Labile Rhenium Complex: An Experimental and Theoretical Investigation Sohail Muhammad, Veeranna Yempally, Muhammad Anas, Salvador Moncho, Samuel J. Kyran, Edward N. Brothers, Donald J. Darensbourg, and Ashfaq A. Bengali pp 13041–13049 DOI: 10.1021/ic302182b

Monomeric Group 13 Metal(I) Amides: Enforcing One-Coordination Through Extreme Ligand Steric Bulk Deepak Dange, Jiaye Li, Christian Schenk, Hansgeorg Schnöckel, and Cameron Jones pp 13050–13059 DOI: 10.1021/ic3022613

Drastic Differences between the Local and the Average Structures of Sr2MSbO5.5 (M = Ca, Sr, Ba) Oxygen-Deficient Double Perovskites Graham King, Kyle J. Thomas, and Anna Llobet pp 13060–13068 DOI: 10.1021/ic302310y

Issue 24

Happy Trails! Rich Eisenberg pp 13069–13071 DOI: 10.1021/ic302224v

Self-Assembly of an Octanuclear Platinum(II) Tetragonal Prism from a New PtII4 Organometallic Star-Shaped Acceptor and Its Nitroaromatic Sensing Study Sankarasekaran Shanmugaraju, Harshal Jadhav, Yogesh P. Patil, and Partha Sarathi Mukherjee pp 13072–13074 DOI: 10.1021/ic301716y

Rosamine-Based Fluorescent Sensor with Femtomolar Affinity for the Reversible Detection of a Mercury Ion Masayasu Taki, Kazushi Akaoka, Shohei Iyoshi, and Yukio Yamamoto pp 13075–13077 DOI: 10.1021/ic301822r

Fast Detection of Water and Organic Molecules by a Change of Color in an Iron(II) Microporous Spin-Crossover Coordination Polymer Francisco J. Muñoz-Lara, Ana B. Gaspar, M. Carmen Muñoz, Andrey B. Lysenko, Konstantin V. Domasevitch, and José Antonio Real pp 13078–13080 DOI: 10.1021/ic302287w

Reduced and Oxidized Forms of the Pt-Organometallic Version of Polyaniline Tommy Kenny, Simon Lamare, Shawkat M. Aly, Daniel Fortin, Gessie Brisard, and Pierre D. Harvey pp 13081–13095 DOI: 10.1021/ic300775n

Selective Synthesis, Isolation, and Crystallographic Characterization of LaSc2N@Ih-C80 Steven Stevenson, Coralie B. Rose, Juliya S. Maslenikova, Jimmy R. Villarreal, Mary A. Mackey, Brandon Q. Mercado, Kelly Chen, Marilyn M. Olmstead, and Alan L. Balch pp 13096–13102 DOI: 10.1021/ic300888e

Turn-On Luminescent Sensing of Metal Cations via Quencher Displacement: Rational Design of a Highly Selective Chemosensor for Chromium(III) Jia-Ni Wang, Qiong Qi, Lei Zhang, and Shun-Hua Li pp 13103–13107 DOI: 10.1021/ic3009267

Fine Hierarchy of the V–O Bonds by Advanced Solid State NMR: Novel Pb4(VO2)(PO4)3 Structure as a Textbook Case Grégory Tricot, Olivier Mentré, Sylvain Cristol, and Laurent Delevoye pp 13108–13113 DOI: 10.1021/ic300966r

Efficient Förster Resonance Energy Transfer in 1,2,3-Triazole Linked BODIPY-Zn(II) Meso-tetraphenylporphyrin Donor–Acceptor Arrays Matthew J. Leonardi, Michael R. Topka, and Peter H. Dinolfo pp 13114–13122 DOI: 10.1021/ic301170a

A Bis(ferrocenyl)phenanthroline Iridium(III) Complex as a Lab-on-a-Molecule for Cyanide and Fluoride in Aqueous Solution Qinghai Shu, Lars Birlenbach, and Michael Schmittel pp 13123–13127 DOI: 10.1021/ic301256g

Visible and NIR Photoluminescence Properties of a Series of Novel Lanthanide–Organic Coordination Polymers Based on Hydroxyquinoline–Carboxylate Ligands Yan-Li Gai, Ke-Cai Xiong, Lian Chen, Yang Bu, Xing-Jun Li, Fei-Long Jiang, and Mao-Chun Hong pp 13128–13137 DOI: 10.1021/ic301261g

Molybdenum(VI) Coordination Chemistry of the N,N-Disubstituted Bis(hydroxylamido)-1,3,5-triazine Ligand, H2bihyat. Water-Assisted Activation of the MoVI═O Bond and Reversible Dimerization of cis-[MoVIO2(bihyat)] to [MoVI2O4(bihyat)2(H2O)2] Marios Stylianou, Vladimiros A. Nikolakis, George I. Chilas, Tamas Jakusch, Tiverios Vaimakis, Tamas Kiss, Michael P. Sigalas, Anastasios D. Keramidas, and Themistoklis A. Kabanos pp 13138–13147 DOI: 10.1021/ic301282q

Modeling Tyrosinase and Catecholase Activity Using New m-Xylyl-Based Ligands with Bidentate Alkylamine Terminal Coordination Sukanta Mandal, Jhumpa Mukherjee, Francesc Lloret, and Rabindranath Mukherjee pp 13148–13161 DOI: 10.1021/ic3013848

Synthesis and Reactivity of Nickel Hydride Complexes of an α-Diimine Ligand Qingsong Dong, Yanxia Zhao, Yuanting Su, Ji-Hu Su, Biao Wu, and Xiao-Juan Yang pp 13162–13170 DOI: 10.1021/ic301392p

Mn4 Single-Molecule-Magnet-Based Polymers of a One-Dimensional Helical Chain and a Three-Dimensional Network: Syntheses, Crystal Structures, and Magnetic Properties Hui-Lien Tsai, Chen-I Yang, Wolfgang Wernsdorfer, Siang-Hua Huang, Siang-Yu Jhan, Ming-Hsuan Liu, and Gene-Hsiang Lee pp 13171–13180 DOI: 10.1021/ic3014333

Ultrafast Intramolecular Charge Separation in a Donor–Acceptor Assembly Comprising Bis(η5-cyclopentadienyl)molybdenum Coordinated to an Ene-1,2-dithiolate-naphthalenetetracarboxylicdiimide Ligand Adam J. Taylor, E. Stephen Davies, Julia A. Weinstein, Igor V. Sazanovich, Oleg V. Bouganov, Sergei A. Tikhomirov, Michael Towrie, Jonathan McMaster, and C. David Garner pp 13181–13194 DOI: 10.1021/ic301436t

Ligand Bond Energies in cis- and trans-[L-Pd(PH3)2Cl]+ Complexes from Coupled Cluster Theory (CCSD(T)) and Density Functional Theory Mingyang Chen, Raluca Craciun, Norris Hoffman, and David A. Dixon pp 13195–13203 DOI: 10.1021/ic3014392

Homoleptic Lanthanide 1,2,3-Triazolates ∞2–3[Ln(Tz*)3] and Their Diversified Photoluminescence Properties J.-Christoph Rybak, Larissa V. Meyer, Julian Wagenhöfer, Gerhard Sextl, and Klaus Müller-Buschbaum pp 13204–13213 DOI: 10.1021/ic301482e

Polyoxopalladates Encapsulating 8-Coordinated Metal Ions, [MO8PdII12L8]n− (M = Sc3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Lu3+; L = PhAsO32–, PhPO32–, SeO32–) Maria Barsukova-Stuckart, Natalya V. Izarova, Ryan A. Barrett, Zhenxing Wang, Johan van Tol, Harold W. Kroto, Naresh S. Dalal, Pablo Jiménez-Lozano, Jorge J. Carbó, Josep M. Poblet, Marc S. von Gernler, Thomas Drewello, Pedro de Oliveira, Bineta Keita, and Ulrich Kortz pp 13214–13228 DOI: 10.1021/ic301537n

New Insights on the Incorporation of Lanthanide Ions into Nanosized Layered Double Hydroxides Tamara Posati, Ferdinando Costantino, Loredana Latterini, Morena Nocchetti, Marco Paolantoni, and Luigi Tarpani pp 13229–13236 DOI: 10.1021/ic301584g

Does Local Disorder Occur in the Pyrochlore Zirconates? Peter E.R. Blanchard, Richard Clements, Brendan J. Kennedy, Chris D. Ling, and Emily Reynolds , Max Avdeev, Anton P.J. Stampfl, and Zhaoming Zhang , Ling-Yun Jang pp 13237–13244 DOI: 10.1021/ic301677b

The Effect of A-Site Substitution of Ce and La on the Magnetic and Electronic Properties of Sr(Ti0.6Fe0.4)O3−δ Films Peng Jiang, Lei Bi, Xueyin Sun, Dong Hun Kim, Daming Jiang, Gaohui Wu, G. F. Dionne, and C. A. Ross pp 13245–13253 DOI: 10.1021/ic301726w

Solid-State and Solution-State Coordination Chemistry of Lanthanide(III) Complexes with α-Hydroxyisobutyric Acid Xiao-Yan Chen, George S. Goff, William C. Ewing, Brian L. Scott, and Wolfgang Runde pp 13254–13263 DOI: 10.1021/ic301775d

Two Bulky-Decorated Triangular Dysprosium Aggregates Conserving Vortex-Spin Structure Shufang Xue, Xiao-Hua Chen, Lang Zhao, Yun-Nan Guo, and Jinkui Tang pp 13264–13270 DOI: 10.1021/ic301785v

Hydrothermal Synthesis and Spectroscopic Properties of a New Glaserite Material, K3RE(VO4)2 (RE = Sc, Y, Dy, Ho, Er, Yb, Lu, or Tm) with Potential Lasing and Optical Properties Martin M. Kimani, Lindsey Thompson, Whitney Snider, Colin D. McMillen, and Joseph W. Kolis pp 13271–13280 DOI: 10.1021/ic301922e

Direct Synthesis of Bimetallic Pd3Ag Nanoalloys from Bulk Pd3Ag Alloy Chi-Kai Lin, Yan-Gu Lin, Tianpin Wu, Heather M. Barkholtz, Qiyin Lin, Haojuan Wei, Dale L. Brewe, Jeffrey T. Miller, Di-Jia Liu, Yang Ren, Yasuo Ito, and Tao Xu pp 13281–13288 DOI: 10.1021/ic301940g

Emissive Behavior, Cytotoxic Activity, Cellular Uptake, and PEGylation Properties of New Luminescent Rhenium(I) Polypyridine Poly(ethylene glycol) Complexes Alex Wing-Tat Choi, Man-Wai Louie, Steve Po-Yam Li, Hua-Wei Liu, Bruce Ting-Ngok Chan, Tonlex Chun-Ying Lam, Alex Chun-Chi Lin, Shuk-Han Cheng, and Kenneth Kam-Wing Lo pp 13289–13302 DOI: 10.1021/ic301948d

Oxidation of Glutathione by Hexachloroiridate(IV), Dicyanobis(bipyridine)iron(III), and Tetracyano(bipyridine)iron(III) Nootan Bhattarai and David M. Stanbury pp 13303–13311 DOI: 10.1021/ic301955y

Cyclometalated Ruthenium Oligomers with 2,3-Di(2-pyridyl)-5,6-diphenylpyrazine: A Combined Experimental, Computational, and Comparison Study with Noncyclometalated Analogous Si-Hai Wu, Stephen E. Burkhardt, Yu-Wu Zhong, and Héctor D. Abruña pp 13312–13320 DOI: 10.1021/ic3019666

Why Are SnN4 (n = 1–4) Species “Missing”? Answers in a Broader Theoretical Context of Binary S–N Compounds Guo-Hua Zhang, Yong-Fang Zhao, Judy I. Wu, and Paul v. R. Schleyer pp 13321–13327 DOI: 10.1021/ic3020095

Multinary Selenides with Unusual Coordination Environment of Bismuth Ming-Yan Chung and Chi-Shen Lee pp 13328–13333 DOI: 10.1021/ic302027b

Carbon Monoxide, Isocyanide, and Nitrile Complexes of Cationic, d0 Vanadium Bisimides: π-Back Bonding Derived from the π Symmetry, Bonding Metal Bisimido Ligand Orbitals Henry S. La Pierre, John Arnold, Robert G. Bergman, and F. Dean Toste pp 13334–13344 DOI: 10.1021/ic302044q

Ca11E3C8 (E = Sn, Pb): New Complex Carbide Zintl Phases Grown from Ca/Li Flux Trevor V. Blankenship, Adrian Lita, and Susan E. Latturner pp 13345–13350 DOI: 10.1021/ic3020833

Model Iron–Oxo Species and the Oxidation of Imidazole: Insights into the Mechanism of OvoA and EgtB? Eric A. C. Bushnell, Grant B. Fortowsky, and James W. Gauld pp 13351–13356 DOI: 10.1021/ic3021172

Ionothermal Synthesis of Four New Nickel Thiophosphate Anions: [Ni(P2S8)2]2–, [Ni(P3S9)(P2S8)]3–, [Ni(P3S9)2]4–, and [(NiP3S8)4(PS4)]7– Jason A. Cody, Kenneth B. Finch, Gilbert J. Reynders, III, Grant C. B. Alexander, Hyung G. Lim, Christian Näther, and Wolfgang Bensch pp 13357–13362 DOI: 10.1021/ic302112g

A New Series of Chiral Metal Formate Frameworks of [HONH3][MII(HCOO)3] (M = Mn, Co, Ni, Zn, and Mg): Synthesis, Structures, and Properties Bin Liu, Ran Shang, Ke-Li Hu, Zhe-Ming Wang, and Song Gao pp 13363–13372 DOI: 10.1021/ic302129m

l- and d-[Ln(HCO2)(SO4)(H2O)]n (Ln = La, Ce, Pr, Nd, and Eu): Chiral Enantiomerically 3D Architectures Constructed by Double −[Ln–O]n– Helices Weiwei Ju, Deng Zhang, Dunru Zhu, and Yan Xu pp 13373–13379 DOI: 10.1021/ic302134m

Synthesis and Characterization of Multi-Alkali-Metal Tetraphenolates and Application in Ring-Opening Polymerization of Lactide Jinjin Zhang, Chunli Jian, Yuan Gao, Lei Wang, Ning Tang, and Jincai Wu pp 13380–13389 DOI: 10.1021/ic302193y

Ba2An(S2)2S2 (An = U, Th): Syntheses, Structures, Optical, and Electronic Properties Adel Mesbah, Emilie Ringe, Sébastien Lebègue, Richard P. Van Duyne, and James A. Ibers pp 13390–13395 DOI: 10.1021/ic302223m

Speciation of La(III) Chloride Complexes in Water and Acetonitrile: A Density Functional Study Michael Bühl, Nicolas Sieffert, Aurélie Partouche, Alain Chaumont, and Georges Wipff pp 13396–13407 DOI: 10.1021/ic302255a

Three-Coordinate Beryllium β-Diketiminates: Synthesis and Reduction Chemistry Merle Arrowsmith, Michael S. Hill, Gabriele Kociok-Köhn, Dugald J. MacDougall, Mary F. Mahon, and Ian Mallov pp 13408–13418 DOI: 10.1021/ic3022968

Solution Structure of Ln(III) Complexes with Macrocyclic Ligands Through Theoretical Evaluation of 1H NMR Contact Shifts Aurora Rodríguez-Rodríguez, David Esteban-Gómez, Andrés de Blas, Teresa Rodríguez-Blas, Mauro Botta, Raphaël Tripier, and Carlos Platas-Iglesias pp 13419–13429 DOI: 10.1021/ic302322r

New Syntheses and Structural Characterization of NH3BH2Cl and (BH2NH2)3 and Thermal Decomposition Behavior of NH3BH2Cl Hima K. Lingam, Cong Wang, Judith C. Gallucci, Xuenian Chen, and Sheldon G. Shore pp 13430–13436 DOI: 10.1021/ic302308v